Convergent Total Syntheses of (−)‐Rubriflordilactone B and (−)‐pseudo‐Rubriflordilactone B

A highly convergent strategy for the synthesis of the natural product (?)‐rubriflordilactone B, and the proposed structure of (?)‐pseudo‐rubriflordilactone B, is described. Late stage coupling of diynes containing the respective natural product FG rings with a common AB ring aldehyde precedes rhodium‐catalyzed [2+2+2] alkyne cyclotrimerization to form the natural product skeleton, with the syntheses completed in just one further operation. This work resolves the uncertainty surrounding the identity of pseudo‐rubriflordilactone B and provides a robust platform for further synthetic and biological investigations.     

LabVIEW和三维虚拟现实技术在物理实验中的应用研究

虚拟仪器技术主要倾向于数据处理的精确性,三维虚拟技术则倾向于形象的仪器展示.利用两者的优势,我们创造性地实现了三维虚拟现实技术与虚拟仪器技术的完美结合,并以"电子示波器的使用"为例,探讨LabVIEW技术和3D技术在物理实验中的应用.     

QCD PERTURBATION THEORY AND NUCLEI (1) THE ENERGY SHIFTS OF HADRENS AND HADRONS MASS DIFFERENCE MASS DIFFERENCE

QCD perturbation theory for confined quarks and gluons (inhadrons) is discussed.Based on the equivalent potential for the quark-gluon interaction derived, the energyshifts of hadrons and hadron mass difference in MIT bag (cavity) model and correcpond-ing approximation of the w. f. with Gassian form are calculated.     

医用固体激光器脉冲式强预燃系统控制电路设计

根据激光医疗所需激光脉冲的特点,针对长脉冲Nd:YAG激光器泵浦闪光灯中脉冲式强预燃系统的控制电路展开研究,采用UCC3895芯片控制预燃电路工作状态的变化,提供所需的预燃电流,从而配合其他电路得到相应的激光脉冲。文中主要阐述以UCC3895为核心的脉冲式强预燃系统控制电路的工作原理,并且根据实验,最终验证了该套系统的可行性。     

全桥变换器中磁通不平衡的抑制

分析了开关电源在采用全桥变换器的时候磁通不平衡现象的产生原因,并提出了实现抑制磁通不平衡的措施。着重介绍了应用阻隔电容实现磁通平衡的措施,同时进行了相关器件的设计与参数的计算。     

正交试验法优选田七花总黄酮的提取工艺

用正交试验法对田七花中的总黄酮提取工艺进行优化.以田七花中的总黄酮含量为考察指标,采用正交试验L9(34)表进行实验,对提取过程中的乙醇浓度、提取时间、提取次数及料液比四个影响因素进行研究.结果显示影响田七花中的总黄酮提取工艺的显著因素是提取次数,最佳提取工艺是:12倍量的80%的乙醇提取3次,每次1 h.     

随机利率下的连续型终身增额寿险

寿险中的随机利率问题,是近来保险精算研究的热点和重点问题之一.以即时赔付的连续型终身增额寿险为对象,对随机利率采用Gauss过程建模,Gauss过程与Poisson过程联合建模,研究赔付现值的各阶矩.并在De Movie假设下,给出其简洁表达式.     

金属磁记忆检测的机理及实现

现代工业的发展,离不开各种先进的无损检测(NDT)手段.但纵观传统的NDT方法,都是在部件缺陷发展形成以后才能被发现.金属磁记忆诊断技术是目前唯一能预测部件早期损伤的新方法.本文从晶体结构出发,在理论上和实验上分析了金属磁记忆检测的机理,并建立了系统模型.     

Theoretical Investigations of Nonlinear Optical Properties of Transition Metal Cluster Anions

In the framework of density functional theory （DFT）, the electronic excitations and nonlinear optical （NLO） properties of six binuclear transition metal cluster anions with the formula of [Ch2M-（μ-Ch）2-M＇CN]^2- （M = Mo, W; Ch = S, Se; M＇ = Cu, Ag） have been systemically investigated at both cases of gas phase and DMF solution. The obtained electronic absorption spectra reveal that the element replacements of metals M and ligands Ch have significant influence on the absorptions, especially on the low-lying ones. In addition, the transitions of μ-Ch→M are dominant for the low-lying excitations, whereas the transitions of M＇→M as well as Ch→M are mainly responsible for the higher excitations. The calculated molecular first and second hyperpolarizabilities present the remarkable element substitution and solvent effects. The analyses show that the transitions involving μ-Ch→M charge transfer make the critical contributions to the first hyperpolarizability t, and that the charge transfers from the moieties of MCh4 to M＇CN as well as those of μ-Ch→M and M＇→M are responsible for the second hyperpolarizability y. Moreover, the introduction of solvent leads to the results that the transitions within the moieties of MCh4 and M＇CN make larger contributions to the hyperpolarizability, especially to γ.     

A spin-parity analysis of the K+K+K− system produced in the reaction K+p → K+K+K−p

We present the first spin-parity analysis of the K⁺K⁺K^?) system produced in the reaction K⁺p → K⁺K⁺K^?p, and show that the general features of this system resemble those of the (ππ⁺π^?) and Kπ⁺π^?) systems produced in the reactions π(K)p → π(K)π⁺π^?p. There is a low mass enhancement, (47 ± 11)% of which corresponds to 1⁺ states decaying to Kø. At higher (K⁺K⁺K^?) masses 2^? → Kf′ becomes increasingly significant and at all masses there is a 0^? contribution of roughly 30%.