三维扩散方程非正交六面体网格的有限体积差分法

三维扩散方程非正交网格的差分方法是计算流体力学和数值热传导中一个基础性的课题。该文在二维扩散方程的有限体积差分方法的基础上,研究了在非正交六面体网格下三维扩散方程的有限体积差分方法,提出了一个计算精度很高、通量守恒且适应大变形网格的有限体积差分格式。取单元中心作为计算节点,减小了计算量;利用通量守恒条件确定界面中心的函数值,保证方法的守恒性;对网格点采用了Lagrange因子插值法,考虑了各插值点的相对位置,因此更适应非正交网格的计算;采用不完全三角分解预处理Bi-CGSTAB方法求解线性代数方程组。不同Z网格上的数值实验结果表明该算法是有效的。     

通信原理教学课件的设计与制作

针对目前网络教育日益普及的趋势,结合<通信原理>课程本身的特点运用Dreamweaver MX、Photoshop7.0、Imageready 7.0、Flash MX等实用的软件进行网页式教学课件的制作,在完成课程教学目标的同时,尽可能突出网页式教学课件新颖活泼的形式以及对学习者而言自主性强的特点.     

农村地类调查技术方法比较

农村地类调查技术方法是决定农村土地调查能否按时保质完成的关键，因地制宜的选择好方法也是完成二调目标和任务的保障。为此，本文根据现阶段农村地类调查实施情况重点讨论了常用地类调绘法的优缺点，以便为技术单位更快更好的完成这项艰巨的任务提供参考。     

免焙烧制备WP/SiO2加氢脱硫催化剂

采用等体积浸渍法制备焙烧和免焙烧的催化剂前驱体,用H2程序升温还原法制备焙烧和免焙烧的WP/SiO2催化剂.对制备的催化剂进行XRD和N2物理吸附表征,并用质量分数为0.8%的二苯并噻吩/十氢萘溶液来考察催化剂的加氢脱硫反应活性.与焙烧的WP/SiO2(C-WP/SiO2)催化剂相比,NC-WP/SiO2具有较大的比表面积和孔容;反应后,两种催化剂的比表面积和孔容均降低.在NC-WP/SiO2上,DBT的转化率略低于C-WP/SiO2,但均随着温度的增加而升高;随着温度的升高,两种催化剂加氢中间体的选择性降低,直接脱硫产物BP的选择性升高,说明增加温度有助于含硫化合物的脱硫.340℃,C-WP/SiO2催化DBT的反应速率(0.33 mol·g－1·min－1)略高于NC-WP/SiO2(0.28 mol·g－1·min－1);在NC-WP/SiO2上,DBT主要以DDS路径脱硫,而在C-WP/SiO2上,加氢活性较高.     

HYDROGEN-SUPPORTED NITROGENASE ACTIVITY IN Rhodopseudomonas capsulata: THE NATURALLY OCCURRING ELECTRON CARRIERS

In vivo the hydrogenase of Rhodopseudomonas capsulata is capable of recycling molecular hydrogen, which is coupled to the nitrogenase for acetylene redaction. A ferredoxin from R. capsulata can be reduced by native hydrogenase with molecular hydrogen as electron donor. The reducing power generated by H_2-hydrogenase could couple to nitrogenase-dependent acetylene reduction via ferredoxin. A natural fraction from crude extracts of R. capsulata has been separated, which functions as an active electron carrier between H_2-hydrogenase system and acetylene reduction reaction by native nitrogenase. A low midpoint redox potential component was identified in this natural fraction. The evidence indicates that the component effective for the coupling of electron might be a cytochrome C_3. A methyl viologen-linked diaphorase activity specific to NADPH has been identified. The possible role of ferredoxincytochrome C_3 complex as an electron carrier system in the hydrogen evolution and hydrogen recycling process by     

Construction of ceo2/rgo/gce electrochemical sensor for the determination of histamine in fishEI北大核心CSCD

