Structural Evolution of Nanostructured γ—Ni—28Fe Alloy Investigated by Using the Internal Friction Technique

The structural evolution of nanostructured γ-Ni-28Fe alloy(n-Ni-Fe)(grain size d-30nm),synthesized by the mechno-chemical method,was investigated by using the internal friction technique combined with differential scanning calorimetry(DSC) in the temperature range from 300K to 670K.An internal friction peak with typical characteristics of the first-order phase transition was observed in the vicinity of 620K,which corresponds to a broad exothermic process revealed by using DSC.Theses results can be explained as the structural changes from the disordering to the ordering transition in the n-Ni-Fe sample.     

Studies on Structure and Porperties of Water Soluble Polysaccharide from Fruiting Body of Cordyceps Militarvs(L.) Link

A water soluble crude polysaccharide has been isolated from the fruiting body of cultivated Cordyceps militarvs(L.)Link.The GC analysis indicated that it contained the monosaccharides of Gal,Man,Glc and GlcA.Their molar ratio is 1.00:1.58:7.89:0.19.The crude polysaccharide was fractionated with ethanol to get three fractions,which were CM-Ⅰand CM-Ⅲ,CM-Ⅱ was further purified to get one homogeneous fraction named CMB.The molecular weight was estimated to be 6000by means of gel filtration.CMB is a greyish white powder.The GC analysis indicated that it was composed of Gal.Man,Glc and the molar ratio is 1.00:1.38:5.10.Partial hydrolysis with an acid.periodate oxidation.Smith degradation.IR,GC and methylation analyses,GC/MS analyses were used for the structure analyses of CMB.Man,(1→6)-linked-Glc,(1→4)-linked-Glc and (1→4)-linked-Gal.Some of (1→4) -linked-Glc and all(1→4)-linked-Gal residues are substituted at 3-O and 6-O respectively,(1→4)-linked-Glc and minor(1→6)-linked-Gle.The nonreduced end is composed of Gal and Glc.The main glycosidic link of CMB is α configuration.     

An Improved Synthesis of Retinoic Acid from β-Ionone

A convenient and large-scale preparation of retinoic acid 1 from β-ionone in five steps with 38% overall yield is described.The key steps are the epoxidization of 2 with a new methylated agent and the condensation 4 with tetraethyl methylenediphophonate in one-pot procedure to prepare 6.     

阳离子道路乳化沥青改性

在不改变胺化木质素为乳化剂的道路乳化沥青的筑路工艺，装备的条件下，加入复合添加剂进行改性，保留了原乳化沥青的优点，缩短了初凝时间，提高了粘聚力和抗磨性能。     

连铸板坯外形的在线检测方法

介绍了板坯外形在线检测的测量原理，计算方法，并给出了实验测量方法，过程及计算机图像处理系统的处理结果，该方法简单，实用，精度较高。     

基于经验模式分解的希尔伯特变换包络提取在机械故障诊断中的应用

本文采用经验模式分解（EMI）提取信号的内在模函数（IMF），并利用希尔伯特变换对所得IMF进行包络分析，提取机械故障特征。与直接对原信号进行包络分析相比较，该方法提取的机械故障特征更明显，数值模拟和对故障轴承振动信号分析表明了该方法的有效性。     

硫酸钛水解制备TiO2纳米粒子载荷添加剂

以硫酸钛为前驱体，采用溶胶－凝胶－超临界干燥法制备TiO2纳米粒子润滑油载荷添加剂。采用红外光谱、BET氮容量吸附、透射电镜、热生－差热分析、X－射线衍射等手段对TiO2纳米粒子的特性进行了表征，分析了制备过程中的各种影响因素。结果表明，采用强烈搅拌、匀速滴加絮凝剂、控制反应终点的pH值以及用乙醇为介质进行超临界干燥的方法制备出的TiO2纳米粒子的平均粒径为15－20nm，比表面积约为100m%2/g，其结构为锐态型，表面有微量水和乙醇吸附。     

筒型基础系缆平台沉／拔过程侧摩阻力原型测试

介绍了1999年首次安装在渤海锦州9－3地区多筒基础平台安装施工过程中的侧摩阻力原型测试研究，描述了简型基础上沉和上拔过程中筒壁侧摩阻力的测试系统和测试方法，给出了主要测试结果并与现行规范进行了对比分析，这项成果对筒型基础平台的设计和施工具有直接的参考意义。     

生态护坡技术的试验研究

为体现环境水利的理念，美化泵站环境，引进了国外生态护坡技术.文中就太浦河泵站有关生态护坡试验研究作简要介绍.     

太浦河泵站斜15°轴伸泵水力动态力分析

太浦河泵站选用的斜15°轴伸式轴流泵(以下简称斜15°轴伸泵)，为特低扬程、大流量的水泵.它具有叶轮直径大、水泵装置流态复杂、水泵轴承受力大等特点.为此，针对太浦河泵站斜15°轴伸泵，进行了水泵装置从吸入口至出口包括叶片、导叶、弯管段等在内的整体三维粘性流动分析，得到了流道内部不同工况下的流动特性如压力、速度分布规律及泵特性曲线，以及流道内部的旋涡分布和水力损失情况.同时进行了导叶和叶轮流动动静干涉引起的三维不稳定流动分析，得到了叶轮在不同工况下受到的轴向水推力及径向水推力在旋转过程中的变化规律，从而为轴承设计提供了比较准确的受力条件.该项研究对其他斜式泵的内部流态及受力分析也是一个很好的借鉴.