Synthesis and Crystal Structure of 7α-[（R）-1-Hy droxyl-1-methyl-3-（ thien-2-yl）-propyl]-6,14-endoethanotetrahydrothebaine

1 INTRODUCTION Opioid analogues still remain important drugs for the relief of severe pain and morphine is still the drug of choice in such situations. For many years, the search for new centrally acting opioid deriva- tives with pain-relieving properties and without un- desired side effects, such as addiction, obstipation, etc., has been the goal of a large number of scien- tists[1-3]. Consequently, a wide variety of modifyca- tions of the well-known alkaloids morphine, codeine and thebai…     

A Density Functional Theory Study on Electronic Structure and Second—order Nonlinear Optical Properties of Some Push—Pull Molecules

Time-dependent density-functional theory(TDDFT)has been applied to calculate the electronic structure and second-order nonlinear optical(NLO) properties of some organic molecules.The two-dimensional(2-D)charge transfer charateristics of calculated molecules were studied and compared with corresponding experimental results.All the theoretical results agree well with the measurement.For 2-D molecule with two-fold symmetry,the dominant charge transfer is off-diagonal,while for three-fold symmetry 2-D molecule,the dominant charge transfer is not only between branches and central group but also among branches.     

十八烷基取代吲哚啉螺吡喃衍生物的合成及光谱性质

本文合成了十种新的十八烷基取代的吲哚螺吡喃衍生物,拟进一步研究这类化合物在LB膜中的光致变色性质.     

二芳杂环基乙烯的合成及其光致变色反应研究

本文报道了2,3-双 (1,2-二甲基-3-吲哚基)-2-丁烯 (DF1),2,3-双 (1,4-二苯基-2-甲基-3-吡咯基)-2-丁烯 (DF2), 2,3-双(1-对甲苯基-4-苯基-2-甲基-3-吡咯基)-2-丁烯 (DF3), 2,3-双(1-对溴苯基-4-苯基-2-甲基-3-吡咯基)-2-丁烯 (DF4) 和2,3-双 (1-对甲氧苯基-5-苯基-2-甲基-3-吡咯基)-2-丁烯 (DF5) 的合成,以及它们的光致变色行为的研究。特别是DF1和DF5的光呈色和光消色过程进行了较为细致的研究。     

醇酸树脂热炼过程中分子量分布的研究

<正> 涂料工业中醇酸树脂基料分子量分布的研究,通常采用萃取分级法和沉淀分级法,近年来发展了高速凝胶色谱法。我们曾报道了高效GPC法测定醇酸树脂的分子量分布的方法。本文就醇酸树脂热炼过程产物作了物性表征和研究。 实验所测试样系取自5吨反应釜热炼生产中酯化过程各阶段和反应终点的产物。各品种醇酸树脂的配方见表1。     

乙烯在纳米催化剂InVO4-TiO2上的可见光降解

The InVO₄-TiO₂ nano-crystalline photocatalyst was prepared by sol-gel method and characterized by DRS, FTIR, Raman and XRD. The photocatalytic activities of the prepared sample were investigated by photocatalytic degradation of ethylene in the gaseous phase under visible light irradiation (λ>450 nm). The results indicate that both of pure TiO₂ and InVO₄ or their simple mixture show no photocatalytic activities for degradation of ethylene under visible light irradiation. However, as-synthesized InVO₄-TiO₂ catalyzes the degradation of ethylene into CO₂ under visible light irradiation. In addition, the interaction between InVO₄ and TiO₂ results in some structural distortion to all the crystal forms of TiO₂ in as-synthesized catalyst InVO₄-TiO₂.     

用溶液聚合法合成高相对分子质量的原油降凝剂

在低压下以异丁醇为溶剂,采用溶液聚合法合成了平均相对分子质量较高的原油降凝剂乙烯醋酸乙烯酯共聚物(EVA),探讨了合成条件对降凝剂EVA产量和性质的影响.实验结果表明,反应体系的压力从4 MPa增加到11 MPa时,EVA的产量从3.88 g增加到11.6 g,醋酸乙烯酯(VA)链节含量从25.2% 下降到16.34%,平均相对分子质量从0.38×104增加到1.37×104;引发剂用量从0.05 g增加到0.25 g时,EVA的产量从6.0 g增加到13.3 g,VA链节含量保持在23.5%左右不变,平均相对分子质量从0.34×104增加到1.72×104.醋酸乙烯酯用量从9.5 g增加到27.0 g时,EVA的产量从4.79 g增加到10.35 g,VA链节含量从8.81%上升到22.2%,平均相对分子质量从0.63×104增加到1.51×104;反应体系的温度从333.5 K上升到373.5 K时,EVA的产量从14.33 g下降到5.14 g,平均相对分子质量从1.39×104减小到0.53×104,EVA分子结构中VA链节含量从16.8% 上升到35.3%, 总支化度从25.0 CH3/(1?000C)升高到72.9CH3/(1?000C); 反应体系的溶剂选用良溶剂时,EVA的平均相对分子质量较低,反应体系的溶剂选用非良溶剂时,EVA的平均相对分子质量较高.当苯作为溶剂时,得到的EVA的平均相对分子质量为4?951;当异丙醇为溶剂时,EVA的平均相对分子质量为1.32×104.     

碳纤维改善水泥石韧性试验研究

针对油田中后期开发面临的固井质量问题，即水泥环脆性破裂问题，对水泥石韧性测定方法进行了讨论，采用水泥试件抗折强度和弹性模量试验以及薄片分析对碳纤维改善水泥石的韧性进行了考察，并分析了碳纤维改善水泥石韧性的机理。结果表明，纤维的加入可以使水泥石的抗折强度提高30％以上；随纤维掺量的增加，水泥石的弹性模量减小，泊松比增加；纤维在水泥石中的分布有效地阻止了裂纹的发展，增强了水泥石的韧性抗断裂能力。对于水泥石的抗折强度存在着最佳纤维长度和纤维掺量，本试验条件下，纤维的最佳长度为700～l400μm，最佳掺量为0．12％～0．19％。     

时间平均白光散斑剪切照相的统计分析

首次运用统计光学的理论，详细研究了时间平均白光散斑剪切照相的统计规律，导出了时间平均白光散斑剪切照相法研测振动问题的条件，指出了物体表面的粗糙度、照明光场的相干性.成像物面的相干域和光学系统的对称性对散斑条纹的影响.