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201.
Fang Lu Xiu‐Li Wang Si‐Chong Chen Ke‐Ke Yang Yu‐Zhong Wang 《Journal of polymer science. Part A, Polymer chemistry》2009,47(20):5344-5353
Starch and poly(p‐dioxanone) (PPDO) are the natural and synthetic biodegradable and biocompatible polymers, respectively. Their copolymers can find extensive applications in biomedical materials. However, it is very difficult to synthesize starch‐graft‐PPDO copolymers in common organic solvents with very good solubility. In this article, well‐defined polysaccharides‐graft‐poly(p‐dioxanone) (SAn‐PPDO) copolymers were successfully synthesized via the ring‐opening polymerization of p‐dioxanone (PDO) with an acetylated starch (SA) initiator and a Sn(Oct)2 catalyst in bulk. The copolymers were characterized via Fourier transform infrared spectroscopy, 1H NMR, gel permeation chromatography, thermogravimetric analysis (TG), differential scanning calorimetry, and wide angle x‐ray diffraction. The in vitro degradation results showed that the introduction of SA segments into the backbone chains of the copolymers led to an enhancement of the degradation rate, and the degradation rate of SAn‐PPDO increased with the increase of SA wt %. Microspheres with an average volume diameter of 20 μm, which will have potential applications in controlled release of drugs, were successfully prepared by using these new copolymers. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 5344–5353, 2009 相似文献
202.
采用耗散粒子动力学(Dissipative particle dynamics,DPD)方法研究了线形两嵌段共聚物在本体中的自组装。通过改变两嵌段共聚物之间的比例、相互作用参数以及盒子的大小来研究对自组装结构的影响。这些模拟结果不仅与理论预测和实验结果相一致,而且证明了耗散粒子动力学方法是一种非常适合研究嵌段共聚物自组装行为的重要方法。 相似文献
203.
摘要: 针对多处理器片上系统 (Multiprocessor System on chip,MPSoC) 的通信优化技术--通信流水线和消息聚合,其过度使用可能会导致系统同步开销上升从而带来整体系统性能降低的问题,提出了基于整数线性规划(Integer Linear Programming, ILP)的优化策略.该策略以综合优化系统通信和同步开销为目标,通过对通信流水线技术和消息聚合技术的合理规划,使系统性能达到最优.实验结果表明,基于ILP的通信优化策略能够充分发挥通信优化技术的优点,使系统性能显著提升.
关键词: 通信优化; 整数线性规划; Simulink
中图分类号: TP 31文献标志码: A 相似文献
204.
基于对砂轮磨削过程中声发射信号的采集,研究了2种砂轮磨削过载判据的特征量提取方法,并提出了评价砂轮磨削过载判据的主要指标即灵敏度、稳定性和算法效率.通过选取合理的采样率与处理间隔,分析比较了2种信号处理方法对砂轮与工件过载的识别效果.结果表明,所提出的信噪特征比方法提取的特征量具有稳定性好、灵敏度和算法效率高的特点,且可以对过载点实现预判,可作为优先选择的磨削过载判据. 相似文献
205.
A practical and step-economic route to Favipiravir, an antiviral drug, was developed. Favipiravir was synthesized in only six steps from 3-aminopyrazine-2-carboxylic acid with an overall yield of about 22.3%. Key intermediates 3 and 6 were obtained in excellent purity via recrystallization from optimized solvents, which was beneficial to large-scale production. In the key synthetic reaction, 3,6-dichloropyrazine-2-carbonitrile (6) was reacted sequentially, in one pot, with KF and 30% H2O2 to give (after crystallization from 95% EtOH) favipiravir as colorless crystals, with a 60% yield for this final step of the synthesis. 相似文献
206.
SELF-ADAPTIVE STRATEGY FOR ONE-DIMENSIONAL FINITE ELEMENT METHOD BASED ON ELEMENT ENERGY PROJECTION METHOD 总被引:1,自引:0,他引:1
Based on the newly-developed element energy projection (EEP) method for computation of super-convergent results in one-dimensional finite element method (FEM), the task of self-adaptive FEM analysis was converted into the task of adaptive piecewise polynomial interpolation. As a result, a satisfactory FEM mesh can be obtained, and further FEM analysis on this mesh would immediately produce an FEM solution which usually satisfies the user specified error tolerance. Even though the error tolerance was not completely satisfied, one or two steps of further local refinements would be sufficient. This strategy was found to be very simple, rapid, cheap and efficient. Taking the elliptical ordinary differential equation of second order as the model problem, the fundamental idea, implementation strategy and detailed algorithm are described. Representative numerical examples are given to show the effectiveness and reliability of the proposed approach. 相似文献
207.
<正>A series of linear and V-shaped oligo(phenylene ethynylene) derivatives 1-3 were synthesized through sequent Sonogashira coupling and propargyl alcohol deprotection reaction in high yields.The alkoxy chains(i.e.,n-hexyloxy groups) were introduced to assure good solubility of compounds 1-3 in common solvents.The photophysical properties of 1-3 in solution depend strongly on the geometries of these compounds. 相似文献
208.
Novel high-reactive polyhedral oligomeric silsesquioxanes bearing multi-N-methylol groups (R-POSS) is synthesized. The chemical structure of R-POSS is characterized by FT-IR, 1H NMR, 29Si NMR. Nano-structure of R-POSS is observed by field emission scanning electro microscope (FSEM) and AFM. R-POSS monomer imparts a nano-sized inorganic core and organic corner with multi-N-methylol groups. R-POSS can readily crosslink to cellulose polymer and improve elastic recovery of cellulose materials. R-POSS as novel POSS reagent may be utilized for preparation of nanocomposite materials and functional biomaterials. 相似文献
209.
Yajuan Xu Tunhai Xu Yue Liu Shengxu Xie Yunshan Si Tonghua Liu Dongming Xu 《Chemistry of Natural Compounds》2010,46(2):242-245
The structures of five furostanol glycosides (1–5), of which the 26-O-β-D-glucopyranosyl-(25S),5α-furost20(22)-en-12-one-2α,3β,26-triol-3-O-β-D-glucopyranosyl-(1→4)-β-D-galactopyranoside (1) was new, from the leaves of Tribulus terrestris L. were established using chemical and NMR spectroscopic methods. 相似文献
210.