ICP－AES中基体元素对硫的光谱干扰（Ⅱ）

ＩＣＰ－ＡＥＳ中基体元素对硫的光谱干扰（Ⅱ）卢汉兵张保军，魏路线（武汉华中师范大学分析测试中心，武汉，４３００７０）（武汉工学院微观分析中心）关键词电感耦合等离子体发射光谱，光谱干扰，硫ＩＣＰ－ＡＥＳ中，由于对２００ｎｍ以下的光谱干扰研究工作报道极少...     

Ce^3＋和Eu^2＋共激活氯硅酸锌钙的光谱和敏化特性

合成了Ｃｅ＾３＋和Ｅｕ＾２＋共激活的氯硅酸锌钙「Ｃａ８Ｚｎ（ＳｉＯ４）４Ｃｌ２：Ｃｅ＾３＋，Ｅｕ＾２＋」绿色荧光粉，并报道了它们的漫反射光谱，激光发光谱及发射光谱，观测到氯硅酸锌钙中Ｃｅ＾３＋对Ｅｕ＾２＋离子发光的显著敏化现象。阐述了氯硅酸锌钙中Ｃｅ＾３＋和Ｅｕ＾２＋发光作用缘于Ｃｅ＾３＋和Ｅｕ＾２＋之间的高效无辐一传递。     

Preparation and characterization of star ABC triblock copolymer of ethylene oxide,styrene and methyl methacrylate

A universally significant method,which combines the anionic polymerization with photoinduced charge transfer polymerization,for preparation of soluble star ABC triblock copolymer of ethylene oxide,styrene and methyl methacrylate,was described.The poly(ethylene oxide) (PEO) block was formed by initiation of phenoxy an-ions using p-aminophenol protected by Schiff's base as the parent compound Then the charge transfer system composed of PEO chains with deprotected-amino end groups and benzophenone initiated the polymerization of styrene and methyl metnacrylate sequentially under UV irradiation.The formed star triblock copolymer of styrene,ethylene oxide and methyl methacrylate could be purified by thin-layer chromatography (TLC) and characterized by IR,1H NMR,GPC (gel permeation chromatogrphy) and PGC (pyrolysis gas chromatography).     

Syntheses of Some New Group 4 non-Cp Complexes Bearing Schiff-base, Thiophene Diamide Ligands Respectively and Their Catalytic Activities for a-Olefin Polymerization

Totally sixteen new titanium and zirconium non-Cp complexes supported by Schiff-base, or thiophene diamide ligands have been synthesized. The complexes are obtained by the reaction of M(OPr-i)4(M=Ti,Zr) with the corresponding Schiff-base ligand in 1:1 molar ratio in good yield. The thiophene diamide titanium complex has been prepared from trimethylsilyl amine [N,S,N] ligand and TiCl4 in toluene at 120℃. All complexes are well charac-terized by ^1H NMR, IR, MS and elemental analysis. When activated by excess methylaluminoxane (MAO), complexes show moderate catalytic activity for ethylene polymerization, and complex If (R^1=CH3,R^2=Br) exhibits the highest activity for ethylene and styrene polymerization. When the complexes were preactivated by triethylaluminum (TEA), both polymerization activities and syndiotacticity of the polymers were greatly improved.     

振动加速度级峰值技术条件(草案)制订

根据试验研究结果 ,制订深沟球轴承振动加速度级峰值技术条件 (推荐 ) ,目的是规范轴承异常声的检测 ,通过试验验证 ,该技术条件能够比较客观的评定轴承的噪声 ,具有重要的实用价值。     

Zr-Al-Ni-Cu系统中非晶合金

Zr-Al-Ni-Cu系及共亚组元体系中非晶合金是由二元合金系开始，发展到今日的四元和五元合金，其形状也从薄带、丝等发展为块体，以源自准晶的等电子浓度理论和等原子尺寸理论为判据设计合金成分，并制备了系列大块非晶合金，它们的△Tx在100k左右，同时具有大的约化玻璃转变温度Trg。     

基于多特征融合和窗口搜索的新型车道线检测算法

针对现有车道检测算法准确性和实时性较难平衡的问题,提出了一种基于多特征融合和窗口搜索的新型车道线检测算法.采用多边形填充方法确定车道线的感兴趣区域(region of interest, ROI),融合车道线的颜色、直方图和梯度特征,以消除ROI中的复杂背景.通过单应性变换得到车道线的二值图像,基于其像素密度分布寻找车道线初始位置,以窗口搜索方式提取整个车道线上的所有候选像素点.通过拟合像素点构建车道线数学模型.结果表明：提出的算法具有较高的准确性和实时性,算法对黄色车道线、树木阴影遮挡、光照变化、车道线缺损和地面交通标志干扰具有较好的鲁棒性.     

基于随机均衡配流的O-D量估计双层规划模型及算法

在传统随机均衡配流模型的基础上,提出了一种增广的随机用户均衡配流模型及其求解算法。在此基础上构造了一个双层规划模型,用以描述基于随机用户均衡原则的从路段观测流量估计O-D交通量的问题,并给出了相应的求解算法。该模型及其求解算法对于解决O-D估计问题是可行有效的。     

北秦岭柳树湾花岗伟晶岩型铀矿床流体包裹体和氢-氧-硫同位素研究

河南省柳树湾花岗伟晶岩型铀矿床位于北秦岭东段,含矿伟晶岩受灰池子岩体与秦岭岩群的接触带控制。通过对研究区的地质特征、流体包裹体以及氢-氧-硫同位素的研究,探讨柳树湾花岗伟晶岩型铀矿床的成矿物质、流体来源。伟晶岩型铀矿成矿流体温度为513.5℃～567.4℃,H同位素为-107.9‰～-89.6‰,O同位素为11‰～13.2‰,S同位素为3.5‰～5.8‰。研究结果表明：柳树湾花岗伟晶岩型铀矿床成矿流体主要为深部岩浆水,成矿物质主要来自深部岩浆。     

激光陀螺正逆光束损耗差对零位漂移的影响研究

激光陀螺长时间工作过程中零位保持不变对于捷联惯导有重要意义。介绍了影响激光陀螺零位的主要因素之一,并分析了导致激光陀螺长时间工作过程中产生零位漂移的机理。实验发现,激光陀螺连续工作1个月,由正逆时针光束损耗差引入的零位漂移在0.005 3°/h左右,伴随正逆时针损耗差变化8%左右。损耗差对激光陀螺零位的影响是长期的、缓慢的。若需要减小激光陀螺长期工作的零位漂移,则应当提高正逆行波损耗差的长期稳定性。