四氢呋喃/三氟化硼乙醚混合电解质中咔唑的电化学聚合

在四氢呋喃/三氟化硼乙醚混合电解质中直接阳极氧化咔唑制备聚咔唑.单体的起始氧化电位为0.92 Vversus SCE,远低于单体在含0.1 mol.L-1Bu4NBF4的乙腈溶液中的起始氧化电位(1.36 Vversus SCE).在此体系中获得的聚咔唑膜具有良好的电化学活性和稳定性,其电导率为7.0×10-3S.cm-1.聚合物可部分溶解于二甲基亚砜等强极性有机溶剂.UV-Vis,FT-IR,1H-NMR证明聚合物共轭长链的形成.该体系中获得的聚咔唑是一种蓝光发射材料,并具有良好的热稳定性.     

Modular Combination Design of Mine Rescue Capsule Based on Load Simulation

Mine rescue capsule is a typical emergency equipment in a coal mine. It provides a safe and confined space for miners when mining disasters occurred. The length of the passenger survival cell is suitable to be adjusted with several predefined modular cells according to various numbers of passengers. Aiming at the shortage of guidance rules for the modular combination design of mine rescue capsule, the configuration situations of survival cells are experimented with static and impact load analysis in ANSYS Workbench. The length range of a single cell, the combination schemes of miner survival section, and the effectiveness proof of assembled rescue capsules were solved sequentially by simulated load analysis on constructed structural models. The modular combination rules of the survival section are developed for variant passenger number ranging from 8 to 20. It also provides a reference for the optimal selection of rescue capsules with the same capacity. The proposed modular rules are effective for the rapid configuration design for mine rescue capsule driven by the number of passengers.     

Compact and broadband circularly polarized ring antenna with wide beam-width for multiple global navigation satellite systems

A compact and broadband circularly polarized (CP) annular ring antenna with wide beam-width is proposed for multiple global navigation satellite systems (GNSS) in the L1 band. The annular ring is excited by two modified L-probes with quadrature phase difference. It has a 36.3% 10-dB return loss bandwidth and a 13% 3-dB axial ratio bandwidth, because of the orthogonal L-probes with 90° phase difference. The measured peak gain of the antenna is 3.9 dBic. It can detect the satellites at lower elevation as its half power beam-width (HPBW) is 113° in both the x-z and y-z planes, achieving a cross-polarization level of larger than 25 dB. Noticeably, the antenna achieves 89% size reduction compared with the conventional half wavelength patch antennas. It can be used in hand-held navigation devices of multiple GNSS such as COMPASS, Galileo, GPS and GLONASS.     

新型生物反应墙原位修复石油烃污染地下水

以功能微生物、泥炭和粗砂为填充介质设计新型生物反应墙,研究了反应墙对地下水中石油烃污染物的修复效果与机理。结果表明:运行期内生物反应墙修复效果良好,苯系物、萘系物及菲去除率为83.6%～99.85%,其中71.23%～99.71%在墙体前半部分被去除。泥炭介质和功能微生物能够稳定发挥对污染物的吸附与降解功能,32.63%～77.98%的BTEX和97.14%～99.81%的目标PAHs被泥炭吸附去除;18.96%～50.98%的BTEX和已吸附于泥炭上的大部分石油烃污染物均显示被生物降解。微生物对污染物的降解可有效延长泥炭的吸附寿命,泥炭对功能微生物的营养供给可使反应墙内长期保持较高的功能微生物数量,每克干介质约含有3.46×106～6.16×109个。因此新型生物反应墙原位修复石油烃污染地下水是可行的。     

细菌生长的热谱图测定和生长速率的研究

用微量热计测定了8种细菌在相同培养基下代谢完整的热谱曲线,并对几个温度下在指数生长期的热谱图进行了动力学处理,得出不同了温度下细菌生长的速率常数和激活能。这些数据为药物对细菌的抑制作用提供了科学依据。     

镉胁迫对玉米生理特性的影响

采用砂培试验．用不同浓度Cd^2 对玉米幼苗进行处理．对处理后玉米的生理特性进行了研究。结果表明：镉对玉米的毒害受到时间和浓度双重因子的控制．在低浓度镉处理下．玉米的叶绿素含量和过氧化物酶活性首先稍升高．可以认为这是植物的一种自我保护性机制在起抗胁迫作用;但随着Cd^2 处理浓度的增大,叶绿素含量和根系活力降低．脯氨酸含量增加．这表明玉米对低浓度Cd^2 有一定的抵抗能力．但在高浓度处理下则受到损害;玉米不适合作为镉污染的环境监测植物．但游离脯氨酸变化明显．因此脯氨酸可以作为植物对镉污染的监测指标。     

天然高分子絮凝剂壳聚糖的改性及在水处理中的应用

壳聚糖作为一种高效,廉价的天然高分子絮凝剂,它也存在着自身的问题。文章介绍了壳聚糖的改性的研制及其特点,并介绍了它在水处理领域的应用研究进展及前景。     

甘氨酸分子的结构和振动频率的理论方法研究

用5种密度泛函、MP2和HF方法计算甘氨酸IP构型的几何参数和谐振频率，并与实验结果进行了比较，得出这些方法在计算甘氨酸的几何参数和谐振频率表现出的优越性关系：在优化几何参数方面，B3LYP方法优于其它方法；在计算谐频方面，标度因子校正是必要的，在非校正的情况下，DFT方法优于MP2和HF方法。     

羟基增塑剂对氨基甲酸酯淀粉与PVA混合浆相分离行为的影响

以初显分离时间和沉降率为量化指标,研究了正丁醇、1,2-丙二醇、丙三醇、季戊四醇、木糖醇和山梨醇6种具有不同羟基数目的增塑剂对氨基甲酸酯淀粉和PVA混合浆相分离行为的影响.研究结果表明,羟基增塑剂的加入能改善混合浆液的稳定性,随着增塑剂中所含羟基数目的增加,混合浆液的稳定性逐渐提高.当羟基数目等于3时效果最佳;但进一步增加羟基数目,氨基甲酸酯淀粉/PVA混合浆液稳定性反而会有所降低.此外,本文还研究了丙三醇的用量、PVA的聚合度和醇解度对混合浆液相分离行为的影响.