5(6)羧基荧光素敏化TiO2纳米粒子的光致电子转移的荧光特性研究

通过水解TiCl₄制备了锐钛矿结构TiO₂纳米粒子, 并用时间分辨荧光光谱研究了5(6)CFL(5(6)-Carboxyfluorescein, 简称5(6)CFL)染料敏化TiO₂纳米粒子体系的光致电子转移动力学. 5(6)CFL染料敏化TiO₂纳米粒子能形成电荷转移复合物, 这归因于染料分子的激发电子态波函数Ψ(D^*)与电荷分离态波函数Ψ(D⁺ +e^-)之间的耦合作用. 当激发5(6)CFL染料敏化TiO₂纳米粒子体系时, 电子以两种不同方式注入TiO₂纳米粒子导带: 第一, 通过5(6)CFL染料分子的激发态注入; 第二, 从电荷转移复合物(5(6)CFL/TiO₂)直接注入. 时间分辨荧光光谱表明, 在水溶液中纯5(6)CFL染料的荧光以寿命为τ₁=41 ps (74.4%) 和τ₂=3.22 ns (25.6%) 的双e指数衰减, 而5(6)CFL染料敏化TiO₂纳米粒子体系的荧光分别以时间常数为τ₁=44 ps (90.4%), τ₂=478 ps (8.6%) 和τ₃=2.41 ns (1.0%) 的三e指数衰减. 本文的研究工作能够为染料敏化太阳能电池的光致电子转移机理提供有价值的参考.     

Quantum and semiclassical studies on photodetachment cross sections of H~- in a harmonic potential

The photodetachment cross section of H~- in a linear harmonic oscillator potential is investigated. This system provides a rare example that can be studied analytically by both quantum and semiclassical methods with some approximations. The formulas of the cross section for different laser polarization directions are explicitly derived by both the traditional quantum approach and closed-orbit theory. In the traditional quantum approach, we calculate the cross sections in coordinate representation and momentum representation, and get the same formulas. We compare the quantum formulas with closed-orbit theory formulas, and find that when the detachment electron energy is larger than3/2hω, where ω is the frequency of the oscillator potential, the quantum results are shown to be in good agreement with the semiclassical results.     

节理化炭质页岩地层隧道围岩大变形及控制技术研究

某高速铁路XHS隧道穿越节理化炭质页岩地层,在施工过程中围岩大变形、失稳坍塌现象显著,现场采用强支护和仰拱加深等措施后围岩变形控制效果不佳。针对XHS隧道节理化炭质页岩地层地质条件,结合现场监测手段、离散-连续耦合数值模拟分析围岩大变形及破坏特征,基于数值模拟提出以采取地层预加固为主的围岩变形控制措施,并通过现场试验探讨该控制措施的应用效果。研究结果表明：隧道开挖后,围岩变形具有变形量大、变形速率快的特点,围岩拱部沉降量大于水平收敛量且变形具有非对称的分布特征;受三台阶法多次开挖扰动影响,围岩卸荷范围动态发育并不断向全环扩展,松动区逐渐由浅部围岩向深部转移,并呈现出非对称的破坏特征,最终引发围岩大变形;采取地层预加固后,模型中围岩变形和松动区范围明显减小,围岩非对称变形破坏也得到了有效控制;在采用地层预加固、管棚超前支护、三台阶临时仰拱法开挖的控制措施后,围岩变形得到控制,施工效果良好,隧道恢复正常施工,保证了隧道的顺利贯通;以地层预加固为主的控制措施是此类节理化炭质页岩地层围岩变形控制的有效手段。     

Photo-induced intramolecular electron transfer and intramolecular vibrational relaxation of rhodamine 6G in DMSO revealed by multiplex transient grating spectroscopy

Photo-induced intramolecular electron transfer （PIET） and intramolecular vibrational relaxation （IVR） dynamics of the excited state of rhodamine 6G （Rh6G＋） in DMSO are investigated by multiplex transient grating. Two major compo- nents are resolved in the dynamics of Rh6G＋. The first component, with a lifetime τTPIET = 140 fs-260 fs, is attributed to PIET from the phenyl ring to the xanthene plane. The IVR process occurring in the range ZIVR = 3.3 ps-5.2 ps is much slower than the first component. The PIET and IVR processes occurring in the excited state of Rh6G＋ are quantitatively determined, and a better understanding of the relationship between these processes is obtained.     

