全文获取类型
收费全文 | 108704篇 |
免费 | 12406篇 |
国内免费 | 17164篇 |
专业分类
化学 | 33086篇 |
晶体学 | 1331篇 |
力学 | 2886篇 |
综合类 | 1650篇 |
数学 | 6592篇 |
物理学 | 19429篇 |
综合类 | 73300篇 |
出版年
2024年 | 316篇 |
2023年 | 1107篇 |
2022年 | 2547篇 |
2021年 | 2788篇 |
2020年 | 2786篇 |
2019年 | 2525篇 |
2018年 | 2235篇 |
2017年 | 2828篇 |
2016年 | 3081篇 |
2015年 | 4462篇 |
2014年 | 5733篇 |
2013年 | 6943篇 |
2012年 | 7578篇 |
2011年 | 8426篇 |
2010年 | 7841篇 |
2009年 | 8293篇 |
2008年 | 8983篇 |
2007年 | 8707篇 |
2006年 | 8397篇 |
2005年 | 7262篇 |
2004年 | 5904篇 |
2003年 | 4567篇 |
2002年 | 5414篇 |
2001年 | 5192篇 |
2000年 | 4541篇 |
1999年 | 2523篇 |
1998年 | 877篇 |
1997年 | 780篇 |
1996年 | 669篇 |
1995年 | 593篇 |
1994年 | 554篇 |
1993年 | 573篇 |
1992年 | 481篇 |
1991年 | 414篇 |
1990年 | 401篇 |
1989年 | 386篇 |
1988年 | 293篇 |
1987年 | 234篇 |
1986年 | 202篇 |
1985年 | 132篇 |
1984年 | 133篇 |
1983年 | 112篇 |
1982年 | 75篇 |
1981年 | 81篇 |
1980年 | 72篇 |
1979年 | 50篇 |
1978年 | 30篇 |
1977年 | 14篇 |
1965年 | 21篇 |
1955年 | 13篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
61.
62.
介绍了可见光通信技术的发展历史及研究现状。基于带宽拓展技术搭建了1 W荧光型LED做光源、PIN光电二极管做探测器、单路速率610 Mb/s的实时传输演示系统,该系统在传输距离为6.2 m时的误码率为3.48×10-5。在此基础上搭建了荧光型LED为光源、PIN光电二极管做探测器的、双向100 Mb/s无线光上网演示系统。 相似文献
63.
为判断动物试验方法是否具备实用性,分析了中国关于实用性的相关规定,通过4个典型案例对动物试验方法是否属于非治疗目的的外科手术方法、是否具备实用性进行了分析,总结判断标准并给出了撰写权利要求的建议。在撰写动物试验方法的专利申请时,应当注意该方法的目的及该方法是否包含外科手术步骤,并针对该方法的不同情况采用不同的撰写策略。 相似文献
64.
The discharge of diverse pollutants has led to a complex water environment and posed a huge health threat to humans and animals. Self-propelled micromotors have recently attracted considerable attention for efficient water remediation due to their strong localized mass transfer effect. However, a single functionalized component is difficult to tackle with multiple contaminants and requires to combine different decontamination effects together. Here, we introduced a multifunctional micromotor to implement the adsorption and degradation roles simultaneously by integrating the poly(aspartic acid) (PASP) adsorbent with a MnO2-based catalyst. The as-prepared micromotors are well propelled in contaminated waters by MnO2 catalyzing hydrogen peroxide. In addition, the catalytic ramsdellite MnO2(R-MnO2) inner layer is decorated with Fe2O3 nanoparticles to improve their catalytic performance, contributing to an excellent degradation ability with 90% tetracycline (TC) removal in 50 minutes by enhanced Fenton-like reactions. Combining the attractive adsorption capability of poly (aspartic acid) (PASP), the composite micromotors offer an efficient removal of heavy metal ions in short time. Moreover, the designed micromotors are able to simultaneously remove antibiotic and heavy metals in mixed contaminants circumstance just in single treatment. This multifunctional micromotor with distinctive decontamination ability exhibits a promising prospective in treating multiple pollutants in the future. 相似文献
65.
Naphthalimide‐phthalimide derivative based photoinitiating systems for polymerization reactions under blue lights
下载免费PDF全文
![点击此处可从《Journal of polymer science. Part A, Polymer chemistry》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Pu Xiao Frédéric Dumur Jing Zhang Bernadette Graff Didier Gigmes Jean Pierre Fouassier Jacques Lalevée 《Journal of polymer science. Part A, Polymer chemistry》2015,53(5):665-674
Naphthalimide‐phthalimide derivatives (NDPDs) have been synthesized and combined with an iodonium salt, N‐vinylcarbazole, amine or 2,4,6‐tris(trichloromethyl)‐1,3,5‐triazine to produce reactive species (i.e., radicals and cations). These generated reactive species are capable of initiating the cationic polymerization of epoxides and/or the radical polymerization of acrylates upon exposure to very soft polychromatic visible lights or blue lights. Compared with the well‐known camphorquinone based systems used as references, the novel NDPD based combinations employed here demonstrate clearly higher efficiencies for the cationic polymerization of epoxides under air as well as the radical polymerization of acrylates. Remarkably, one of the NDPDs (i.e., NDPD2) based systems is characterized by an outstanding reactivity. The structure/reactivity/efficiency relationships of the investigated NDPDs were studied by fluorescence, cyclic voltammetry, laser flash photolysis, electron spin resonance spin trapping, and steady state photolysis techniques. The key parameters for their reactivity are provided. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 665–674 相似文献
66.
