亚太地区外交 中东和会 乌拉圭回合

布什总统的亚太四国之行:政治意义大于经济收获 1991年12月30日至1992年1月10日,美国总统布什对澳大利亚、新加坡、南朝鲜和日本进行了为期12天的访问,这是“冷战”结束和苏联解体后美国总统对亚太地区的首次访问。布什此行的主要目的     

岡比亚

西非最小的国家岡比亚在非洲西部,是一狭长平原,面积一万零三百六十七公里,是英国在西非最小的屬地。岡比亚由两部分組成:一部分是位于岡比亚河口和河中的几个小島組成的殖民地,另一部分是位于岡比亚河两岸狭长地带的?さ亍H丝谖蛄?其中90%以上分布在保护地。主要民族是曼丁哥族,居民大多信仰伊斯兰教。     

受控热核反应

最近,一台小型的准稳态环形强磁场受控热核反应实验装置,在中国科学院物理研究所研制成功,并且已经调试运转,做了八百多次实验。这是我国年轻的科学工作者在党的领导下,坚决走毛主席指引的独立自主,自力更生的道路,艰苦奋斗的丰硕成果。什么是受控热核反应? 热核反应就是在极高温度下轻原子核(如锂、氚、氘等)发生的聚变过程。当温度足够高时,这种聚变能够自动持续进行并放出巨大的能量。例如太阳具有很高     

提高矩阵变换器传输性能的优化开关调制函数

用数学方法推导出矩阵变换器主电路开关矩阵调制函数的通解,针对变换器不同的传输性能指标,可对开关调制函数进行相应的优化,函数形式比较简单．在正弦输入和输出的目标下,可获得变换原理限定的最高电压传输率和接近为１的功率因数．给出了部分计算机仿真及实验结果．     

新型阴极材料Ba0.5Sr0.5Co0.8Fe0.2O3-σ制备与性能研究

Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3-σ(BSCF), a new cathode material for solid oxide fuel cell (SOFC), was synthesized by polyacrylicacid (PAA) method. The lattice structures of samples calcined at different temperatures were characte-rized by XRD. Shrinkage, porosity and pore size of the porous BSCF as a function of sintering temperature were investigated. It was found that the cubic perovskite structure could be formed after calcination at 800 ℃ for 2 h, but not well crystallized as seen from some unknown phases, and the pure cubic perovskite structure was formed after calcination at 1 150 ℃ for 2 h. The particle size of BSCF was less than 1～2 μm. The shrinkage of the porous BSCF increased with sintering temperature, but the opposite was true for the porosity. After sintering at 1 100 ℃ for 4 h, the porous BSCF was still in an appropriate structure, with porosity of 29% and electrical conductivity above 400 S·cm^-1.     

蔗糖测定的紫外分光光度新方法研究及应用

方法基于在酸性条件下,蔗糖水解生成果糖和葡萄糖,果糖受热破坏后,其产物在285nm处有较大的紫外吸收。通过试验,确定了最佳条件,并建立了测定蔗糖的新紫外分光光度法;其线性范围为0.27～31.2μg/mL,摩尔吸光系数ε为9.63×103L·mol-1·cm-1。该法简单、快速,准确度高,用于甘蔗汁中蔗糖含量的测定,结果满意。对蔗糖水解的机理进行了初步探讨。     

阴极材料LaFe0.8-xCuxNi0.2O3的合成和烧结性能

LaFe_0.8-xCu_xNi_0.2O₃ (x=0.0~0.2) (LFCN), a new cathode material of solid oxide fuel cell (SOFC), was synthesized by Co-precipitation method using sodium bicarbonate. The lattice structures of samples with different x contents were characterized by XRD. Porosity and density of the porous LaFe_0.8-xCu_xNi_0.2O₃ (x=0.0~0.1) as a function of sintering temperature were investigated. It was found that the orthorhombic structure could be formed after calcination at 900 ℃ for 4 h. The particle size of LFCN was about 350 nm. The density of the porous LFCN increased with sintering temperature, but the opposite was true for the porosity. On the other hand, at the same sintering temperature, the porosity of LaFe_0.8-xCu_xNi_0.2O₃ (x=0.0~0.1) decreased with increasing x contents. It is indicated that the dopant of Cu on LaFe_0.8Ni_0.2O₃ can facilitate the sintering of the materials. After sintering at 1 100 ℃ for 4 h, the porous LaFe_0.7Cu_0.1Ni_0.2O₃ was still with appropriate structure, and its porosity was 29%.     

催化新材料氮化钼和碳化钼的新进展

本文综述了近年来有关高比表面积氮化钼和碳化钼作为催化材料研究的新进展，着重对氮化钼的合成方法，ＭｏＯ３和ＮＨ３程序升温反应机理，以及γ－Ｍｏ２Ｎ，Ｍｏ２Ｃ和ＷＣ作为催化剂所涉及到的催化反应等方面进行了扼要介绍。     

a,a,a,b-ZnT(o-BocThr)APP对咪唑衍生物和氨基酸酯的分子识别研究

Molecular Recognition of α,α,α,β-ZnT（o-BocThr）APP （1） toward a series of imidazole derivatives and amino acid esters was investigated. Association constants were determined in chloroform by means of UV-Vis titration method. The association constants of 1 with imidazole derivatives are larger than those of 1 with amino acid esters. 1H NMR spectra were investigated to describe the binding mode of the recognition system, showing that all the protons of the guests were shifted to upfield. The circular dichroism spectra of 1-L-/D-ValOMe showed a split cotton effect in Soret region, while those of 1-L-/D-PheOMe showed no split cotton effect. Molecular modeling was performed to understand chiral recognition on a molecular level. Quantum chemical calculation was carried out based on the stable conformations of these recognition systems, which gave a reasonable explanation for the behavior of molecular recognition. The results indicated that the conformation of 1-D-ValOMe was more stable than that of 1-L-ValOMe.