Coherent coupling between vibrational modes of Cben H bonds at different positions studied by femtosecond time-resolved coherent anti-Stokes Raman scattering

We performed femtosecond time-resolved coherent anti-Stokes Raman scattering (fs-CARS) measurements on liquid toluene and PVK film. For both samples, we selectively excited the CH stretching vibrational modes and observed the expected quantum beat signals. The frequency of the well-defined beats is in good agreement with the energy difference between the two simultaneously excited modes, which demonstrates that a coherent coupling between the vibrational modes of the C-H chemical bonds exists at the different positions of the molecules. The dephasing times of the excited modes are obtained simultaneously.     

含水率对侧向卸荷条件下原状黄土黏聚力与摩擦角力学性质的影响

选取陕西省泾河南塬Q_2原状黄土,按主应力固结比σ_3/σ_1=0.33进行固结,以模拟土样原位地层的初始应力状况;固结完成后,在侧向卸荷条件下进行不排水剪试验,研究黄土滑坡过程中含水率对黄土的黏聚力、摩擦角等力学特性的影响。试验结果表明:含水率从10%→30%,黏聚力的变化范围从33.51→8.18 k Pa,随着含水率的增大,黏聚力明显降低,用线性关系式可以较好地拟合黏聚力和含水率之间的关系,且拟合相关系数R为0.970 8;含水率变化范围为10%~30%时,内摩擦角的变化范围为26.40°~29.60°,随着含水率的增大,内摩擦角的变化范围在3.2°以内,波动范围较小,其平均值为27.99°,因此卸荷条件下含水率变化主要影响原状黄土的黏聚力,对内摩擦角影响较小。