Comparative Studies on Structure and Electronic Properties Between Thermal Lithiated Li_(0.5)MnO_2 and LiMn_2O_4

Monoclinic Li0.5MnO2 was synthesized by solid state reaction and the spectral and magnetic properties were studied in comparison with those of spinel LiMn2O4.The XRD pattern and Raman spectrum of Li0.5MnO2 are different from those of LiMn2O4,which indicate the different long-range and short-range crystal structure.XPS result shows the binding energies of 2p3/2 and 2p1/2 in Li0.5MnO2 are located at 642.3 and 653.6 eV,respectively.Through fitting the XPS spectra,the valence state of Mn ion in Li0.5MnO2 coincides with that in LiMn2O4.The high-temperature susceptibility of Li0.5MnO2 can be fitted by Curie-Weiss law whose Curie and Weiss constants are 33 A·m2·K/(mol·T) and-277(6) K,respectively.Although Li0.5MnO2 shows spin glass ground state,the transition temperature of Li0.5MnO2 is about 9 K lower than that of LiMn2O4.     

模型中强极小集的关系

研究了完全理论的模型中强极小集之间的关系,并证明了如果T是一个完全理论,Ψ1(x)和Ψ2(x)是T的两个强极小公式,则Ψ1(x)可以被Ψ2(x)X-表示,或Ψ2(x)可以被Ψ1(x)X-表示,或Ψ1(x)和Ψ2(x)独立.     

简单节杆菌AS 1.94*生物转化17α-甲基睾丸素C1,2-脱氢制备美雄酮

以17α-甲基睾丸素为底物，利用简单节杆菌（Arthrobacter simplex）AS 1.94^＊生物催化其C1，2-脱氢获得17α-去氢甲基睾丸素，即美雄酮。发现生长培养基的组成对转化结果有较大的影响；pH6．47—7．30有利于产物的积累；以较高的底物浓度（12g/L发酵液体积）投料时加入亲水性有机溶剂二甲亚砜，在转化结束后，能使发酵液中出现较大的产物结晶，并使最终转化率达70％以上。产物与未转化的底物经吉拉德试剂分离纯化后，产物质量符合BP98版标准。     

Total Synthesis of (±)-Nimbonone and (±)-12-Ethyl-13-methoxy- 8,11,13-podocarpatriene

Most diterpenoids exhibit significant bioactivities, such as antidermatophytic, antibact- erial, and antioxidant. Although a large number of aromatic tricyclic diterpenoids have been isolated, there are a few of them having ethyl substituent. The synthesis of this type diterpenoids has been seldom reported. In order to further study the relationship between the structure and bioactivities of the diterpenoid, we extended the diterpene synthesis1,2,3. It is desirable to report herein the syn…     

First Total Synthesis of (±)-Abieta-8, 11, 13-trien-7β-ol

The first total synthesis of (±)-abieta-8, 11, 13-trien-7β-ol (7) was accomplished via a strategy of AC→ABC, in which the reduction of the ketone 6 with LiAlH4 gave exclusively the title compound.     

筒型基础海洋平台气浮拖航稳性分析

介绍了筒型基础平台充气浮运的浮稳性和自由运动周期的理论分析方法。气浮体的浮稳性通过稳性高参数来判断，并提出了稳性高参数的计算式。气浮体的自由运动周期采用单自由度弹簧体系来计算，部分参数通过试验确定。理论计算得到的稳心半径与模型试验和现场原型试验的测算值非常吻合，气浮结构的静稳性分析理论和浮态分析理论得到了相互验证。最后利用气浮分析理论对一工程结构进行了计算分析。     

三（3,5-二叔丁基水杨醛缩苯乙胺）镧引发ε-己内酯开环聚合研究

首次采用三（3,5-二叔丁基水杨醛缩苯乙胺）镧[La（OPEBS）3]作为单组份引发剂用于引发ε-己内酯（ε-CL）的开环聚合.系统研究了溶剂、反应温度、单体/引发剂比例、单体浓度和反应时间对聚合反应的影响.研究结果表明La（OPEBS）3具有很高的催化活性,可以在反应温度为40℃,[-εCL]/[La]摩尔比为1 000,反应时间为40 min的聚合条件下得到分子量约为5.84×104,产率为99.9%的聚己内酯（PCL）.1H NMR结果显示己内酯单体是通过酰-氧键的断裂插入增长链.     

《跻春台》校点商榷

《跻春台》是清末四川中江人刘省三编辑的话本小说集，是研究近代汉语的珍贵语料。蔡敦勇先生的校点本错误较多，文章试从点、校两个方面对该本提出数十条商榷意见。     

L′ω1ω上的α-省略型定理及其应用

本文建立了L′_(ω1ω)上的一种α-省略型定理,并利用这一定理证明了当|T|是可测基数时的Morley猜想。     

Total Synthesis of (±)-Celaphanol A

Celaphanol A was a diterpene isolated from the stems of Celastrus stephanotifolius1, which have been the subject of continued and growing interest, due to the range of biological activities shown by many members of this family2. Some have been used in traditional medicine3 or as a stimulant4 from ancient times. In order to further study the relationship between the structure and biological activity of the diterpene compound and as an extension of diterpenoid synthesis in our laboratory5, 6, …