应用扩展的2CJL模型确定微观势能参数

本文应用扩展的2CLJ势能模型优化了若干线型分子的微观势能参数.该模型包含了二分子间长程静电和诱导作用,同时也考虑了极性分子偶极矩与分子轴不平行的情况.通过第二维里系数的实验数据回归获得简单线型分子N2、O2、Cl2、F2、CO、NO、C2H6和C2F6的硬球直径σ和阱深ε.强极性分子CH3Cl、CH3F、CH3CF3、CF3CH2F和CH3CHF2的第二维里系数运用改进的混合规则计算得到,计算结果与实验数据符合很好.     

Dynamical Localization in a Two—Electron Quantum Dot Molecule Biased by a dc Voltage

We study the dynamics of two interacting electrons in a coupled-quantum-dot system with a time-dependent external electric field. The numerical results of the two-particle states reveal that the dynamical localization still exists under appropriate dc and ac voltage amplitudes. Such localization is different from the stationary localization phenomenon. Our conclusion is instructive for the field of quantum function devices.     

Layering of confined water between two graphene sheets and its liquid-liquid transition

Molecular dynamics(MD) simulations are performed to explore the layering structure and liquid–liquid transition of liquid water confined between two graphene sheets with a varied distance at different pressures. Both the size of nanoslit and pressure could cause the layering and liquid–liquid transition of the confined water. With increase of pressure and the nanoslit's size, the confined water could have a more obvious layering. In addition, the neighboring water molecules firstly form chain structure, then will transform into square structure, and finally become triangle with increase of pressure. These results throw light on layering and liquid–liquid transition of water confined between two graphene sheets.     

头孢噻肟钠、转铁蛋白相互作用的光谱特征EI北大核心CSCD

将转铁蛋白(TRF)的荧光变化作为研究对象,在298,310,318 K下采用紫外吸收、传统荧光、同步荧光、圆二色谱法,对TRF与头孢噻肟钠(CEM)的结合进行综合分析。数据处理和分析结果显示:TRF的荧光伴随CEM浓度的提高而呈现规律性猝灭,猝灭方式是静态的。两者借助静电作用结合,反应生成新物质。结果的准确性通过上述方法进行了验证。此外,同步荧光和圆二色谱也表明CEM影响了TRF的构象。     

三聚氰胺结石与疑似三聚氰胺结石的红外光谱分析

本文通过对三聚氰胺、尿酸、三聚氰胺结石和疑似三聚氰胺结石的红外光谱分析, 根据它们的特征峰位、峰形的特点和三聚氰胺、尿酸、草酸钙的标准红外光谱比较, 推出三聚氰胺结石由尿酸、尿酸胺、草酸钙和三聚氰胺形成的混合性结石。疑似三聚氰胺结石是草酸钙结石。因此, 红外光谱法可作为一种辅助手段, 为医学诊断提供理论依据。     

Er3+-Yb3+共掺碲酸盐玻璃上转换绿光激发过程的研究

根据Er³⁺-Yb³⁺共掺碲酸盐玻璃绿光上转换发光的能级结构和相关跃迁建立的速率方程模型,分析了Er³⁺的⁴S_3/2能级上升特性与⁴I_11/2能级和Yb³⁺的²F_5/2能级的关系.通过模型对实验观测的上升和衰减曲线的拟合,确定速率方程模型的相关参数,计算⁴S_3/2能级粒子数布居趋于稳定时能量传递粒子数与激发态吸收粒子数之比.进一步分析了Er³⁺-Yb³⁺共掺绿光上转换发光的动力学过程. 关键词： 速率方程模型 上转换 3+-Yb³⁺')" href="#">Er³⁺-Yb³⁺ 方波激发     

Cross-Correlation of Excitation Functions for Different Fragments and Different Scattering Angles in ^27Al（^19F,x）y Reactions

Excitation functions have been measured for different projectile-like fragments produced in ^27Al（^19F, x ）y reactions at incident energies from 110. 25 to 118. 75 Me V in 250 ke V steps. Strong cross section fluctuations of the excitation functions are observed. The cross-correlation coefficients of the excitation functions for different atomic number Z and for different scattering angle θcm have been deduced. These coefficients are much larger than the statistical theoretical calculated ones. This indicates that there are strong correlations between different exit channels in the dissipative heavy ion collision of ^27Al（^19F, x）y.     

高清医用电子内窥镜微型CMOS摄像模组(英文)

研发并报道一个全新的130万像素电子内窥镜微型摄像模组.该模组采用低压差分信号技术实现图像数据的长距离高保真传输,它包括一个1/5.5英寸、分辨率为1280×1024像素的CMOS图像传感器,一个视场角为140°的小型镜头以及2个电路板.小型镜头座直接粘合到图像传感器的非光学窗口部分,两块印刷电路板垂直装配,使模组的尺寸缩小到长宽高分别为15.0mm、5.5mm、5.2mm的空间.编码芯片将并行数字信号编码成低压差分信号经双绞线传出模组.搭建了实验系统并对摄像模组的实践性能进行评价.实验表明:模组分辨率达到136lp.mm-1,图像传输距离达到2m以上.紧凑的结构、高清分辨率图像、大视场和长传输距离使其适用于内窥镜诊治,特别是高清胃镜和结肠镜.     

倾斜沙漏流与颗粒休止角研究

本文发现在测量误差内颗粒物质的下列三个临界角度相等: 1)从直径为D的倾斜孔洞流出的Beverloo颗粒流的流量开始停止的临界倾角θ_c 向大孔径极限线性外推θ_c∞≡θ_c(D→∞) 的补角θ_s∞= 180°-θ_c∞;2) 从靠近堆顶的点源向光滑底板缓慢下落颗粒形成的圆锥形堆的休止角θ_r; 3) 直接剪切矩形颗粒固体测得的库仑内摩擦角φ. 该结果倾向支持倾斜孔洞和颗粒堆自由表面的固-液转变与颗粒固体内部的库仑屈服均来自材料的同一临界性质. 由于三种情况样品的内部应力和变形等都是目前还远不能定量分析的复杂非均匀分布, 我们仅从定性角度对此给出一些讨论.     

圆柱定程干涉法声速测量系统的实验测试

研究了圆柱腔体共振频率的测量方法,测试了新建立的声速实验系统,结果显示圆柱共鸣腔具有较高的信噪比,共振频率的测量不确定度小于5×10^-6。采用Ar气（99.999%）标定了声速共鸣腔的有效长度,不确定度为1.8×10^-5。开展了303～333 K下CO₂的气相声速实验研究,实验结果表明,当实验工质具有较高的纯度（>99.995%）时,气相声速的测量精度优于0.01%。