超高效液相色谱在烟草化学分析中的应用

对2000年至2017年期间超高效液相色谱法(UPLC)与光学检测器、质谱检测器联用测定烟叶原料、卷烟烟气、烟用材料等相关成分的应用进展作了评述,主要对色谱条件、前处理方法以及实际应用常见问题进行了讨论,并对目前UPLC技术使用的优势、不足及未来发展方向作了简要阐述(引用文献60篇)。     

模糊耦合神经网络的系统供热预测研究

热流量的准确预测,对于日益庞大的城镇供热系统能效提升起着至关重要的作用。首先对影响热流量的各因素应用数理统计的方法进行分析,然后采用模糊耦合神经网络算法对供热系统建立热流量预测模型,并通过某热源的历史运行数据进行分析,与小波神经网络算法比较,证实了该耦合算法的高准确性。这种将模糊理论与神经网络相结合的预测方法兼顾了二者的优点,使其既具有模糊逻辑的不确定信息处理能力,又可以有神经网络的自学习能力。该研究符合城镇供热系统非线性的特性,可以应用于智能热网的热流量预测。     

Structure and Optical Property of a New 1D Iodoplumbate Hybrid Directed by in situ Synthesized Asymmetrical N-benzyl-1,4-diazabicyclo[2.2.2]octane

Simple solvothermal reaction of PbI_2,1,4-diazabicyclo[2.2.2]octane and benzyl alcohol in the presence of HI acid creates a new organically templated iodoplumbate hybrid:[(N-Bz-DABCO)(PbI_3)]_n(1,N-Bz-DABCO+ = N-benzyl-1,4-diazabicyclo[2.2.2]octane).Compound 1 crystallizes in orthorhombic space group P2_12_12_1 with a = 20.044(9),b = 8.002(3),c = 12.345(5) ?,V = 1980.1(14) ?~3,Z = 4,C_(13)H_(19)N_2PbI_3,M_r = 791.19,D_c = 2.654 g/cm~3,F(000) = 1408,μ(Mo Kα) = 13.189 mm–1,the final R = 0.0303 and w R = 0.0849 for 3777 observed reflections(I 2σ(I)).Compound 1 contains one-dimensional anionic [PbI_3]nn-chains that are enclosed into the cationic channel formed from the N-benzyl-1,4-diazabicyclo[2.2.2]octane.Noteworthy,compared with common symmetrical N,N?-dialkyl-DABCO~(2+) cations,in-situ formed asymmetrical N-monoalkyl-DABCO~+ cation is first used as structure directing agents/templating agents in the haloplumbate system,finally leading to the occurrence of noncentrosymmetric feature in compound 1.In addition,UV-Vis absorption spectrum analysis reveals that compound 1 is a potential semiconductor material with energy gap of 2.80 eV.     

含参一元二次不等式解法浅析

和相等关系一样，现实世界和日常生活中同样存在大量的不等关系.学习研究不等式不仅是今后工作、生活的需要，而且是高考考纲中明确要求的必考内容.二次不等式又是不等式中的重要内容.因此，学好二次不等式是高中数学的一个重要课题.     

2080 nm long-wavelength,high-power dissipative soliton resonance in a dumbbell-shaped thulium-doped fiber laser

We demonstrate a 2080 nm long-wavelength mode-locked thulium(Tm)-doped fiber laser operating in the dissipative soliton resonance(DSR) regime. The compact all-fiber dumbbell-shaped laser is simply constructed by a 50/50 fiber loop mirror(FLM), a 10/90 FLM, and a piece of large-gain Tm-doped double-clad fiber pumped by a 793 nm laser diode. The 10/90 FLM is not only used as an output mirror, but also acts as a periodical saturable absorber for initiating DSR mode locking. The stable DSR pulses are generated at the center wavelength as long as 2080.4 nm, and the pulse duration can be tunable from 780 to 3240 ps as the pump power is increased. The maximum average output power is 1.27 W, corresponding to a pulse energy of 290 nJ and a nearly constant peak power of 93 W. This is, to the best of our knowledge, the longest wavelength for DSR operation in a mode-locked fiber laser.     

Strain Induced Nanopillars and Variation of Magnetic Properties in La_(0.825)Sr_(0.175)MnO_3/LaAlO_3 Films

To investigate the process of strain relaxation and resultant variation of microstructure and magnetic properties,low-doped La_(0.825)Sr_(0.175)MnO_3 epitaxial films with different thicknesses are deposited on LaAlO_3 substrates and strain induced nanopillars are discovered inside the La_(0.825) Sr_(0.175)MnO_3 film. Perpendicular oriented nanopillars mainly exist below 30 nm and tend to disappear above 30 nm. The distribution of nanopillars not only induce the variation of lattice parameters and local structural distortion but also lead to the deviation of easy magnetization axis from the perpendicular direction. Specifically, the out-of-plane lattice parameters of the film decrease quickly with the increase of the thickness but tend to be constant when the thickness is above 30 nm. Meanwhile, the variations of magnetic properties along in-plane and out-of-plane directions would also decline at first and they then remain nearly unchanged. Our work constructs the relationship between nanopillars and magnetic properties inside films. We are able to clearly reveal the effects of inhomogeneous strain relaxation.     

长期权力感知对谈判结果的影响研究

为了探究个人长期权力感知对谈判结果的影响及作用机制,丰富和创新现有的谈判理论,针对实验被试者设计并实施了一次多事项模拟谈判实验;以实验测量所得的长期权力感知、首次报价、调节作用分别作为自变量、中介变量以及调节变量,探究长期权力感知对谈判结果的影响、首次报价所起到的中介作用以及调节定向的调节作用;结果显示长期权力感知与谈判收益之间具有正向相关关系,首次报价在过程中起到中介作用,但是调节定向的调节作用在其中却并不显著;基于以上研究,长期权力感知更强的谈判者会提出更高的首次报价,从而获取更好的谈判收益,调节定向的调节作用在以后的研究中有待进一步探究。     

基于exp(-Φ(ξ))方法求解系列Burgers方程的近似解析解

研究了Burgers方程和改进Burgers方程基于exp(-Φ(ξ))方法的近似解析解.数值算例表明该方法求解Burgers方程和改进Burgers方程的近似解析解是有效的.     

河南省产业转移的创新响应区际差异研究

以产业转移的创新响应系数作为测度产业转移创新响应强度的变量指标,根据标准差和变异系数、相对发展率(Nich)以及离差(Di)和比率(Gi)等方法分析了河南省产业转移创新响应强度的区际差异及其影响因素。结果发现:(1)2007—2015年河南省产业转移的创新响应强度呈现不断增大的态势并呈现出阶段变化的特征。(2)河南省产业转移的创新响应强度从静态格局和动态变化上都呈现出明显的时空差异性,并根据各市的区域特点及产业转移的创新响应强度将河南省18个地市划分为强、较强、中等、较弱以及弱等5种区域类型;(3)创新能力、人才密集度、科技投入对产业转移的创新效应作用较大,技术市场需求和信息化作用相对较小。