By preparing nano-CeO2 (CeO2) and reduced graphene oxide (RGO), an electrochemical sensor based on CeO2/RGO composite was constructed for the detection of histamine. The morphology and structure of the composites were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The electrochemical behavior of histamine on the sensor was studied by cyclic voltammetry (CV), and the conditions such as the type proportion and addition amount of the composite scanning rate and buffer pH were optimized. The results showed that the optimal conditions were as follows: The mass ratio was m(CeO2): M(RGO)=1: 0.25, the addition amount of composite material was 10 μL, the scanning rate was 300 mV/s and the pH of buffer solution was 8. A good linear relationship was observed between the peak current and the concentration of histamine in the range of 0.25–100 mg/L with the detection limit of 0.16 mg/L. The CeO2/RGO/GCE electrochemical sensor has been applied to the determination of histamine in fish samples with the spiked recoveries of 98.4% −104%. The method can be used to determine histamine content in fish products. © 2023, Youke Publishing Co.,Ltd. All rights reserved.     

冷拌冷铺乳化沥青混合料在不同应变组合下的疲劳性能研究

目的 研究在单级应变与双级应变组合的不同加载方式下冷拌冷铺乳化沥青混合料劲度模量及疲劳寿命的变化规律,为冷拌冷铺乳化沥青混合料的抗疲劳性能研究提供借鉴。方法 综合考虑车辆荷载的大小,选定A(200×10^-6)、B(400×10^-6)、C(600×10^-6)三个应变水平,以单级应变为试验对照组,以A-B和C-A为双级应变组合,对冷拌冷铺乳化沥青混合料分别进行单级及双级应变下的四点弯曲疲劳试验,由此对比分析混合料疲劳寿命与劲度模量随应变量及应变组合不同而变化的规律。结果 在单级应变作用下,试件劲度模量先急剧下降,然后缓慢衰减,且应变越大劲度模量衰减越快;在应变水平由低到高的双级应变A-B组合作用下,由A应变转入B应变加载后,劲度模量瞬间增大了35%,之后先急剧降低再进入平缓阶段,且疲劳寿命在A、B单级应变加载之间;而在应变水平在由高到低的C-A加载组合中,由C应变转入A应变加载后,劲度模量瞬时衰减11%,之后先急剧降低再进入平缓阶段,且疲劳寿命要长于在应变中值水平B单级应变加载下的。结论 从低应变到高应变的加载过程中,恢复了...     

磷酸铈对磷化镍催化苯酚转移加氢的促进作用

通过氢气原位程序升温还原法制备了一系列不同Ce/Ni摩尔比的CePO₄-Ni₃P及Ni₃P催化剂,考察了其在苯酚催化转移加氢反应的催化性能.研究了Ce/Ni摩尔比、供氢溶剂、反应温度和反应时间对催化剂性能的影响,并初步考察了苯酚转移加氢的反应动力学.研究结果表明,CePO₄的加入能显著提升体相Ni₃P催化苯酚转移加氢的转化率,且Ce/Ni摩尔比为0. 2时促进作用最显著;在所考察的供氢溶剂中异丙醇展现出最好的性能;使用Ce PO₄(0. 2)-Ni3P作为反应催化剂,异丙醇作为供氢溶剂,220℃下反应6 h,苯酚转化率和环己醇选择性分别可达93. 1%和92. 0%.     

COF固载铜盐催化苯硼酸与咪唑的Chan-Lam偶联反应

制备了一种含有联吡啶位点的共价有机骨架(COF)材料TpBpy,并通过配体上的联吡啶位点固载铜盐实现了功能化,得到的Cu@TpBpy具有大量的不饱和铜配位位点和高表面积,可用作苯硼酸与咪唑的Chan-Lam偶联反应的多相催化剂.通过优化溶剂、铜源、碱及反应时间等反应条件,发现使用质子极性溶剂MeOH时的反应产率最高,而Cu(OAc)₂@Tp Bpy是效果最佳的催化剂,可溶性有机碱三乙胺(TEA)的促进效果最好.Cu(OAc)₂@TpBpy在碱TEA的促进下于70℃催化咪唑与苯硼酸反应4 h后,得到目标产物1-苯基咪唑的最大产率为66%.在最优反应条件下进行了底物拓展,结果表明,取代基的位阻效应对催化体系影响显著,其中对位取代基的4-氯苯硼酸的产率最高(62%).