Facile fabrication of fast recyclable and multiple self‐healing epoxy materials through diels‐alder adduct cross‐linker
下载免费PDF全文
![点击此处可从《Journal of polymer science. Part A, Polymer chemistry》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Xiao Kuang Guoming Liu Xia Dong Xianggui Liu Jianjun Xu Dujin Wang 《Journal of polymer science. Part A, Polymer chemistry》2015,53(18):2094-2103
A reversibly cross‐linked epoxy resin with efficient reprocessing and intrinsic self‐healing was prepared from a diamine Diels‐Alder (DA) adduct cross‐linker and a commercial epoxy oligomer. The newly synthesized diamine cross‐linker, comprising a DA adduct of furan and maleimide moieties, can cure epoxy monomer/oligomer with thermal reversibility. The reversible transition between cross‐linked state and linear architecture endows the cured epoxy with rapid recyclability and repeated healability. The reversibly cross‐linked epoxy fundamentally behaves as typical thermosets at ambient conditions yet can be fast reprocessed at elevated temperature like thermoplastics. As a potential reversible adhesive, the epoxy polymer with adhesive strength values about 3 MPa showed full recovery after repeated fracture‐thermal healing processes. The methodology explored in this contribution provides new insights in modification of conventional engineering plastics as functional materials. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 2094–2103 相似文献
67.
以宁波市公共自行车为例,将因子分析法与二项logistic法相结合,对采集的1 688份居民满意度有效问卷展开分析。利用因子分析法筛选出6个因子,利用二项logistic法剔除并筛选出5个有效因子构建公共自行车服务满意度评价模型,合理评估当前宁波市公共自行车服务满意度。同时,利用随机抽取并不参与建模的5%问卷样本对评价模型进行校验,以确保模型的准确性与合理性。该研究有助于合理评价当前宁波市居民对公共自行车的服务满意度,同时适用于对未来一段时间内公共自行车服务满意度的预测。 相似文献
68.
69.
对石英音叉增强型光声光谱(QEPAS)系统中常用的石英音叉进行了有限元模态计算,获得石英音叉前6阶振型与模态频率,认知了第4阶对称摆动振型为有效振动,利用单因素法分析了石英音叉的音臂长度l1、音臂宽度w1、音臂厚度t、音臂切角θ、音臂圆孔直径d及音臂圆孔高度h对低阶有效共振频率(Fre)的影响,敏感度依次为: l1> w1>d>θ>t>h,考虑实际设计情形,筛选出了l1,w1,d与h四个石英音叉设计变量,采用Box-Behnken实验设计方案与RSM(response surface methodology)方法,以Fre为函数目标,建立l1,w1,d与h的二次回归响应面模型,得到了参数之间的交互作用,利用Design-Expert软件对响应面模型进行设计参数反求,结果表明,在15 000 Hz≤Fre≤25 000 Hz计算区域内误差较小,基本满足QEPAS系统的计算需求,所提出的研究与设计方法具有一定通用性,可为QEPAS系统中石英音叉结构参数设计提供参考。 相似文献
70.
Xiao Sun Li Zhang Yu Cao Jinhua Li Atanas G. Atanasov Linfang Huang 《Biomedical chromatography : BMC》2020,34(12):e4949
Balanophora involucrata J. D. Hooker has been known to possess potential anti-inflammatory and antibacterial activities; however, its antiviral activity has not been evaluated so far. In order to find new neuraminidase inhibitors (NAIs), the neuraminidase (NA) inhibition activity of different B. involucrata extracts was evaluated. In this study, an in vitro NA inhibition assay was performed to identify which extract of B. involucrata exhibits (maximal) inhibitory activity against NA. Ultra high performance liquid chromatography/quadrupole time-of-flight–tandem mass spectroscopy (MS/MS) and molecular docking techniques were used to identify the specific compounds responsible for the anti-influenza activity of the extract, and to explore the potential natural NAIs. The ethyl acetate extract of B. involucrata exhibited significant inhibitory activity against NA with 50% inhibitory concentration (IC50) value of 159.5 μg/mL. Twenty compounds were identified according to the MS/MS spectra; among them two compounds (quercitrin and phloridzin) showed obvious inhibitory activity against NA, with IC50 of 311.76 and 347.32 μmol/L, respectively. This study suggested that B. involucrata can be a potential natural source of NAIs and may be useful in the fight against ferocious influenza viruses. 相似文献