一种用于大容量逆流色谱制备的立式多层螺旋管行星式离心机

Owing to no complications caused by solid supports, such as adsorptive sample loss and deactivation, tailing of solute peaks, and contamination, countercurrent chromatography (CCC) has been an area of intense research since the first introduction of CCC in 1970,[1] and various apparatus and broad applications have been advanced[2,3]. For these developments, the type-J synchronous planet centrifuge has received considerable attention, which relies not only on its relatively simple mechanic design, but also on its high partition efficiency and short elution time caused by mixing and settling for the efficient chromatographic separations. In the past, however, almost all of type-J centrifuges rotated slowly were disposed horizontally due to the original design and some experiments that gravis plays an important role at a low rotary speed as similar to type-V rotating multilayer helical tube in unit gravity[4-9]. In fact,we discovered that the upright apparatus holds more retention of stationary phase than the horiziontal aparatus when large standard tubings were used as mutilayer coil column and the aparatus was operated under same contions. We report here a new coil planet centrifuge with four upright cylindrical columns for large scale countercurrent chromatographic preparation. The design principle and apparatus of UCCC is as samilar to type-J multilayer coil planet centrifuge. Four uptight cylindrical column holders are symmetrically arranged around the centrifuge axis as similar to the type-J HSCCC with three horizontal multilayer coils connected in series[8] . A series of experiments indicat that upright CCC has many advantages over the horizontal CCC when using a large-bore tube as multilayer coil column for large scale countercurrent chromatographic separation.Upright CCC provide a versatile countercurrent chromatographic method for large-scale preparation from very crude sample. It has good preparative capacity and flexible suitability to various sample and two-phase system.The present apparatus not only can be operated at a high speed as similar as commonly used HSCCC for the system having short settling time and but also can be run at a low speed for the system having relative long settling time. Because of automatical control and seal-free flow through device, the uptight CCC apparatus may be readily scaled up to industrial preparation.     

以PVA为分散介质制备纳米氧化铁颗粒及其ESR特征(英文)

利用金属离子在高分子配合物中独特的离子簇结构以及PVA对所制样品颗粒的良好保护和分散作用,通过配位转换的方法,在PVA介质中制备出超微氧化铁颗粒,并通过高温煅烧高分子金属氧化物复合体获得红褐色纳米氧化铁颗粒.XRD测试表明此氧化物为α Fe2O3和Fe3O4的混合物,粒径为40～65nm;样品的ESR结果表明该法制备的氧化铁颗粒具有较强的磁性.同时,还初步研究了PVA中氧浓度与Fe离子浓度的比及氨水浓度对产物粒径的影响.     

多气隙电阻板室的宇宙线测量结果

介绍了20多个多气隙电阻板室的宇宙线测量结果.测量所用的宇宙线平台可以同时测量同一个电阻板室的多个cell,其参考时间的时间分辨为70ps.在宇宙线的测量条件下,用国产材料制作的多气隙电阻板室的时间分辨可达到90ps.利用这套宇宙线测量系统,还对多气隙电阻板室的探测效率和cell间的相互串扰进行了研究.     

一种检测十二指肠胃返流光纤传感器的研制

设计了可检测十二指肠胃返流的光纤传感器,该传感器由470 nm的信号光、595 nm参考光和光纤束构成,主要检测十二指肠返流物中的胆红素在470 nm与595 nm的吸光度,本文还对影响传感器检测的因素,诸如波长、pH、胃液中悬浮颗粒造成的散射作用以及其他的因素,做了详细评价.传感器可以达到10 mg/dl优良的动态响应范围,离体实验结果表明,该传感器可以作为临床动态检测手段.     

BEPCII新加速管的高功率测试和老练

BEPCⅡ(北京正负电子对撞机重大改进工程)要求其直线注入器提供更高的能量和流强,为此必须改进正电子产生靶前后的加速管,以提高加速梯度,并消除原有加速管因长期运行后性能有所下降的隐患.本文叙述了新加速管的高功率测试,包括测试装置的设计、建立,微波功率源(速调管)的调试和加速管高功率测试结果及其分析.     

具有时滞的非线性强迫微分方程振动的充分必要条件

对于一类特殊的具有时滞的二阶次线性强迫微分方程x"(t) +a (t)|x(τ(t))|γsgnx(τ(t)) =g(t)(0＜τ＜1),给出了它的所有解振动的一个充要条件.     

一个与人类待定肿瘤抑制基因同源的水稻基因的分离

从水稻基因文库中筛选到一个与人类待定肿瘤抑制基因QM同源的基因,命名为OSQM2．该基因片断长为3．1kb,编码一个具有184个氨基酸的高度碱性的蛋白质,与其他已知QM基因相比,该基因具有一个非常特殊的启动子,包含许多在植物中已发现的与抗逆有关的顺式作用因子,如：“G盒”,“DRE盒”,“MYC盒”等,故而该基因有可能是一个新的受环境胁迫因子诱导的基因,Southern杂交表明它以单拷贝形式存在于基因组中。     

基于谱方法的管内非牛顿流体非定常流动

以上随体Maxwell流体为非牛顿流体介质，探索了一种用谱方法解析处理水平圆管内非牛顿流体非定常流动的方法.该非定常问题归结为一个非线性二阶偏微分方程的求解问题.用谱方法将非线性二阶偏微分方程求解问题化为常微分方程组Chebyshev多项式数的近似问题，用Laplac变换法和本征值方法求解常微分方程组得到问题的解析结果.     

基于质量均匀分布的新型MTMD设计模型

提出了刚度和阻尼保持常量但质量均匀分布的新型MTMD设计模型以控制基底加速度激励下结构的振动，结构用某一受控振型的降阶模型表示.利用数值优化技术，研究了MTMD的最优参数，讨论了它对MTMD有效性和鲁棒性的影响.MTMD参数包括：质量间隔、频率间隔、平均阻尼比、调谐频率比、总质量比和总数.MTMD的优化准则定义为结构最大动力放大系数的最小值的最小化.为进行比较，还考虑了刚度和阻尼保持常量但频率均匀分布的MTMD设计模型.数值分析表明，新型MTMD设计模型不存在近0最优平均阻尼比，而且这种新型MTMD设计模型和频率均匀分布的MTMD设计模型达到近似同样的有效性和鲁棒性.     

中国人口、能源、经济发展的环境影响通径分析

提出采用多元通径分析的数学模型,定量分析我国人口数量、经济发展水平、能源资源消费对环境污染造成的直接和间接影响,并设计了这一方法的应用步骤.计算结果表明,现阶段我国庞大的人口数量和以煤炭为主的能源资源消费结构是造成我国环境污染的主要根源.