Synthesis of New Spiropyrans With a Polyaromatic or Heteroaromatic Pendant and Their Photochromic Bedhaviors

A series of spiropyrans with a polyaromatic or heteroaromatic pendant was synthesized conveniently.Their photochromic behaviors were investigated with the aid of absorption spectral measurements.The results indicated that the compounds with the same parent spiropyran but different aromatic pendant show significantly different photochromic properties.This may be due to the π-π orbital interaction between the polyaromatic pendant and the open photomerocyanine form of spiropyran.The results obtained are very useful in the molecule design area.     

THE EFFECT OF PHOTO-CROSSLINKING ON THE ORIENTATION STABILITY OF POLYVINYL ALCOHOL CONTAINING 4-NITRO-4′-ALKOXYSTILBENE AND CINNAMYL PENDENT GROUPS*

Crosslinking is one of the effective routes for improving the orientation stability of poledpolymer films. The derivative of polyvinyl alcohol containing 4-nitro-4'-alkoxystilbene andphoto-crosslinkable cinnamyl groups as side chains has been synthesized. The in-situ simul-taneous photo-crosslinking poling of synthesized polymer films has been performed. Thesecond order nonlinear optical coefficient d_(33) of poled film is 11 pm/V. The SHG mea-surements show that the break-over temperature of SHG signal is raised obviously afterirradiation, its orientation stability is doubled as compared with that of non-crosslinkingsamples.     

DNA与中性红相互作用电化学和光谱研究

利用电化学和光谱方法研究中性红和DNA的相互作用,根据其循环伏安曲线和紫外-可见光谱,在pH=7.05缓冲体系中中性红与DNA发生了嵌插作用.     

混凝土强度检测抽样系统

具体介绍了砼强度检测抽样的几种方法:现行规程抽样法;简单随机抽样法;分层抽样法．分层抽样 法又分一般方式分层抽样,比例分配分层抽样,及最优分配和奈曼分配分层抽样．在理论上得到各方法的 抽样数量值的基础上,发展了一个混凝土强度检测抽样系统．软件采用Microsoft Visual Basic 6．0编制,软件 应用简单、方便快捷,并通过实例介绍软件的使用方法．     

静压预制管桩施工技术

分析静压预制管桩的优点,总结静压预制管桩的施工步骤及施工要点,并提出静压预制管桩的局限性。     

基于PRO/ENGINEER的WFCAD系统菜单的开发

运用Pro Engineer软件开发了WFCAD(WeldingFixturesandJigsComputerAidedDesign)系统的菜单 ,以第一、二类杠杆 铰链焊接工装夹具为设计对象 ,就如何采用Pro Engineer的用户化工具包Pro Toolkit的开发步骤和使用方法进行了介绍 ,实现了第一、二类杠杆 铰链焊接工装夹具的计算机辅助设计 .     

一种基于属性抽取与整合的Petri网模型

将感觉神经检测机制融合于Petri网中，提出了一种新的基于属性抽取与整合的感觉神经检测Petri网模型，使得Petri网更加适合于对神经思维的描述，提高了系统的智能行为。     

高含水硫酸铝的微波脱水研究

研究了水合硫酸铝微波脱水的动力学，测定了水合硫酸铝在微波场中的升温性能，根据微波加热过程的特点，指出了水合硫酸铝微波脱水的非等温动力学模型，并与常规脱水进行了比较。     

农地承包权的历史考察及法律问题

随着《农村土地承包法》的颁布,农村土地承包经营权的相关问题再一次成为法学界争论的焦点。土地承包经营权是农村家庭联产承包责任制在法律上的具体体现,是具有中国特色的一种新型权利。通过对土地承包经营权的历史性考察,可以对我国土地承包经营权相关立法和司法提供参考。     

纳米TiO2的制备及光催化性能

采用RF-PCVD法，以TiCl4 O2为反应体系，制备出了球状纳米级TiO2粉体。经TEM，XRD，BET测试表明，粉体为锐钛型金红石型的混晶体，粒径范围为20-60nm，平均粒径45nm。苯酚降解实验表明，TiO2粉体具有明显的光催化活性，并就光催化效率与德国产TiO2进行了比较。