卡尔曼 波—分光光度法用于复方雷锁辛涂剂中苯酚与间苯二酚的测定

本文研究了卡尔曼滤波－分光光度法及其在多组分混合物同时光度测定中的应用。测定复方雷琐辛涂剂中苯酚与间苯二酚，平均回收率分别为100.86％与98.76％。     

ZK—4、NaANaHS3种沸石的铝化

用高温气－固相置换法对ZK－4、NaANaHS3种沸石进行铝化。组成分析、尾气分析、X射线衍射、晶体形貌分析、红外光谱和^29Si高分辨魔角固体核磁结果表明，3种低硅铝比沸石铝化后骨架可能存在Al-O-Al键。     

SYNTHESIS AND MOLECULAR STRUCTURE OF METHYL 1—BENZYL—6—PHENYLPIPERIDIN—2—ONE—5—CARBOXYLATE

<正> C20H21NO3,Mr=323.39,monoclinic, space group P21, a= 7. 338(2), b=15. 419(3),c=7. 515(1)A,β=95.98(1)°,V= 845. 7(2)A3,Dm(flotation in aq. KL)=1.267,Dx(Z=2)=1.270gcm-3,λ(MoKα)=0.71069A,μ=0.08cm-1,F(000)=344,T=295°K,final RF=0. 042 for 1651 observed reflections. The title compound was synthesized and established as the trans isomer, with the phenyl and carbomethoxy substituents occupying pseudo-axial and axial positions, respectively, of the piperidin-2-one ring in a half-chair conformation.     

CRYSTAL AND MOLECULAR STRUCTURE OF N—ETHYLPHENOTHIAZINE RADICAL CATION HEXACHLOROANTIMONATE EPT^＋SbCl6^—

<正> C14H13Cl6NSSb, Mr =561.8, Monoclinic, C2/c1 8=15,32(1), b= 11.72(1), c= 11.10(1)A,β=99.31(3)°,V=1969(1)A3,Dc=1,902g.cm-3, Z=4,CuKα,λ=1.5418A,μ=200.95cm-1.Room temperature, final R=0.051 for 1197 unique reflections with I>, 3.0σ(I).Pronounced defornation of the Molecular structure has been observed when the neutral N-ethylphenothia-zine is transformed into its radical cation. The structural features of the radical cation are compared with those of N-methyl analogue.     

SYNTHESIS AND STRUCTURE OF A NEW TYPE OF COORDINATION COMPOUND OF Tb（Ⅲ）WITH BENZOIC ACID

<正> The synthesis and crystal structure of a novel rare earth coordination compound are reported. [TbL3(HL)H2O]2 (HL=henzoic acid) Mr=1324. 81, triclinic, space group P1, a=9. 148(1), b=11. 4 60(2), c=13. 506(2) A ;a=112. 76(1), B=91.83(1),y=91. 99(1) ;Z=1 ;V=1303. 3(4)A3;Dc=1.69g.cm-3;F(000)= 656;u=28. 4cm-1(MoKa). The final R is 0. 024. Each rare-earth ion in the title complex is nine-coordinated by seven oxygen atoms from five benzoate groups, one benzoic acid, and one aqua molecule, forming a distorted monocapped square antiprism.