分光光度法测定竹节人参甲醇提取物中皂甙含量

采用分光光度法,以人参皂甙Rbl为对照,选择波长为571 nm,建立了测定竹节人参皂甙含量的方法. 实验结果表明,皂甙含量在100～600 μg之间,皂甙的质量与吸光度具有明显线性关系. 在此范围内,建立的皂甙质量(μg)和吸光度之间回归方程为Y=392.47x+104.18(R2=0.998 5). 检测方法的加样回收率为99.54%,RSD为0.97%. 测定方法与高效液相色谱法的测定结果无显著差异.     

一类非线性差分方程的精确解

将非线性微分方程的独立通解法推广到差分方程,给出了一类非线性差分方程的精确解,该精确解是由若干个独立通解共同构成,且独立通解的个数与差分方程的次数n无关.     

深基坑开挖对周边地表沉降变形的影响

为有效控制基坑周边地表的沉降变形,应用弹塑性大变形理论与有限差分理论,对哈尔滨地区桩-锚支护形式下深基坑开挖引起的周边地表沉降进行了数值模拟,分析了开挖深度、锚杆层数、建筑物距离对基坑周边地表沉降变形的影响规律及基坑周边地表沉降变形的量化范围。结果表明,基坑周边地表的沉降量与沉降范围随锚杆层数的增加而减小;建筑物的存在不仅增大了地表的沉降量,而且使基坑周围地表的最大沉降区向基坑方向移动;当建筑物与基坑的距离小于1.0倍基坑设计开挖深度时,建筑物距离对地表沉降变形的影响较明显;基坑开挖对周边地表的影响范围基本在与基坑边缘相距1.5倍基坑设计开挖深度范围之内。     

Compton散射下等离子体中电子相轨道的演化

用KMR模型研究了等离子体中多光子非线性Compton散射下电子相轨道的演化,发现电子与光子进行能量交换后,只有未被俘获电子的相轨道才能从周期性向非周期性、随机型演化,其演化剧烈程度随电子吸收光子数的增大而加剧,随电子与光子碰撞非弹性成分和碰撞前初始速度的增大而迅速减弱,但低于强激光场中的剧烈程度。当电子被光场俘获时,这种演化过程结束并做稳定的运动,光子不再为电子提供能量。     

一种新的锆石平衡态理论晶型

利用Machenzie方法, 计算了锆石晶体的{100}, {110}, {101}和{211}面的表面张力; 然后, 根据Wulf定律, 作出了一种新的锆石平衡态理论晶型. 该理论晶型由{211}锥面和不完全发育的{100}柱面组成, 与PBC理论晶型比较存在较大的差异. 平衡态理论晶型的推导将有助于理解深源岩浆或岩浆早期结晶锆石的晶型演化, 从而说明了锆石的形态具有岩石学标型意义.     

μ—均苯四甲酸根双核铜（Ⅱ）配合物的合成,磁性与？…

合成了三种新的双核铜（Ⅱ）配合物「Ｃｕ２（ＰＭＴＡ）（ｅｎ）２」（１）,「Ｃｕ２（ＰＭＴＡ）（ｐｎ）２」（２）和「Ｃｕ２（ＰＭＴＡ）（ａｐ）２」（３）;其中ＰＭＴＡ代表均苯四甲酸根阴离子;ｅｎ,ａｐ和ｐｎ分别表示惭二内二胺和１,３－丙二妥,经元素分析,摩尔电导和磁性的测定以及红外光谱等地这些配合进行了表征,测定和解析了配合物（１）的变温磁化率（４－３００Ｋ）;研究辽些配合物的生物活性,结果表明双核     

Structure and Properties of Porous Silk Fibroin Materials

In this article the structure and properties of freeze-dried porous silk fibroin materials were tested and analyzed.The results indicated that for porous silk fibroin materials prepared by means of freeze-drying,if freez-ing temperature was below —20℃,the structure of silk fibroin was mainly amorphous with a little silk Ⅱ crystal structure,and if freezing temperature was above —20℃,quite a lot of silk Ⅰ crystal structure formed.Porous silk fibroin materials,with average pore diameter be-     

多光子近场共焦光学扫描显微镜表面非传播光场的特性研究

对多光子近场共焦光学扫描显微镜非传播光场的特性进行了系统的理论分析。导出了多光子近场共焦光学扫描显微镜表面非传播光场的频率宽与相差的测不准关系表达式及二维的点扩散函数光学传递函数和能量分布表达式。研究结果表明：多光子近场共焦光学扫描显微镜比单光子共焦显微镜具有更高的横向分辨率和纵向分辨率。而多光子近场共焦光学扫描显微镜比双光子共焦显微镜具有更高的空间分辨率。样品置于其表面的非传播光场内,能得最佳的超分辨效果。     

Three-dimensional size and orientation of the precipitates in AZ91 magnesium alloys measured by TEM techniques

Knowledge of the microscopic structure, including three-dimensional (3-D) size and orientation of the precipitates, is essential to fully understand the mechanical properties of the magnesium alloys and designing the alloys with better performance. Analytical TEM with high spatial resolution offers the simultaneous measurements of 3-D size, structure, orientation, composition of the precipitates from one typical sample along an established crystallographic axis. Besides popular Burgers orientation relationship (OR), other ORs such as Pitsch--Schrader OR, Crawley OR, Potter OR and a new OR with the form of [0001]_α 1.0° from [311]_γ and (11\bar 20)_α 2.0° from (03\bar 3)_γ between the magnesium matrix and the precipitate γ -Mg₁₇Al₁₂ are identified by TEM imaging and diffraction techniques. As a case study, the thicknesses of the individual precipitates with Burgers OR are further measured to be 100--200~nm through both electron energy-loss spectroscopy and x-ray energy dispersive spectroscopy combining differential x-ray absorption and extrapolation, which are in agreement with the overall 3-D size statistic distribution results obtained through analysing various samples along various directions. Furthermore, the fabricated wedge-shape structure provides a platform on which to study the dependence of the interfacial strain on the variation of the thickness.     

不可逆卡诺循环火用经济优化准则

研究了存在热阻、热漏及气缸吸放热等损耗下的不可逆卡诺循环火用经济优化准则.结果表明:热机的最大输出功率不受高、低温热源热漏的影响,但与其热阻成反比;火用损耗率与热阻、热漏成正比.