Effect of Pressure on Absorption Spectra of Lycopene in n-Hexane and CS2 Solvents

The absorption spectra of lycopene in n-hexane and CS2 are measured under high pressure and the results are compared with β-carotene. In the lower pressure range, the deviation from the linear dependence on the Bayliss parameter （BP） for β-carotene is more visible than that for lycopene. With the further increase of the solvent BP, the 0-0 bands of lycopene and β-carotene red shift at almost the same rate in n-hexane; however, the 0-0 band of lycopene red shifts slower than that of β-carotene in CS2. The origins of these diversities are discussed taking into account the dispersion interactions and structures of solute and solvent molecules.     

二甲基亚砜溶剂中All-trans-astaxanthin的拉曼和红外光谱

The Raman and infrared spectra of all-trans-astaxanthin (AXT) in dimethyl sulfoxide (DMSO) solvent were investigated experimentally and theoretically. Density functional cal-culations of the Raman spectra predict the splitting of the υ₁ band into υ_1-1 and υ_1-2 compo-nents. The absence of splitting in Raman experimental spectra is ascribed to the competition between the two symmetric C=C stretching vibrations of the backbone chain. The υ₁ band is very sensitive to the excitation wavelength: resonance excitation stimulates the higher-frequency υ_1-2 mode, and off-resonance excitation corresponds to the lower-frequency υ_1-1 mode. Analyses of the intramolecular hydrogen bonding between C=O and O-H in the AXT/DMSO system reveal that the C4=O1...H1-O3 and C4''=O2...H2-O4 bonds are strengthened and weakened, respectively, in the electronically excited state compared with those in the ground state. This result reveals significant variations of the AXT molecular structure in different electronic states.     

DMSO溶剂中All-trans-astaxanthin激发态的飞秒时间分辨光谱

基于飞秒时间分辨瞬态吸收和多元瞬态光栅光谱技术对全反式Astaxanthin(AXT)在DMSO溶剂中的超快激发态弛豫动力学进行了观测.结果表明,光激发后AXT/DMSO体系直接发生S_0→S_2跃迁,基态漂白对应光谱范围为420~550nm.由S_2→S_1的内转换过程发生的时间常数为120~160fs.S_1态激发态吸收对应的光谱范围为550~740nm,基态漂白恢复过程对应的是S_1→S_0的内转换过程,其时间尺度为4.50~5.50ps.     

水溶性CdTe量子点的稳态和纳秒时间分辨光致发光光谱

报道了以飞秒脉冲激光为激发光源的水溶性CdTe量子点(QDs)的稳态荧光光谱和纳秒时间分辨荧光光谱.实验发现CdTe量子点的荧光光谱峰值位置随激发波长变化发生明显移动，激发脉冲波长越长，荧光峰位红移越大.荧光动力学实验数据显示，在400nm和800nm脉冲激光激发下，水溶性CdTe量子点的荧光光谱中均含有激子态和诱捕态两个衰减成分，两者的发射峰相距很近，诱捕态的发射峰波长较长.在800nm脉冲激光激发下的诱捕态成分占总荧光强度的比重比400nm激发下的约高3倍，其相对强度的这种变化导致了稳态荧光发射峰位的红移. 关键词： CdTe 量子点 时间分辨 荧光光谱 上转换荧光     

考虑现实因素的模糊多目标投资组合策略

真实金融市场上的红利和税收等现实因素对投资者的决策活动有着直接的影响.考虑风险资产的红利、税收及交易费用等因素及最小交易单位与投资比例边界等约束,将每个风险资产的收益率和红利率视为梯形模糊数,以最大化投资组合净收益的期望与偏度、最小化其下半方差与模糊性为目标函数,建立了带红利和税收的模糊多目标投资组合优化模型.然后,采...     

IT产业集群的形成机制研究

一个国家信息产业的发展直接影响到其国民经济的发展,发达国家和发展中国家信息产业的实践证明信息产业集群对发展信息产业的重要作用,结合产业集群理论和信息产业本身特点研究信息产业集群的形成机制,可以促进信息产业集群的形成和发展。