功能化微纳米硅胶表面亚铁配位化学及其催化降解邻苯二酚的性质

含吡啶硫醚有机分子功能化的微/纳米硅胶粒子利用表面有机分子分别与氯化亚铁和硫酸亚铁发生配位作用, 制得两种功能化材料, 即Fe^C@L-NSiG和Fe^S@L-NSiG。采用红外光谱(FTIR)、紫外可见吸收光谱(UV-Vis)、热重(TGA)和扫描电镜(SEM)对这两种材料进行了表征;同时对材料表面Fe(Ⅱ)可能的配位化学性质以及其催化双氧水氧化降解邻苯二酚的性能进行了研究。为了探究两种材料表面上亚铁中心的配位化学性质, 合成了类似于功能化微/纳米硅胶表面上的有机官能团(吡啶硫醚)的含“NS”杂原子的配体L, 即2-((乙基硫代)甲基)吡啶。配体L与FeCl₂反应后得到配合物[Fe(L)₂Cl₂], 通过X-射线单晶衍射方法测定了它的晶体结构, 并将该配合物作为对照物进行研究。结果表明:Fe^S@L-NSiG表现出更高的催化效果, 几乎是Fe^C@L-NSiG的两倍。与材料Fe^C@L-NSiG相比, Fe^S@L-NSiG的催化效率上升是由于其表面上Fe(Ⅱ)中心含有更多的易离去配体(溶剂分子或水分子), 从而使底物更容易接近金属中心。     

基于席夫碱配体的锰羰基配合物可见光诱导释放一氧化碳性能

利用五羰基溴化锰和2-吡啶甲醛以及卤代苯胺通过一步法合成得到了3个含席夫碱配体的锰羰基配合物[Mn(CO)₃(py(CH=N)ph-X)Br],其中X=Cl (1)、Br (2)、I (3),并采用核磁、X射线单晶衍射、红外光谱、紫外可见光谱和荧光光谱对其进行了表征。这类配合物在非光照下稳定,在可见光(LED蓝光、绿光和红光)作用下分解释放CO,可以作为光诱导的一氧化碳释放剂(photoCORMs)。研究表明蓝光是促进配合物分解释放CO的最有效光源。此外,CO释放动力学分析显示配合物分解释放CO过程符合一级动力学模型。配合物3的释放研究表明脱氧肌红蛋白能够捕捉所释放的CO。尽管这些配合物本身的细胞毒性(IC50)达到微摩尔级,但光照下的细胞兼容性有显著改善,上升为接近100微摩尔级。这些配合物具有荧光性质,在450 nm激发波长下在500～700 nm范围内发射一定强度的荧光,可以作为荧光标记物用以监测细胞或生物体内释放剂分布及CO释放情况。     

山地城市交叉口车辆纵行运行特性

为研究车辆在山地城市道路交叉口停车减速阶段的运行特性,利用无人机采集了某山地城市道路交叉口的高空视频数据。基于云平台DataFromSky AI,采用Lucas-Kanade和背景差分等算法提取视频中车辆的速度和加速度等数据。按照不同坡度类型,分析停车减速过程中速度变化特征、停车点位置分布规律等运行特性。结果表明：在不同坡度路段,越靠近停止线的车辆其截面初速度越大,离散程度越高;停止线位置处的速度均与停车距离具有较强的正相关性;上坡路段车辆截面初速度、减速率和速度降幅均小于下坡路段;车辆与停止线距离越近,其停车位置点分布越集中;下坡路段车辆停车点位置更分散,分布的区间也较大,停车距离也逐渐增大。本次研究结果可以为山地城市道路交叉口仿真模型参数标定与修正等方面提供理论支撑和数据支持。     

考虑信号控制影响的低频浮动车路径估计

针对低频浮动车中相邻GPS匹配点跨越多个路段的路径估计问题,考虑信号控制以及其他影响绕行的因素,建立最优路径的层次分析模型。首先,选取评价指标进行模糊等级划分;其次,利用各指标间的判断矩阵和权系数向量得到各路段阻抗因子;最后,以路段阻抗代替路段长度,利用Dijkstra搜索算法找到最"短"路径,判定为浮动车驾驶者最可能的行驶路径。以北京市石景山区实际车辆GPS数据为例,选取其中跨越多路段的GPS点进行分析,所得路径估计结果与该车实际行驶路径相一致。     

