固载杂多酸催化合成戊二酸二异辛酯

研究了活性碳固载杂多酸催化戊二酸和异辛醇合成戊二酸二异辛酯的反应 ,探讨了原料配比 ,反应时间 ,催化剂用量等参数对酯化率的影响 ,在适宜工艺条件下 ,酯化率可达96.8 %     

基于人工神经网络的高考扩招趋势预测研究

高考扩招系统足一个“黑箱”,各因素问是否存在因果关系还很模糊,基于人工神经网络自身的特点,采用BP模型,借助MATLAB语言对高考扩招系统进行预测研究．通过对历史数据的处理、程序的设计、网络的训练等进行分析,最终预测出中国未来20年高等教育发展的趋势,为国家相关政策的制定提供参考依据．     

景观设计的坐标——生态设计

景观的生态性并不是新鲜的概念。无论在什么环境中建造,景观都与自然发生密切的联系。任何与生态过程相协调,尽量使其对环境的影响破坏达到最小的设计形式都称为生态设计。景观与生态设计反映了人类新的美学观和价值观——人与自然的友爱关系。     

批判意识与反思意识——“归来者”诗与“朦胧诗”价值取向比较论

劫后余生的“归来者“诗人和“朦胧诗“人在各自的创作中都把“文革“作为他们写作的文化资源;基于不同的人生经历、人生信仰,相异的个体生命体验、生命意识,他们用自己诗歌塑造出不同的“文革记忆“。在诗歌的价值取向上主要表现为对昨天的不同态度:“归来的歌“是一种明显的批判意识,在批判中确立自我的合法性;而“朦胧诗“有一种明确的反思意识,在反思中寻找自我的位置。     

Prediction of Anthropometric Dimensions Based on Grey Incidence Analysis and ANFIS

In order to select the efficient input variables of adaptive ncuro-fuzzy infence system （ANFIS）during the prediction anthropometric dimenions, grey incidence （GI） analysis, as a mastic method that ranks the sequence of of lots of variables in complicated factors has been applled.According to the prediction accuracy （A） between the predicted values and actual measured values, the ANFISG1 model with the parameters selected by using the GI analysis were more correct and effective than those done by multiple regression model and the model with input parmeters nonelected. The model prediction accuracy △Regrauskn= 0.804 7〈 △ANE3CI=0.9725, which proves the nodel with few parameters is more correct and effective than the other merits.     

单时滞倒立摆系统的稳定性分析

对单时滞倒立摆系统方程进行稳定性分析,通过对系统线性化方程的特征方程根分布的分析,给出了时滞量改变对系统稳定性影响的具体结论和公式.适当的滞量值会使倒立摆系统具有良好的稳定性.     

槲皮素与3d-过渡金属二价离子的配位反应研究

利用配体在配位反应前后的UV吸收变化与反应转化的关系,对槲皮素与3d-过渡金属二价离子在非水体系下的配位反应进行了探讨.实验表明,槲皮素金属配位反应活性受其羟氧自由离子的影响.同时,不同阴离子的同金属盐参与的配位反应会得到不同结构和性质的配位产物,也影响槲皮素的金属配位活性;槲皮素-金属配位反应对不同金属离子的反应配比不同.水和温度对配位反应的转化率会产生影响.     

Electronic properties and stabilities of methoxy-substituted Lindqvist polyoxometalates [Nb2W4019CH3]3- by DFT

The electronic properties and stabilities of five [Nb2W4O18OCH3]3-isomers have been investigated using a density functional theory method.The results show that the isomer with the methoxy group occupying a bridging position between two tungsten atoms(two tungsten atoms in the plane that contains two niobium atoms) in the [Nb2W4O18OCH3]3-framework is the most stable isomer in acetonitrile.The stability of the one-electron-reduced isomers changes little.The most stable one-electron-reduced isomer has the methoxy group occupying a bridging position between niobium atoms in the [Nb2W4O18OCH3]4-framework.The M-Ob(M = Nb,W;b denotes bridging) bond lengths in anions in which the metal atoms are connected by a methoxy group are longer than those in [Nb2W4O19]4-.The highest occupied molecular orbitals(HOMO) in [Nb2W4O19]4-mainly delocalize over the bridging oxygen atoms of two niobium atoms and two tungsten atoms located in the equatorial plane,and the bridging oxygen atoms on the axial surface.The lowest unoccupied molecular orbitals(LUMO) of [Nb2W4O19]4-are mainly concentrated on the tungsten atoms and antibonding oxygen atoms.Methoxy substitution modifies the electronic properties of the [Nb2W4O18OCH3]3-isomers.The HOMOs in the five isomers formally delocalize over the bridging oxygen atoms,which are distant from the surface containing the methoxy group and four metal atoms.The LUMOs delocalize over the d-shells of the four metal atoms that are close to the methoxy group,and the p-orbitals of oxygen.One-electron reduction occurred at the tungsten atoms,not the niobium atoms.     

二价铬或锰取代的硅钨杂多酸异构体的聚苯胺掺杂材料的制备及其热稳定性和荧光性能的表征

预先制备了由二价铬或锰取代的硅钨杂多酸钾盐的α及βi(βi=β1,β2及β3)异构体,然后在室温及无酸的条件下与聚苯胺进行固相掺杂,用红外光谱法、紫外-可见分光光度法、X射线衍射法、差示热重量法及分子荧光光度法对所得的掺杂材料的结构、热稳定性及荧光性能等特性作了表征.