FeCl_3催化合成新型烯丙基醚类化合物

以烯丙基醇类化合物(1a~1i)和乙醇为起始原料,FeCl_3为催化剂,经分子间亲核取代反应合成了9个烯丙基醚类化合物(2a~2i,其中2c,2e~2i为新化合物),收率80%~95%,其结构经1H NMR,13C NMR和HRESI-MS表征。研究了催化剂,溶剂,反应温度和反应时间对2a产率的影响。结果表明:在最优反应条件[1a 0.5mmol,Fe Cl34 mg,Et OH 2.5 mmol,CH2Cl2为溶剂,于室温反应0.8 h]下,2a收率95%。     

金星水星异常自转的自然形成机制

金星和水星有着与众不同的长周期自转,金星的缓慢逆向自转尤其引人注目,曾有多种假说试图解释其起源.本文在行星物质共同形成学说基础上,假定太阳系形成初期,所有大行星都一样顺向自转,在与公转轨道上星际物质碰撞过程中,因物质密度的不均匀分布使金星和水星获得了反向的角动量,形成了现在的自转状态.对行星角动量变化的积分计算显示,分别经过约50亿年和20亿年,金星和水星的自转可达到目前的状态.     

输出功率5.2 W的全固态连续单横模671 nm红光激光器

设计了全固态连续单横模671 nm红光激光器.利用880 nm LD双端端面泵浦Nd:YVO4复合晶体,实现了均匀泵浦并改善了激光晶体热效应;考虑到影响倍频转化效率的各种因素,优化设计了Z字形四镜激光谐振腔,采用I类临界相位匹配晶体LBO作为腔内倍频晶体;当泵浦功率为42.5W时,获得了5.2W的连续单横模671 nm红光输出,光-光转化效率达到12.2％,激光器长期功率稳定性优于±2.5％(1 h).     

Quantum Dynamics of Entanglement and Single Excitation Transfer in LH1-RC-Type Trimer

In this paper,we study quantum dynamics of entanglement and single excitation transfer(SET) in an LH1-RC-type trimer which can describe a basic unit cell in the LH1-RC complex in the photosynthetic process.It is shown that there exists a sudden change of entanglement at the critic point of quantum phase transition(QPT) of the system at low temperatures,the entanglement sudden change caused by the QPT is suppressed at higher temperatures.We investigate the influence of environment on entanglement and SET.We show the generation of the dephasing-assisted entanglement between a donor and an acceptor and the existence of the steady-state entanglement,and demonstrate the entanglement transfer from donor-donor entanglement to donor-acceptor entanglement in the dynamic evolution.We reveal the close relation between the SET probability and donor-acceptor entanglement.Especially,we find that the SET probability is proportional to the amount of donor-acceptor entanglement under certain conditions.     

输出功率12W的全固态连续单横模1.34μm激光器

设计了全固态连续单横模1.34μm激光器。利用880nm激光二极管双端纵向泵浦Nd:YVO4复合晶体,在泵浦功率为51W时,获得12.4W的连续单横模1.34μm激光输出,光-光转换效率达到24.3%,激光器长期功率稳定性优于±1.2%(3h)。     

Exciton transfer dynamics in a trimer system

We study exciton transfer dynamics in a trimer system by investigating excitation transfer probability (ETP). We calculate ETP in the zero-temperature limit and theoretically predict the environment-assisted quantum critical effect, in which ETP exhibits a sudden change at the critical point of quantum phase transition for the trimer. In particular, we find that the steady-state ETP can be observed in the presence of the environment interaction.     

Study of the structure of borromean nucleus 17Ne

The ¹⁷Ne nucleus is a possible candidate with a two-proton borromean halo structure. Since the theoretical model is difficult to handle the three-body system, it is difficult to determine the two-proton halo structure in ¹⁷Ne. In the present research, we try to study the breakup reaction of ¹⁷Ne. For the Borromean nuclei, one-proton knockout results in an unstable nucleus which is decaying further by proton emission. This process will result in an angular correlation between the direction of the aligned recoiling unstable nucleus and its decay products. The angular correlations can give us information about the configuration of the valence proton in the ¹⁷Ne. Furthermore, theoretical calculations indicate that the momentum distributions of ¹⁶F c.m are sensitive to the structure of the halo in ¹⁷Ne. Thus the measurement of momentum distributions of ¹⁶F c.m may also give us conclusive information on the structure of ¹⁷Ne. The present experiment has been done at IMP in Lanzhou using the radioactive beam ¹⁷Ne at 30.8 MeV/u on a 43mg/cm^{2 12}C target. The data analysis is under procedure and the primary results are provided.     

Investigation on Characteristics and the Improving Method of Double Loop Optical Buffer

We establish an equivalent cascaded semiconductor optical amplifier system model to analyze the characteristics of the double loop optical buffer （DLOB）. The theoretical analysis finds that the performance of the DLOB can be improved by inserted amplifying process in an interval of some cycles. The experiment demonstrates that the buffered cycles can be improved from 20 to 50 and the bit error rate is less than 10-9 by inserting amplifying process in an interval of about 10 cycles.     

Quasi-Elastic Scattering of 16C from 12C at 47.5 MeV/Nucleon

Differential cross sections for the quasi-elastic scattering of^16 C at 47.5 MeV/nucleon from ^12 C target are measured.Coupled-channels calculations are carried out and the optical potential parameters are obtained by fitting the experimental angular distribution.     

量子光学实验中宽带低噪声光电探测器的研制

针对量子光学实验的特殊要求,通过设计优化宽带低噪声放大电路,研制出宽带低噪声光电探测器.我们重点分析了影响光电探测器增益、带宽和噪声的因素,通过选择合适的光电二极管、取样电阻、反馈电阻和输出电容,获得了宽带低噪声光电探测器.该光电探测器的带宽为2～50 MHz,能够用于输入功率达15 mW光场的噪声测量,适用于包括平衡零拍探测、差拍探测等量子光学实验.考虑到在量子光学实验中需要一对平衡的光电探测器,我们制作了一对2 MHz～31 MHz带宽内共模抑制比大于30 dB的平衡光电探测器,并用于1064 nm激光和1550 nm激光的强度噪声测量和散粒噪声基准的校准.