A Tunable Acousto-Optic Fiber Filter Based on Two Simultaneous Mode Coupling Processes

A dynamically tunable fiber filter realizing complex spectra of phase-shifted long period fiber gratings （LPFGs） is proposed and demonstrated experimentally. The principle of the filter is based on two acousto-optic coupling processes occurring simultaneously. The first coupling process acts as a normal LPFG, while the second makes the coupling direction of the first process change continuously, leading to a similar transmission spectrum with the phase-shifted LPFGs, in which the changing of coupling direction is realized by the discrete phase shifts of the index modulation. By adjusting the acoustic tuned to realize the phase-shifted LPFGs＇ spectra drive signals, its transmission spectrum can be dynamically under different phase shift numbers and locations.     

单向拉伸作用下Cu(100)扭转晶界塑性行为研究

应用分子动力学方法研究了在不同扭转角度下的Cu（100）失配晶界位错结构,以及不同位错结构对晶界强度的影响.模拟结果表明：小角度扭转晶界上将形成失配位错网,失配位错密度随着晶粒之间的失配扭转角度的增加而增加.变形过程中,位错网每个单元中均产生位错形核扩展.位错之间的塞积作用影响晶界的屈服强度：随着位错网格密度的增加,位错之间的塞积作用增强,界面的屈服强度得到提高.大角度扭转晶界将形成面缺陷,在变形中位错由晶界角点处形核扩展,此时由于面缺陷位错开动应力趋于一致,因此晶界的临界屈服强度趋于定值. 关键词： 扭转晶界 失配位错网 强化机理 分子动力学     

Improving spatial resolution in fiber Raman distributed temperature sensor by using deconvolution algorithm

The deconvolution algorithm is adopted on the fiber Raman distributed temperature sensor （FRDTS） to improve the spatial resolution without reducing the pulse width of the light source. Numerical simulation shows that the spatial resolution is enhanced by four times using the frequency-domain deconvolution algorithm with high temperature accuracy. In experiment, a spatial resolution of 15 m is realized using a master oscillator power amplifier light source with 300-ns pulse width. In addition, the dispersion-induced limitation of the minimum spatial resolution achieved by deconvolution algorithm is analyzed. The results indicate that the deconvolution algorithm is a beneficial complement for the FRDTS to realize accurate locating and temperature monitoring for sharp temperature variations.     

融合事件信息的复杂问句分析方法

问答系统中的复杂问句通常涉及很多事件信息,正确处理其中的事件内容对提高系统准确率有重要的影响.为此,文中提出了一种融合事件信息的复杂问句分析方法.该方法将事件视为由多个要素构成的复杂数据对象,从而定义了事件的语义表征模型,给出了相似度计算方法.文中首先利用相关的事件抽取方法获取复杂问句中的事件信息,生成事件的语义模型实...     

A novel control method for on-off gain and gain tilt of fiber Raman amplifiers

Considering spectrum tilt due to signal-to-signal Raman scattering (SSRS) in backward distributed fiber Raman amplifiers (B-DFRA), an inverse tilted on-off gain profile is adopted to achieve flat net gain. A simple approximate linear relationship of pump power at each wavelength versus on-off gain level and tilt was derived numerically and experimentally so that a novel control method was established. Since there are only 3 pre-determinable constants required for individual pump wave, it is easy to be realized. As an example, maximum errors less than 0.2 and 0.4 dB respectively for average gain and gain tilt were achieved over C+L band in 100-km back-pumped standard single-mode fiber (SMF) experimentally.     

Numerical comparison on the characteristics between backward and bi-directionally pumped DFRAs in hybrid Raman/EDFAs

The characteristics of broadband backward and bi-directionally pumped distributed fiber Raman amplifiers (DFRAs) in hybrid Raman/erbium-doped fiber amplifiers (HFAs) configuration are compared numerically based on noise-nonlinear figure (NNF) when standard single mode fiber (SMF) and non-zero dispersionshifted fiber (NZDSF) are considered. It is found that achievable NNF in optimized bi-directionally pumped HFAs is about 1.2 dB (or 1.7 dB) higher than that in backward pumped HFAs for SMF (or NZDSF), and better characteristics can be achieved by using NZDSF rather than SMF for long haul transmission.