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151.
Organically modified solid-state silicates (ORMOSILS) doped with a new laser dye 1,3,5,7,8-pentamethylpyrromethene-2,6-disulfonate-BF2 complex (pyrromethene 556) have been synthesized by a sol-gel method and the compositional effects on pore characteristics, fluorescence and lasing properties have been investigated. It is found that the use of dimethylsulfoxide and γ-glycidoxypropyltrimethoxysilane could greatly change the structure properties of sol-gel derived ORMOSILS cage, and thus the fluorescence and lasing properties of the materials could improve significantly. A successful laser oscillation from this dye-doped ORMOSILS sample has been achieved upon pumping with a Q-switched frequency-doubled Nd:YAG laser at 532 nm. A slope efficiency of 54% with a useful lifetime greater than 10,000 shots has been demonstrated at a pump repetition rate of 1 Hz and a pump intensity of 1 J/cm2 by using the new ORMOSILS cage on our newly designed laser system. Our results have shown that it is possible to obtain a high-efficiency with a long-lifetime for a compact new laser device by low cost dye-doped solid-state ORMOSILS. 相似文献
152.
X.T Zhang Y.C LiuZ.Z Zhi J.Y ZhangY.M Lu D.Z ShenW Xu X.W FanX.G Kong 《Journal of luminescence》2002,99(2):149-154
The properties of the excitonic luminescence for nanocrystalline ZnO thin films are investigated by using the dependence of excitonic photoluminescence (PL) spectra on temperature. The ZnO thin films are prepared by thermal oxidation of ZnS films prepared by low-pressure metalorganic chemical vapor deposition (LP-MOCVD) technique. The X-ray diffraction (XRD) indicates that ZnO thin films have a polycrystalline hexagonal wurtzite structure with a preferred (0 0 2) orientation. A strong ultraviolet (UV) emission peak at 3.26 eV is observed, while the deep-level emission band is barely observable at room temperature. The strength of the exciton-longitudinal-optical (LO) phonon coupling is deduced from the temperature dependence of the full-width at half-maximum (FWHM) of the fundamental excitonic peak, decrease in exciton-longitudinal-optical (LO) phonon coupling strength is due to the quantum confinement effect. 相似文献
153.
154.
The magnetic and electric properties of the Sr2FeMoO6 compound produced under different preparation conditions were studied. Depending on the preparation condition, a strong variation in the nonmagnetic SrMoO4 impurity content was found, which in turn determined the metallic or semiconducting behavior of the resistivity of the Sr2FeMoO6 compound. There was also evidence that SrMoO4 played a crucial role in modifying the low magnetic field intergrain tunneling magnetoresistance in Sr2FeMoO6. In addition, we have established a simple method to prepare the single phase Sr2FeMoO6 polycrystals. 相似文献
155.
文章依据我国近年来税收增长和GDP增长的统计数据,得出税收增长速度高于GDP增长速度的客观事实,并就其原因进行了综合分析,最后指出,从长远来看我国未来的税收增长必将回归到与经济同步增长或者略低于经济增长的轨道上来,以为政府决策提供参考。 相似文献
156.
就近几年图书馆界关于新世纪馆员意识转换及社会角色转换等方面的研究进行了综述,指出新时期的馆员要实现自我社会角色的转换,首先是要明确转换的必要性,然后采取有效的策略逐步地、系统地推进转换,才能取得较好的效果。 相似文献
157.
158.
57Fe Mössbauer effect study has been performed on intercalated compound 2H?Fe0.5TaSe2 over a temperature range between 14K and 500K. The highly concentrated intercalation samples 2H?FexTaSe2 with Fe atoms (x up to 2) are prepared by the electrochemical method for the first time. The Mössbauer measurement shows that iron is in Fe3+ high spin state and with the same probability occupies both octahedral and tetrahedral interstices of the Van der Waals gap. The fact that effective masses of iron ions in both sites are close to 57 amu and characteristic temperatures (ΘM =130K, 107K respectively) are found to be relatively small is attributed to the weak forces on Fe3+. 相似文献
159.
H. Postma J. D. Bowman C. D. Bowman J. E. Bush P. P. J. Delheij C. M. Frankle C. R. Gould D. G. Haase J. Knudson G. E. Mitchell S. Penttilä N. R. Roberson S. J. Seestrom J. J. Szymansky S. H. Yoo V. W. Yuan X. Zhu 《Hyperfine Interactions》1992,75(1-4):153-163
Parity violation effects have been studied at 40 neutron p-wave resonances of the even-even nuclei238U and232Th. Of these 11 show parity violation effects larger than 2 standard deviations, making parity violation a rather common phenomenon.
Parity mixing up to 10% has been found. The root-mean squared matrix elements for parity violation derived from these resonances
are M=0.58 (+0.50/-0.25) meV for238U, respectively 1.39 (+0.35/-0.38) meV for232Th. 相似文献
160.
Main chain liquid crystal polymers are modelled as either worms or jointed rods. In reality they are composed of mesogenic units (rods) linked by spacers with varying degrees of flexibility. We present a molecular model to describe non-homogeneous nematic polymers. The model takes account of molecular parameters, such as the lengths of the mesogenic group and the spacer units, and the interactions between them. The spacers are found to have an order differing from the mesogenic units. If the spacer is not very long and thus in effect is inflexible, one end of the spacer can retain to some extent the orientation of the other end, allowing orientational correlation between spacers mediated by the intermediate mesogenic unit. This is important in giving the chain a global rod-like behaviour as the nematic field becomes strong or the temperature low. The nematic order of the two components (mesogens and spacers), the nematic-isotropic transition as well as the latent entropy are examined. Furthermore, the anisotropic conformations of the polymers are investigated, which show either rod-like or random walk behaviour. Comparison of our results with experiment is found to be satisfactory. 相似文献