BaCe0.8Ho0.2O3-a陶瓷的性质与应用

Ceramic BaCe0.8Ho0.2O3-α with orthorhombic perovskite structure was prepared by conventional solid state reaction, and its conductivity and ionic transport number were measured by ac impedance spectroscopy and gas concentration cell methods in the temperature range of 600-1000 ℃ in wet hydrogen and wet air, respectively. Using the ceramics as solid electrolyte and porous platinum as electrodes, the hydrogen-air fuel cell was constructed, and the cell performance at temperature from 600-1000 ℃ was examined. The results indicate that the specimen was a pure protonic conductor with the protonic transport number of 1 at temperature from 600-900 ℃ in wet hydrogen, a mixed conductor of proton and electron with the protonic transport number of 0.99 at 1000 ℃. The electronic conduction could be neglected in this case, thus the total conductivity in wet hydrogen was approximately regarded as protonic conductivity. In wet air, the specimen was a mixed conductor of proton, oxide ion and electron hole. The protonic transport numbers were 0.01-0.09, and the oxide-ionic transport numbers were 0.27-0.32. The oxide ionic conductivity was increased with the increase of temperature, but the protonic conductivity displayed a maximum at 900 ℃, due to the combined increase in mobility and depletion of the carriers. The fuel cell could work stably. At 1000 ℃, the maximum short-circuit current density and power output density were 346 mA/cm^2 and 80 mW/cm^2, respectively.     

体温计模型的临界行为

提出一个可用离散朗之万方程描述的体温计模型.该体温计的特点是其温度示数只能随外界温度的升高而上升,当外界温度降低时,其示数却不能下降.根据体温计示数这种只升不降的特点,定义了“停顿”事件.用随机行走的理论解析地推导了停顿时间分布函数数值模拟和解析结果都显示这种分布函数呈幂律形式D(s)∝s^-ξ,揭示出在这一过程中所表现出的临界性. 关键词：     

ORACLE的PL／SQL在商品竞价交易决策系统中的应用

ＯＲＡＣＬＥ ＤＢＭＳ是当今应用于中、大型事务处理性能的关系数据库系统之一,它所采用的ＳＱＬ标准语言,具有集查询、操纵、定义和控制四大功能于一身的特点,但它是高度非过程化的,在某些特殊应用要求下,会受到局限。本文分析研究了ＯＲＡＣＬＥ系统中内嵌的ＰＬ／ＳＱＬ语言的特点后,把它应用于商品竞价交换决策中,取得了较好的效果,体现了简单、高效、实用的原则。     

不同药物对心理应激猕猴的抗应激作用

本文以心理应激猕猴为动物模型,比较研究了猕猴应激前后外周血中ＡＣＴＨ、皮质醇、胰岛素以及游离Ｔ３,Ｔ４的变化,并对安定、心得安等药物的抗应激效应进行了初步的探讨．实验结果表明,在应激前后,ＡＣＴＨ、皮质醇呈显著性差异（Ｐ＜０．０５和Ｐ＜０．０１）,胰岛素呈上升趋势．安定可使应激动物的ＡＣＴＨ、皮质醇的水平明显降低（Ｐ＜０．０５）,但是,对ＦＴ３,ＦＴ４的影响不明显．心得安对各种激素无明显影响．     

发射药热自燃的数值模拟研究

对发射药热自燃现象进行了数值模拟研究。通过与在实验室中进行的小模型实验及在野外进行的大模型实验结果的比较,确定了发射药热自燃的反应模型;在此基础上,通过数值模拟研究了直径和壁面温度对发射药热自燃的影响规律。结果发现：实验段四周壁面温度越高、实验段直径越大,发射药越容易自燃;发射药Ｎｏ．１比发射药Ｎｏ．２更容易发生热自燃。还预测了在各种温度条件下,发射药Ｎｏ．１与发射药Ｎｏ．２可能发生热自燃的直径范围。     

基于分维计算的颗粒粒度分析方法

提出了一种基于分形检测超细颗粒粒度的新方法及实现算法,超细颗粒在一定条件下产生布朗运动,通过光电系统记录的图象可看成是群体颗粒无规则漫游的结果,从而可用分数布朗运动模型去描述,对所获取的超强微粒布朗运动图象进行处理,然后按以上分形模型进行逐点的分维计算,再用统计的方法转换为粒度信息,从而实现粒度测量,文中给出了具体的算法及算例。     

中国南部二叠纪末和三叠纪初的沉积分区及其相型

本文论述了中国南部二叠纪末、三叠纪初的沉积岩相和生物相类型,并划分了若干性质不同的沉积区和相区。晚二叠世晚期有2个沉积区和8个相区;三叠纪初则演变为2个沉积区和斗个相区。文中还探讨了古生代与中生代之交沉积环境、气候以及生物群的演替等问题,认为中国南部大部分地区二叠系与三叠系之间无论岩相或生物相都显示了过渡性质。     

碱性介质中二过碲酸合铜(III)氧化乙二醇的反应动力学及机理

本文采用分光光度法研究了碱性介质中二过碲酸合铜(III)(DTC)氧化乙二醇(Glgcol)在291.2-303.2K的反应动力学机理。结果表明, 反应对氧化剂(DTC)是一级, 对乙二醇也是一级, 准一级([Glycol]0>>[DTC]0)速率常数Kobs随着[OH^-]增加而增加, 随着[TeO4^2^-]增加而降低, 并且有负盐效应, 提出了一种含有前期平衡的反应机理。据此导出了一个能够解释全部实验事实的速率方程, 求出平衡常数、速控步骤的速率常数及298.2K时的活化参数。     

应用新型立式逆流色谱制备分离南蛇藤中的南蛇藤素

A versatile countercurrent chromatography with upright multilayer coil planet centrifuge, named upright countercurrent chromatography (UCCC), was applied to the isolation and purification of celastrol from the roots of Celastrus orbiculatus Thunb. The crude celastrol was obtained by elution with petroleum ether from ethanol extracts using a 15 cm length and 5 cm I.D. of silica gel flash chromatography. Preparative UCCC (Fig. 1) with a two-phase system composed of petroleum ether (b. p. 60 ～ 90 ℃ )-ethyl acetate-tetrachloromethanemethanol-water ( 1:1:8:6: 1, v/v) was successfully performed, yielding 705 mg celastrol at 99.5 % purity from 1020 rng of the crude extract in one step separation.     

次甲基硅SiH与H2X(X=O,S)反应的热力学及动力学性质研究

在量子化学对SiH与H₂O和H₂S反应计算的基础上,运用统计热力学和Wigner校正的Eyring过渡态理论,计算了上述两反应在200～2000 K温度范围内的热力学函数、平衡常数、频率因子A和速率常数随温度的变化。计算结果表明,两反应在低温下具有热力学优势,而在高温下具有动力学优势。比较两反应的计算结果发现,在相同的温度下,SiH与H₂O反应比SiH与H₂S反应放热较多,但速率常数却较小。SiH与H₂O反应和前文报道的SiH与HF反应的比较表明,SiH与H₂O反应放热较少,而且在相同温度下,速率常数也较小。