SYNTHESIS AND MOLECULAR STRUCTURE OF Co（Ph2pyPO—N,O）2Cl2[Ph2pyPO=DIPHENYL（2—PYRIDYL）PHOSPHINE OXIDE]

<正> Complex Co(Ph2pyPO-N,O)2Cl2 was synthesized and its crystal and molecular structure was determined. Crystal data: Co(Ph2C5H5NPO-N,O)2Cl2, Mr = 688.4, monoclinic, space group A 2/a, a = 13.085(2), b = 11.134(3), c = 21.769(4)A,β=102.29(1)°,Z = 4, V = 3098.6 A3, DC = 1.476 g/cm3, final R= 0.049 and Rw=0.057 for 2804 independent reflections. The cobalt atom in the title molecules is coordinated by two chlorine atoms and two nitrogen and two oxygen atoms from the two phosphine oxide ligands, forming a distorted octahedron.     

A New Approach to α—Bromochalcones

α-Bromo benzolymethylene triphenylphosphorane 3 has been synthesized by the reaction of benzoylmethylene triphenylphosphorane 1 with N-bromosuccinimide in the yield of 87% and can react with aromatic aldehydes 4 to give α-bromochalcones 5 in good yields.     

Synthesis and Properties of Aryloxy—terminated Polydimethylsiloxanes

Aryloxy-terminated polydimethylsiloxanes (AOS) were synthesized by the telomerization of hexamethylcyclotrisiloxane(D3) with phenols.The structures of AOS were characterized by UV,IR,^2HNMR and elemental analysis,The effects of the reaction conditions and the mole ratios of the reactants on the molecular weight of the polymer were discussed.AOS′s structural influence on bactericidal action,flocculation and hydrolysis was studied.     

MAP载波带局域网通信控制器的研制

ＭＡＰ载波带局域网通信控制器的研制夏勤，顾冠群，潘建平计算机集成制造系统（ＣｏｍｐｕｔｅｒＩｎｔｅｇｒａｔｅｄＭａｎｕｆａｔｕｒｉｎｇＳｙｓｔｅｍ，ＣＩＭＳ）是八十年代以来随着信息技术，制造技术，计算机及网络通信技术的不断发展而出现的一项飞速发展的高...     

彩纹海棠叶片组织培养技术研究

以叶片外植体，在附加2mg／16－BA和0．5mg／1NAA的ms培养基上诱导长芽，在1／2ms附加0．5mg／1NAA培养基上诱导出根，对提高繁殖率、试管苗移栽成活等做了系统的研究。结果表明：在芽的诱导中，6－BA和NAA的浓度配比起关键作用，在诱导生根中，附加0.5％活性碳对生根起促进作用，培养物分别转移次数对苗的增殖有明显影响，次数少，增殖率明显低，试管苗的移栽成活对批量生产有重要意义。     

MPEG-2节目流到数字电视传输流的转换系统

为了给数字电视广播提供丰富的节目源，作者研究并实现了一个从MPEG-2节目流到数字电视传输流的转换系统．文中首先介绍了MPEG-2节目流和数字电视广播所使用的传输流的结构，在此基础上提出了具体的转换系统实现方案，并对其中涉及的一些关键技术作了详细的讨论．实时播放分析和离线分析的结果都表明，本系统可以正确、稳定地实现码流的转换．     

PLC虚拟数字实验室研究

本项目采用计算机仿真技术,以PLC教育为对象,开发了由虚拟的多种常用PLC系统和多种多媒体图形动画虚拟PLC被控对象组成的PLC虚拟数字实验室系统;提出了解决工程教育中虚拟数字实验室的设计方案,虚拟数字实验室的框架结构、实验环境、实验方法和实验操作步骤。