乙酸乙酯合成反应的实时在线拉曼光谱测量

本文报道一种用于在线拉光谱测量的技术。可以在工业生产过程中对产品的成分和工作条件进行实时的监测,在本实验中,用我们自己研制的光纤探头,配合现有的拉曼光谱装置对合成乙酸乙酯的化学反应过程进行了实时跟踪测量。得到了反应过程中乙醇-,乙酸和乙酸乙酯的拉曼光谱,从谱图分析了它们的特征峰与时间的关系,从而可由这些结果确定在此实验条件下反应物与生成物的浓度随时间的变化,进而可确定反应过程完成的时间。     

空气源热泵除霜性能的实验研究

空气源热泵目前应用十分广泛,但是冬季热泵翅片管式蒸发器表面结霜会对其性能造成很大危害。因此除霜性能是影响热泵整体性能的重要因素之一。为了解决热泵除霜问题,实验测量了风冷热泵除霜的性能,研究了热泵除霜时各主要部件的性能变化,研究结论对热泵系统除霜研究具有重要的参考价值。     

Effect of Mn substitution on superconductivity in iron selenide(Li,Fe)OHFeSe single crystals

We synthesize a series of Mn substituted(Li, Fe)OHFeSe superconductor single crystals via a modified ion-exchange method, with the Mn concentration z(the atomic ratio of Mn:Se) ranging from 0 to 0.07. The distribution homogeneity of the Mn element incorporated into the lattice of(Li, Fe)OHFeSe is checked by combined measurements of high-angleannular-dark-field(HAADF) imaging and electron energy-loss spectroscopy(EELS). Interestingly, we find that the superconducting transition temperature T_c and unit cell parameter c of the Mn-doped(Li, Fe)OHFeSe samples display similar V-shaped evolutions with the increasing dopant concentration z. We propose that, with increasing doping level, the Mn dopant first occupies the tetrahedral sites in the(Li, Fe)OH layers before starting to substitute the Fe element in the superconducting Fe Se layers, which accounts for the V-shaped change in cell parameter c. The observed positive correlation between the T_c and lattice parameter c, regardless of the Mn doping level z, indicates that a larger interlayer separation, or a weaker interlayer coupling, is essential for the high-T_c superconductivity in(Li, Fe)OHFeSe. This agrees with our previous observations on powder, single crystal, and film samples of(Li, Fe)OHFeSe superconductors.     

原子间相互作用势对中Al浓度Ni75AlxV25-x合金沉淀序列的影响

基于微观相场模型与反演算法,研究了中Al浓度及温度对Ni₇₅Al_xV_25-x合金沉淀过程的影响：在相同浓度下,L1₂与DO₂₂结构的第一近邻原子间相互作用势随温度升高呈线性增加,两者呈正比的关系;但在同一温度下,L1₂（DO₂₂）结构的第一近邻原子间相互作用势随Al原子浓度的增加而增加（减少）.同时将反演得出的原子作用势代入微观相场模拟中,探讨中Al浓度合金沉淀序列与原子作用势的关系,即当L1₂的第一近邻原子间相互作用势大于（小于）DO₂₂时,L1₂（DO₂₂）优先析出;当L1₂和DO₂₂的第一近邻原子间相互作用势相等时,两者同时析出.特别地,当Al原子的浓度等于0.0589时,发现L1₂和DO₂₂同时析出.利用微观相场法反演原子间相互作用势,为判断中Al浓度合金的沉淀序列增加了可信度.     

关于使用光谱仪的一些建议

关于使用光谱仪的一些建议肖新民高长连王建模辛建之陶向阳罗宏雷１刘正东２（江西师范大学物理系南昌３３００２７）（１杭州三维高技术产业公司杭州３１００１２）（２浙江大学物理系杭州３１００２７）ＳｏｍｅＳｕｇｇｅｓｔｉｏｎｓｆｏｒＯｐｅｒａｔｉｎｇＳｐｅ...     

Zn_(1-x)Mn_xTe/ZnTe超晶格的多声子拉曼谱

Ｚｎ１－ｘＭｎｘＴｅ／ＺｎＴｅ超晶格的多声子拉曼谱陈辰嘉李海涛王学忠李晓莅孙允希王晶晶周赫田（北京大学物理系北京１００８７１）Ｍｕｌｔｉ┐ｐｈｏｎｏｎＲａｍａｎＳｐｅｃｔｒａｏｆＺｎ１－ｘＭｎｘＴｅ／ＺｎＴｅＳｕｐｅｒｌａｔｉｃｅＣｈｅｎＣｈｅｎｊ...     

随机共振研究进展

全面介绍了随机共振的概念、机理、理论和实验研究的主要进展及研究现状，对随机共振研究的可能应用也做了富有建设意义的展望性介绍。     

真空紫外光激发下掺Pr3+铝酸盐的自陷激子对Pr3+发光的影响

研究了SrAl12 O19:Pr3+和Y3Al5O12(YAG):Pr3+在20K,77K和300K的真空紫外(VUV)光谱,二者除了表现出Pr3+特有的发射性质外,还产生了一种特殊的发射现象,即自陷激子(STE)发射,并且其随着稀土离子浓度和温度的降低而增强.还着重讨论了自陷激子对Pr3+发光的影响.     

Hash function based on the generalized Henon map

A new Hash function based on the generalized Henon map is proposed. We have obtained a binary sequence with excellent pseudo-random characteristics through improving the sequence generated by the generalized Henon map, and use it to construct Hash function. First we divide the message into groups, and then carry out the Xor operation between the ASCII value of each group and the binary sequence, the result can be used as the initial values of the next loop. Repeat the procedure until all the groups have been processed, and the final binary sequence is the Hash value. In the scheme, the initial values of the generalized Henon map are used as the secret key and the messages are mapped to Hash values with a designated length. Simulation results show that the proposed scheme has strong diffusion and confusion capability, good collision resistance, large key space, extreme sensitivity to message and secret key, and it is easy to be realized and extended.     

Quantum state sharing of an arbitrary qudit state by using nonmaximally generalized GHZ state

We present a scheme for quantum state sharing of an arbitrary qudit state by using nonmaximally entangled generalized Greenberger-Horne-Zeilinger （GHZ） states as the quantum channel and generalized Bell-basis states as the joint measurement basis. We show that the probability of successful sharing an unknown qudit state depends on the joint measurements chosen by Alice. We also give an expression for the maximally probability of this scheme.