巯基修饰寡聚DNA诱导的具有光学各向异性的金纳米粒子组装体

Two complemental 2′-phosphorothioate oligo-DNA compounds were used as linker molecules to provide the necessary symmetry-breaking mechanism to direct the assembly of 13 nm Au nanoparticles into aggregates with anisotropic optical properties.     

具有锐钛矿骨架结构TiO2介孔分子筛的合成

在“酸-碱对”合成高度有序TiO₂介孔分子筛的基础上, 引入具有促进质子转移作用的硝基甲烷作为晶化助剂, 增强了合成体系中无机-无机之间相互作用力. XRD, TEM, BET, UV-Vis表征表明, 成功合成了骨架为锐钛矿的高度有序TiO₂介孔分子筛. 研究发现, 适量晶化助剂是成功合成的关键.     

63Cu(n,α)60Co反应截面测量

本文报告了E_n=13.6—14.8MeV中子能区用活化法以²⁷Al(n,α)²⁴Na截面为中子注量标准得的⁶³Cu(n,α)⁶⁰Co的反应截面.在中子能量为13.64,13.79,14.03,14.33,14.60和14.80MeV的截面值分别为58.3±3.1,56.3±2.4,53.4±2.0,50.8±1.9,48.4±1.7和47.4±1.7mb.在文中还列举了一些作者的数据以作比较.中子能量是用铌锆截面比法测定的.     

Observation of polarization in bottomonium production at square root of s = 38.8 GeV

We present a measurement of the polarization observed for bottomonium states produced in p-Cu collisions at square root of s = 38.8 GeV. The angular distribution of the decay dimuons of the Upsilon(1S) state shows no polarization at small values of the fractional longitudinal momentum x(F) and transverse momentum p(T) but significant positive transverse production polarization for either p(T)>1.8 GeV/c or for x(F)>0.35. The Upsilon(2S+3S) (unresolved) states show a large transverse production polarization at all values of x(F) and p(T) measured. These observations challenge NRQCD calculations of the polarization expected in the hadronic production of bottomonium states.     

CONVERGENCE OF (0,1,2,3) INTERPOLATION ON AN ARBITRARY SYSTEM OF NODES

1. IntroductionThis note deals with convergence of (0,1,2,3) illterpolation on an arbitrary system of nodes.Fisrt we illtroduce some definitions and notations.LetGiven a fiXed even integer m, let Ajk 6 Pm.--1 (the set of polynomials of degree at most mn-- 1)satisfyThen the (0,1,...,m--1) Hermite--Fej6r type illterpolation for f 6 C[--1, 1] is defined byand the (0,1,...,m--1) Hernilte interpolation for f e Cd--'[--1, 1] is defined by(of. [6]). We also need a well known fact:where 11' 11 sta…     

氧化钼-二氧化钛复合膜的可见光致变色性能研究

采用溶胶凝胶法制备了一系列氧化钼-二氧化钛纳米复合物, 用柠檬酸作分散剂, 将得到的纳米复合物粉末分散成溶胶, 涂膜制备了具有可见光变色性能的均匀透明的光致变色(λ≥420 nm)复合膜. 通过红外、XPS、ESR测定表明, 在氧化钼、二氧化钛复合界面上生成了Mo—O—Ti键, 此键的存在是该复合膜具有可见光致变色响应的内在原因. 在可见光的照射下, 电子从二氧化钛的价带经由Mo—O—Ti键, 被激发到氧化钼的导带上. 研究了光致变色过程的动力学, 发现光致变色反应的速率取决于膜中复合物的摩尔比([MoO₃]/[TiO₂])以及电荷转移能量(CTE).     

直链醇对反胶束体系中木素过氧化物酶催化活性的影响

根据研究发现, 在有醇作助表面活性剂的CTAB反胶束中木素过氧化物酶(LiP)不能表现活力, 而在水介质中CTAB对LiP的催化活性影响又不是很大. 为了揭示其中醇的影响, 本工作就不同碳链长度的醇对LiP酶催化性能的影响进行了研究. 由于CTAB反胶束体系中醇浓度较高, 且碳原子数大于4的直链醇在水中的溶解度又很小, 为此采用了LiP可在其中显示催化活性的CTAB正胶束、AOT反胶束和Brij30反胶束作介质, 通过研究这些介质中不同链长的醇对LiP催化活力的影响, 来探讨CTAB反胶束中木素过氧化物酶(LiP)不能表现活力的原因. 结果表明, 不管表面活性剂聚集体的结构、电性质及反胶束大小如何, 只要醇的浓度超过500 mmol•L^－1 (丁醇≥1200 mmol•L^－1), LiP在上述原本可显示活力的介质中均无催化活性. 据此推测CTAB反胶束中木素过氧化物酶(LiP)不能表现活力的原因主要是由助表面活性剂醇造成的.     

Simulation for the primary electronic donor of photosystem IIin vitro

Histidine coordinated to Chi a is a distinct characteristic of Chl ain vivo. By using histidine analogue of 1-methylimidazole (C₄H₆N₂2) and measuring the UV/vis absorption, CD and MCD spectra of the interaction between C₄H₆N₂ and Chl a in CCI₄, we have obtained that: (i) In pure CCl₄ solvent, Chl a molecule is in five-coordinate state, and two Chl a molecules form an asymmetric compact-dimer with strong coupling interaction. We propose that the two Chl a molecules are connected by two unequally coordinated Mg-O bonds (the two oxygen atoms come from the C=O of C13¹ keto and C17 ester, respectively); (ii) when the molar ratio of C₄H₆N₂/Chl a is 0.5 or 1 (corresponding to 2Chl a · 1C₄H₆N₂ and 2Chl a · 2C₄H₆N₂, respectively), significant changes have been observed in the absorption, CD and MCD spectra, which indicate that the Chl a remains in dimer form, but the coupling interaction between them reduces greatly. We postulate that C₄H₆N₂ replaces the ligation of C=O of C17 ester and C13¹ keto to Mg atoms sequentially. The two Chl a molecules linked by two weakly interacted Mg…O bonds form a relaxed-dimer. The structure of the model is essentially similar to that of the primary electronic donor, P₆₈₀, of photosystem II in high plants and algae.     

Abnormal Raman spectral phenomenon of silicon nanowires

The Raman spectra of two one-dimensional silicon nanowire samples with different excitation wavetengths were measured and an abnormal phenomenon was discovered that the Raman spectral features change with the wavetengths of excitation. Closer analysis of the crystalline structure of samples and the changes in Raman spectral features showed that the abnormal behavior is the result of resonance Raman scattering setection effect.     

THE OVERLAPPING DOMAIN DECOMPOSITION METHODFOR HARMONIC EQUATION OVER EXTERIOR THREE-DIMENSIONAL DOMAIN

1.IntroductionManyscientificandengineeringproblemscallbereducedtoexteriorboundaryvalueproblemsofpartialdifferentialequations.Althoughthenumericalmethodstosolveboundaryvalueproblems,suchasthefiniteelementmethodandthefinitedifferencemethod,areveryeffectiveonboundeddomains,yetweoftenfinditdifficulttousethemtodealwithunboundedproblems.Theboundaryreductionisaforcefulmeanstosolvesomeproblemsoverunboundeddomains.Amongmanyboundaryreductions,thenaturalboundaryreductionfoundedbyK.FengandD.H.Yuhassomed…