基于FT-ICR质谱仪的光解离光谱自动化谱图采集程序的开发与应用

光解离光谱在气相离子结构及动力学研究中发挥着重要的作用.这种方法非常灵活,可在实验室中利用不同种类的激光器及质谱仪的结合来开展相应的研究.但也存在一些问题,例如,自动化水平低,费时,长时间的操作容易引入人为错误,使实验结果的可信度降低.为解决此类问题,该工作开发了一套可用于光谱自动采集和分析的程序AutoMS.该程序包...     

细颗粒湍流聚并的分区法群平衡模拟

通过聚并促进细颗粒(PM2.5)特别是亚微米颗粒(PM1.0)团聚长大或被大颗粒捕集,是提高其脱除效率的有效方法之一.本文采用分区法对燃煤电厂尾部烟气中飞灰的聚并进行了群平衡模拟研究.利用圆柱阵列实现的湍流聚并装置,圆柱横向间距为4倍直径时,纵向间距宜在圆柱直径的15～30倍之间,在工程上较为可行的条件下,对于PM1....     

一类六参数非协调任意凸四边形单元

本文构造了一类六参数非协调四边形单元,证明由此产生的有限元对任意四边形网格通过Irons分片检查,其收敛效果同Wilson元相当且形状函数的选择不依赖于单元本身。类Wilson元及改进的Wilson任意四边形单元是其中的特例。     

具有几何对称性的12参数矩形板元

1 引言 三角形板元中,形式最简单的是九参数元,节点参数是单元三个顶点上的函数值和两个一阶偏导数值,非协调九参三角形板元的研究取得了丰硕成果,根据不同方法已构造出多种收敛性能好的单元.相比之下,矩形板元的研究较少见报道.矩形板元中形式最简单的是12参元,节点参数是单元4个顶点上的函数值和两个一阶偏导数值,这类似于九参三角形板元.常见的12参矩形板元是ACM元,其形函数空间是完整3次多项式空间加上两个4次多项式的基函数,ACM元是C°元,但位移形函数的外法向导数平均值在单元间不连续,这类似于Zienkiewicz九参三角形板元,但由于矩形单元的特殊形状,ACM元是收敛的.龙驭球教授等在[1]中提出一种12参矩形广义协调元,其位移形函数的外法向导数平均值在     

A design of resonant cavity with an improved coupling-adjusting mechanism for the W-band EPR spectrometer

We report a new design of resonant cavity for a W-band electron paramagnetic resonance (EPR) spectrometer. An improved coupling-adjusting mechanism, which is robust, compact, and suits with both solenoid-type and split-pair magnets, is utilized on the cavity, and thus enables both continuous-wave (CW) and pulsed EPR experiments. It is achieved by a tiny metal cylinder in the iris. The coupling coefficient can be varied from 0.2 to 17.9. Furthermore, two pistons at each end of the cavity allow for adjustment of the resonant frequency. A horizontal TE₀₁₁ geometry also makes the cavity compatible with the two frequently used types of magnets. The coupling-varying ability has been demonstrated by reflection coefficient (S₁₁) measurement. CW and pulsed EPR experiments have been conducted. The performance data indicates a prospect of wide applications of the cavity in fields of physics, chemistry and biology.     

Photoluminescence of green nanophosphors Sr2MgSi2O7 doped with Tb3+ under 374-nm excitation

A series of Sr₂MgSi₂O₇:Tb³⁺ nanophosphors is prepared using a high-temperature solid-state reaction. The x-ray diffraction patterns show that the crystal structure of the sample is not significantly affected by Tb³⁺ ions. However, the images of the scanning electron microscope illustrate that the average size of nanoparticles becomes larger with the increase of Tb³⁺ concentration. Unlike earlier investigations on down-conversion emission of Tb³⁺ ion excited by deep ultraviolet light, in this work, the photoluminescence characteristics of Sr₂MgSi₂O₇ nanophosphors doped with different Tb³⁺ concentrations are analyzed under 374-nm excitations. The intense green emission at 545 nm is observed at an optimal doping concentration of 1.6 mol%. The main reason for the concentration quenching is due to the electric dipole-electric dipole interaction among Tb³⁺ ions.     

Steady State Entanglement and Saturation Effects in Correlated Spontaneous Emission Lasers

It has recently been shown that correlated spontaneous emission lasers （CEL） exhibit transient entanglement in the linear regime. Here we re-examine the quantum correlations in two-photon CEL and explore the saturation effects on continuous variable entanglement. It is shown that the steady state entanglement is obtainable in the weak or moderate saturation regime, while is washed out in the deep saturation regime.     

天鹅绒阴极产生的双脉冲强流相对论电子束特性实验研究

在时间分辨的模式下, 实验研究了天鹅绒阴极产生的双脉冲相对论强流电子束的束心运动、束包络和束的发射度. 在实验中, 电子束流强度和电子束心运动用电阻环进行测试, 而电子束和石英玻璃的相互作用产生的契仑科夫辐射用来给出电子束包络和发射度信息. 电子束和石英玻璃作用产生的契仑科夫辐射用1台8幅分幅相机记录. 实验结果表明, 天鹅绒阴极产生的相对论强流双脉冲电子束在束流大小、束心运动轨迹、束包络及束发射度等方面具有较好的一致性.     

SrTiO3金属-绝缘体-半导体结构的介电与界面特性

采用金属有机分解法在p型Si衬底上制备了SiTiO3(STO)薄膜.研究了STO薄膜金属-绝缘体-半导体(MIS)结构的介电和界面特性.结果表明,STO薄膜显示出优异的介电性能,在10kHz处的介电常数约为105,损耗低于0.01,这来源于多晶结构和良好的结晶性;MIS结构中的固定电荷密度Nf和界面态密度Dit分别约为1.5×1012cm-2和(1.4-3.5)×1012 cm-2 eV-1,这主要与Si/STO界面处形成的低介电常数界面层有关.     

亚微秒脉冲下高梯度绝缘子的沿面闪络特性

介绍了一种由聚酰亚胺和不锈钢叠加而成的高梯度绝缘子的实验研究工作。该绝缘子样品的直径60 mm,厚度8 mm,在脉冲宽度120 ns(FWHM)的电压脉冲加载下最高获得了接近13 MV/m的绝缘强度。研究了测试方法以及绝缘层厚度与金属层厚度的比例对高梯度绝缘子绝缘强度的影响,并与相同尺寸的普通材料绝缘子的绝缘强度进行了对比。结果表明,高梯度绝缘子的绝缘强度明显高于仅由聚酰亚胺构成的普通绝缘子。