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191.
提出了用草酸.邻菲哕啉去除硅灰石中Fe^2 的方法,研究了浸取剂的浓度、浸取时间和温度等条件对Fe^2 的去除率的影响,在最佳的浸取条件下,Fe^2 的去除率达到98.35%。在去除猝灭剂后的硅灰石矿物中,掺加适量的稀土激活剂Eu^3 ,通过高温固相法制成荧光发光材料,发光强度明显提高,接近于化学试剂合成的发光材料。 相似文献
192.
Zhi Qiang Shi Ya Qing Feng Bing Zhao Wen Xiang Wang 《中国化学快报》2007,18(12):1493-1495
A novel series of N-alkylphthalimidylaminocarbonylmethoxylcalix[4]arenes with the reaction between 4-(N-bromoacetyla- mino)-phthalimide derivatives and calix[4]arene has been synthesized and structurally characterized by IR,~1HNMR and MS.From their analysis data,it was found that compounds 7a-7d adopted a cone conformation. 相似文献
193.
A novel molecular probe for identifying properties of supported transitionmetals and metal oxides catalysts was established.The catalytic mechanism oftransition metals was proposed. 相似文献
194.
GABAA五种亚型受体与BZ配基的3D-QSAR研究 总被引:1,自引:0,他引:1
GABAA受体是中枢神经系统内重要的抑制性受体,有广泛的神经生理活性.由于镇静/抗惊厥药物在临床上的广泛应用,使得其中苯并二氮杂作用位点尤为重要.我们用比较分子场法(CoMFA)对一系列咪唑苯并二氮杂类化合物(BZ)与五种重组受体亚型的亲和力进行了结构活性关系研究,得到的一组模型都有较高的交叉验证系数.并在此基础上,建立了非交叉验证的一组PLS模型.用该组模型对随机选择的6个化合物组成的测试集进行了预测,都得到了相当满意的结果,表明所建立的一组模型具有良好的预测能力.本研究对于设计高亲和力的BZ受体的配基和研究GABAA受体的模型有指导意义. 相似文献
195.
Recently, we have developed a fast approach to calculate NMR chemical shifts using the divide and conquer method at the semiempirical level. To demonstrate the utility of this approach for characterizing protein-ligand interactions, we used the deviation of calculated chemical shift perturbations from experiment to determine the orientation of a ligand (GPI-1046) in the binding pocket of the FK506 binding protein (FKBP12). Moreover, we were able to select the native state of the ligand from a collection of decoy poses. A key hydrogen bond between O1 and HN in Ile56 was also identified. Our results suggest that ligand-induced chemical shift perturbations can be used to refine protein/ligand structures. 相似文献
196.
通过对烷烃,醇类等有机物在五种不同极性固定相上的气相色谱保留值的测定,提出了从有机物气相色谱保留值测定其正辛醇/分配系数的公式,研究了从不同极性固定相上测得的保留值来测定其分配系数的准确性,得出烷烃类在所有柱上测得的保留值与其分配系数间均具有很好的关联,烷烃醇类在极性相异柱上的保留值之比值与其分配系数间也有很好的相关性,从而为烷烃及醇类等有机物分配系数的测定提供了一种简单、可靠,易行的新方法。 相似文献
197.
The localization of Terbium (Tb3+) cations binding to deionized bacteriorhodopsin (bR) has been studied by using spectroscopic methods. It was found that adding
Tb3+ cations to deionized bR affects the fluorescence lifetimes of tryptophan (Trp) in bR, the wavelength of fluorescence peak
shifts “blue” and the peak value of fluorescence decreases. It was also found that adding one Tb3+ cation to deionized bR can restore the purple state from its blue state obviously. The measurements of absorbance, fluorescence
and lifetime of fluorescence also show that when more than three Tb3+ cations are added, no further changes can be found. It is suggested that one Tb3+ specific binding site for the color-controlling is located on the exterior of the bR trimer structure to negatively charged
lipids near Trp-10 and Trp-12. Three Tb3+ cations binding per bR is needed for the regenerated bR. 相似文献
198.
Rui Qi SONG * Jian Qing ZENG Bing ZHONG Guangzhou Institute of Chemistry Chinese Academy of Sciences Guangzhou State Key Laboratory of Coal Chemistry Institute of Coal Chemistry Chinese Academy of Sciences Taiyuan School of 《中国化学快报》2002,13(10)
We have studied the palladium-catalyzed alkoxycarbonylation of allyl bromide in supercritical (sc) CO2 and found the reaction rate in sc CO2 was lower than those in some organic solvents1. The possible reason was the lower solubility of sc CO2 for the palladium catalyst. As an effective approach to improve the solubility of varieties of solutes, cosolvent such as ethanol has been widely used in the sc CO2 extraction2,3. Based on the above consideration, we chose several organic reagents… 相似文献
199.
1 INTRODUCTION Tri-butyl phosphate (TBP) has been widely used as the extraction reagent in U-Th fuel to separate uranium from thorium. But di-butyl phos- phate (DBP) and butyl phosphate (MBP), the radio- lytic products of TBP, exhibit some coordinated ability to the fission elements, such as Zr and Nb. The substitutes for TBP have being studied for several decades[1~4]. The physical and chemical properties of amides are similar to those of TBP and they selectively extract U(Ⅵ… 相似文献
200.
THE COMPARISON OF LANZHOU LOESS PROFILE WITH VOSTOK ICE CORE IN ANTARCTICA OVER THE LAST GLACIATION CYCLE 总被引:4,自引:0,他引:4
Loess near Lanzhou in the late Pleistocene is very sensitive to climatic fluctuations. The Beiyuan terrace profile in Linxia City, of which the curve of susceptibility tallies with the trend of isotopic curves of Vostok 2083 m ice core in Antarctica, is 35m thick. There are five layers of paleosols under Malan loess(L_1). Upper three layers (S_(1-a),S(1-b)and S_(1-c) correspond to three warm stages in last interglaciation, Interstadial of Last Glacial (C stage in Antarctic ice core)was clearly recorded in the Beiyuan profile, in which three layers of paleosols and two of loess were formed. The lowest section of the profile belongs to penultimate glaciation, in which fossils of cold-drought-resistant mammal and mollusc have been discovered. 相似文献