三元体系MCl-SbCl~3-HOAc (M=Li,Na; 25℃)的研究

测定了三元体系MCl-SbCl~3-HOAc(M=Li,Na;25℃)的溶度数据和饱和溶液的折光指数,并绘制了相应的溶度图及其折光指数曲线。M=Li时,体系的溶度曲线和折光指数曲线均由三支组成,分别与LiCl.0.5HOAc,LiCl,SbCl~3相对应。M=Na时,体系属于简单共饱型,无任何新相形成。研究结果表明,当M分别是Li,Na或K,NH~4,Rb,Cs时,体系的物理化学行为有着极为显著的不同,说明MCl-SbCl~3-HOAc(M=Li,Na,K,NH~4,Rb,Cs)体系可以作为区分碱金属系列阳离子性质差别的典型体系。     

SOLITARY WAVES IN MARANGONI-BENARD CONVECTING FLUID

In this paper the evolution of nonlinear long surface waves in a Marangoni-Bénard convecting fluid is considered. The fluid system is bounded below by an isothermic plane and above a free deformable surface, on which a heat flux is fixed. We show that the nonlinear behavior of the long surface wave is governed by the Korteweg-de Vries equation when the Rayleigh number is near its critical value. A head-on collision between two solitary waves traveling from opposite directions is also investigated by use of the Poincaré-Lighthill-Kuo method. The results show that the solitary waves emerging from the collision can preserve their original identities to the second order. The phase shifts due to the collision are calculated analytically.     

铱配合物催化下不饱和仲醇的氢转移反应

报导了IrH5(i-Pr3P)2(1)对不饱和仲醇的反应, 发现(1)可以催化分子内氢转移反应, 使不饱和仲醇转变为酮, 讨论了这一反应机理.     

用纸色谱法测定岩石及矿物中金、锑、硒、砷、铊、（铋）

文献报道了用纸色谱法测定岩石及矿物中铜、铅、锌等十二种元素的研究,并对其影响因素也作了探讨。而金、锑、硒、砷、铊、(铋)在4mol/L饱和正丁醇展开剂中用纸色谱法进行分离文献已有介绍,但利用此方法在岩石及矿物中对它们进行测定却未见报道。本文在此基础上,利用新华大张定性滤纸(50×60cm)作载体展开后,将谱带分别剪下进行测定。经实验表明,这种方法既简单、又快速还能解决干扰问题,若和文献结合起来,对于研究成矿规律及指导找矿是大有帮助的。     

The second harmonic resonance for the shallow water surface-wave in a rectangular trough

By using the perturbation method of multiple scales, this paper deals with the phenomenon of the second harmonic resonance for shallow water surface-wave in a rectangular trough. The results show that the envelope of the wave only depends on slow-variables of time. Eqs. of wave envelope are strictly solved and the results are discussed.Project Supported by the Natural Science Fund of China.     

全氟酰胺键合YWG填料分离苯二酚异构体和苯酚

苯酚和苯二酚的三个异构体虽然可以用无定形硅胶为填料作正相色谱分离,也可以用反相色谱来分离。可是当样品中存在较多量水时,不宜用硅胶作固定相。此外硅胶作固定相时,其间、对位苯二酚的分离度不佳,且邻苯二酚的色谱峰有“拖尾”现象。     

2D NMR研究呋喃糖Grignard加成产物的绝对构型

通过对相应呋喃糖进行Grignard亲和加成合成了苯基及苄基取代呋喃糖.所得主要产物的结构和绝对构型通过二维核磁共振进行了研究.其结果通过计算机分子模拟优化,并进行了比较和确认.     

晶格气体模型在重离子物理中的应用

介绍了用于描述中高能重离子碰撞后期形成的热发射源系统行为的晶格气体模型的原理,并同渗透模型作了比较．综述了该模型在描写核态方程、相变和临界现象的新进展及不足之处． The Lattice Gas Model is introduced to describe the features of phase transition and critical phenomena that take place after the collision between heavy ions at intermediate or high incident energy. New progresses in application into equation of state, phase transition and critical pheonomena, and shortcomings of this model in itself are also presented.