To improve the key properties of nonlinear optical crystals assembled with tetrahedral functional building units

Nonlinear optical (NLO) crystals assembled with conventional non-π-conjugated tetrahedral functional building units (FBUs), generally referring to [PO₄] and [BO₄], usually exhibit weak nonlinearity and poor birefringence. It is currently proposed that partially substituting oxygen atoms with fluoride atoms in these FBUs could enhance these crucial properties. Hence, we investigated for the first time the NLO-related properties of NH₄BAsO₄F (ABAF), which was constructed from tetrahedral [BO₃F] and [AsO₄] FBUs, and enhancements of these properties were observed in this material, that is large second-harmonic generation (SHG) response (2 × KDP) and improved birefringence (0.03 at 1064 nm). Notably, both SHG coefficient and birefringence of ABAF exceeded those of a great majority of phosphates, sulfates, or boron phosphates and achieved a preferable balance. It is interesting that ABAF shows vast structural similarities to the typical NLO crystals Sr₂Be₂B₂O₇ (SBBO) and KBe₂BO₃F₂ (KBBF), which might be the partial reason why it showed improvement in these vital properties. This work may afford some inspiration for enhancing the key performances of NLO crystals assembled with non-π-conjugated tetrahedra.

We report a new nonlinear optical crystal assembled exclusively with tetrahedral functional building units in which enhanced birefringence (Δn) and second-harmonic generation (d_eff) were observed.     

One-step hexaplex immunoassays by on-line paper substrate-based electrospray ionization mass spectrometry for combined cancer biomarker screening

Mass spectrometry (MS) is attractive as a multiplexed immunoassay readout benefiting from its high sensitivity, speed and mass resolution. Here, a simple paper-based hexaplex immunoassay with an on-line MS readout was proposed, using functionalized paper as the immune substrates, along with rhodamine-based mass tags assembled on gold nanoparticles prepared as the mass probes (MPs). Simultaneous immune capture and labeling were conducted in one step on paper substrates in 96-well plates with a high throughput within 30 minutes, and the on-line efficient dissociation of the mass tags highly facilitated the hexaplex readout of the immune signals by a newly established on-line paper substrate-based electrospray ionization-MS setup. Six MPs were synthesized for the simultaneous quantification of six important cancer protein markers (cancer antigen 15-3, cancer antigen 19-9, carcinoma embryonic antigen, cancer antigen 125, human epididymis protein 4, and alpha fetoprotein) using only 10 μL serum, presenting satisfactory sensitivity, accuracy and specificity. This platform was further tested in screening for the six biomarkers in serum samples of patients with breast, liver and gastric cancers, showing its high potential for sensitive and specific early cancer diagnosis.

On-line paper substrate based electrospray ionization mass spectrometry for hexaplex immunoassays.     

在线分离光度法测定痕量金的研究

本提出了一种泡沫塑料柱在线分离富集／β－环糊精－十二烷基苯磺酸钠溶液在线洗脱／硫代米蚩酮光度法测定痕量金的新方法。方法的检测出限是３×１０＾－＾８ｇＡｕ，线性范围是５×１０＾－＾７－８×１０＾－＾６Ａｕ，对于１．０μｇＡｕ进行１１次测定，相对标准偏差小于３．０％。     

New perylene polyimides containing p‐n diblocks for sensitization in TiO2 solar cells

Three novel perylene polyimides (PPIs) containing p‐n diblock units were designed and synthesized for use in dye‐sensitized mesoporous TiO₂ solar cells. They all dissolve in m‐cresol and N‐methyl‐2‐pyrrolidone (NMP). Their visible light absorption, electrochemical and photoelectrochemical properties were systematically studied. The polyimides have band gap energies of 2.16, 2.19 and 2.25 eV deduced from ultraviolet–visible absorption spectra, and electron affinity (E_a) and ionization potential (IP) of ?3.93 and 6.10 eV for PPI1, ?3.94 and 6.13 eV for PPI2, ?3.93 and 6.59 eV for PPI3, respectively, deduced from cyclic voltammogram. Experimental data show that introduction of 4,4′‐bisaminetriphenylamine cannot only greatly enhance optic‐electro conversion efficiency, but also enhance the dissolubility which in favorable for making the devices. The relationship of structure and properties of PPI is discussed and the mechanism of photocurrent generation is explained. Copyright © 2004 John Wiley & Sons, Ltd.     

从OSI看K-NET

随着微型计算机在我区的应用普及,许多用户已从分散、独立的单机作业向着联网作业迈进。国际标准化组织已推出一种开放式系统互连七层参考模型,这一模型已得到国际电报电话咨询委员会的承认,成为国际上网络通信的标准化基础。在许多局部网络中,K－NET因高效、低价、易学易用而对用户具有很强的吸引力。K－NET所采用的新思想和技术完全遵循OSI标准。因此,K－NET是值得推广的先进产品。     

合肥地区高校安居园工程可行性研究

文章针对合肥地区高校教师住房面积普遍偏小,尤其是中青年教师住房十分困难。经过对合肥地区高等院校教师现有住房情况的调研,提出了建造高等院校教师安居园工程的设想及实施方案,对实施“科教兴皖”的战略方针具有现实意义。     

高氯氧化锌烟尘浓硫酸脱氯的影响因素

研究了浓硫酸用量、固化反应时间、物料粒度对浓硫酸法脱氯的影响。结果表明,随着浓硫酸用量增加脱氯率增大,当烟尘酸量达到０．５２ｍｌ／ｇ时,再继续增加酸量,脱氯率反而下降;固化反应时间与脱氯率呈线性关系,随着固化反应时间的延长,脱氯率增大;氯化锌烟尘粒度在６０￣１７５μｍ范围内,对脱氯率影响不大。     

多媒体通信的技术特点和主要应用

介绍了计算机通信的技术特点,简要这了多媒体通信的主要应用领域。     

数字无绳电话PHS及其系统软件设计

数字无绳电话ＰＨＳ系统是结合了最新无线访问技术和智能网络技术的新的通信服务．介绍了ＰＨＳ系统的无线访问方法ＴＤＭＡ／ＴＤ和无线通道．按照通信协议的分层,设计了相应的软件结构．在物理层,实现了基本的物理帧传输;在数据链路层,实现了滑动窗口协议的数据帧传输;在网络层,实现了无线管理、移动管理、呼叫控制等．给出了这些层的典型函数模块．应用层是由中断驱动来实现各种服务的,并按优先级来调度处理事件．ＰＨＳ具有很高的性能价格比,具有广阔的应用前景．