Some Possible Asymmetry Effects of Nuclear Matter in Relativistic Heavy Ion Collisions

The asymmetry dependence of nuclear incompraeaibility and that of nuclear critical temperature are calculated baaed on a Thomas-Fermi model with Seyler-Blanchard interaction. It is found that the asymmetry effects are big enough to allow for checking the existence of these effects in relativistic heavy-ion collision experiments.     

Kishner-Wolff改良法——Ⅸ.α,β-环氧酮化合物的还原反应

α,β-环氧甾酮类化合物Ⅰ,Ⅶl及Ⅺ经用Kishner-Wolff改良法还原分别得相应的煤丙醇型化合物Ⅱ,Ⅷ及Ⅻ.至于芳基取代的链状环氧酮化合物ⅩⅦ及ⅩⅩⅡ则分别还原生成相应的吡唑化合物ⅩⅧ及ⅩⅩⅢ.化合物ⅩⅤ用水合肼处理得双羟基化合物ⅩⅥ.对于上述反应产物以及副产物的生成机理曾加以推测.     

FREE NON-LINEAR VIBRATION OF A ROTATING THIN RING WITH THE IN-PLANE AND OUT-OF-PLANE MOTIONS

Free non-linear vibration of a rotating thin ring with a constant speed is analyzed when the ring has both the in-plane and out-of-plane motions. The geometric non-linearity of displacements is considered by adopting the Lagrange strain theory for the circumferential strain instead of the infinitesimal strain theory. By using Hamilton's principle, the coupled non-linear partial differential equations are derived, which describe the out-of-plane bending and torsional motions as well as the in-plane bending and extensional motions. During deriving the equations of motion, we discuss how to model the circumferential stress and strain in order to consider the geometric non-linearity. Four models are established: three non-linear models and one linear model. For the four models, the linearized equations of motion are obtained in the neighbourhood of the steady state equilibrium position. Based on the linearized equations of the four cases, the natural frequencies are computed at various rotational speeds and then they are compared. Through the comparison, this study recommends which model is appropriate to describe the non-linear behaviour more precisely.     

关于新型蜂窝状筛网催化剂的研究——制备方法和催化性能

将活性组分负载于金属筛网模件上，制备了具有三维通透结构的蜂窝状筛网催化剂，100%的二氧化钛、2%的磷酸、0.25%的聚乙烯醇和聚乙二醇为最佳的成型助剂配方，经盐酸刻蚀、高温焙烧后，在金属筛网上将产生表面粗糙的基质层，其主要成分为Fe3O4，经过NH3选择性催化还原NO反应的考察发现，将质层对反应的化学动力影响不大；二氧化钛的涂覆能显著降低氨氧化副反应，同时在高温下二氧化钛涂层具有一定的NO还原活性，蜂窝状筛网催化剂具有良好的催化活性，当T=300℃时，催化活性可达90%以上。     

New Sesquiterpene Glycosides from Culture Hairy Roots of Catharanthus roseus

Two new compounds cadin-2-en-1β-ol-1β-D-glucuronopyranoside （1）, guaia-l,7-dien-3β,13-diol-13α-D- glucofuranoside （2） along with three known compounds have been isolated from the culture hairy roots of Catharanthus roseus. Their structures have been elucidated with the help of 500 MHz NMR using 1D and 2D spectral methods： viz： ^1H and ^13C NMR, ^1H-^1H COSY, ^1H-^13C HETCOR and DEPT aided by ELMS, FAB-MS, HR-FABMS and IR spectroscopy.     

Synthesis, characterization, and photophysical properties of Os(II) diimine complexes [Os(N(wedge)N)(CO)(2)I(2)] (N(wedge)N = bipyridine, phenanthroline, and pyridyl benzoxazole)

A new series of Os(II) diimine complexes with the general formula [Os(N(wedge)N)(CO)(2)I(2)], N(wedge)N = 2,2'-bipyridine (bpy) (1), 4,4'-di-tert-butyl-2,2'-bipyridine (dbubpy) (2), 4,7-diphenyl-1,10-phenanthroline (dpphen) (3), 2-(2'-pyridyl)benzoxazole (pboz) (4), and 5-tert-butyl-2-(2'-pyridyl)benzoxazole (bupboz) (5), were synthesized and characterized by spectroscopic methods and by a single-crystal X-ray diffraction study on the dpphen complex 3. The corresponding photophysical properties were studied using UV-vis and emission spectrometry. The resulting phosphorescence features both in solution and as a solid film, in combination with the MO calculation, lead us to conclude that the emissions originate from mixed halide-to-ligand (XLCT approximately 70%) and metal-to-ligand (MLCT approximately 30%) transitions instead of the typical MLCT transition. Using complexes 4 and 5 as the dopant emitters, we evaluated their potential to serve as a phosphor for organic light emitting diodes by examining their electroluminescent performances. Reddish orange electroluminescence centered around 600 nm was observed for organic light emitting diodes (OLEDs) fabricated using complex 5 as the emitter; the device efficiency was shown to be as high as 2.8% (and 5.0 cd/A or 2.7 lm/W), and the peak luminance was shown to be 5600 cd/m(2) at a driving voltage of approximately 15 V.     

介观光学结构提高蓝色顶发射有机电致发光器件效率

利用宽带有机半导体材料(2, 9-二甲基-4, 7-二苯基-1, 10-菲啰啉, BCP)形成无序介观光学结构来提高蓝色顶发射有机电致发光器件(OLED)的出光效率,从而提升器件的外量子效率.基于BCP折射率匹配的作用,在顶电极上增加一层BCP薄膜,器件内的波导光能够被进一步散射出来,且由于此材料本身具有低的玻璃化转变温度,在一定的环境条件下(温度及湿度)下BCP易发生自聚集结晶而形成无序介观光学结构,藉此结构使原来被限制于表面等离激元(SPP)的能量而耦合成自由光场,从而被有效提取出来.通过BCP结构薄膜的作用,器件最大亮度从4500 cd·m^-2提升至9840 cd·m^-2,外量子效率(EQE)从0.42%提升至1.14% (提高了1.7倍),此外光谱也蓝移12 nm,实现了蓝色发光光谱的优化.     

Na23(p,α)反应的两个很靠近的共振能级

在质子能量为1416千电子伏的附近,测量了Na²³(p,α)反应的α₀激发曲线。在这里过去认为只有一个共振能级,现在发现有两个能级存在:一个在质子能量为1416.8千电子伏处;另一个在1410.4千电子伏处,这个能级主要通过放出α粒子而衰变到Ne²⁰的基态。     

我们还需要前馈神经网络技术？

定义了前馈核神经网络的体系结构。从实际应用的需求出发。所定义的网络涵盖了目前多数前馈神经网络。从理论上证明了该网络的批量学习过程实际上所表达的是一种核学习机,进而证明了网络的学习仅需在最后一层实施即可,而在隐含层的参数可任意赋值。因此,该结论事实上是现有LLM及ELM的拓广。同时,发现在逼近精度要求不是太高的情况下,目前的前馈神经网络学习技术因过于繁琐而没有必要,仅需对网络最后一层进行学习即可。而前馈神经网络技术目前最前沿的应用是解决大样本及深度知识表达问题。针对这两个热点问题,分别提出了大样本下的廉价学习策略和深度知识挖掘下的灵巧学习策略。在此,作者希望该文能引起广泛讨论甚至争论。