二氧化钛太阳能电池减反射膜结构和光学特性

用溅射功率为100～500 W的直流反应磁控溅射法制备出不同结构与特性的TiO2薄膜样品;采用原子力显微镜(AFM)、X线衍射仪(XRD)、傅里叶红外光谱(FTIR)和紫外可见光分光光度计对薄膜的形貌、结构及光学特性进行表征;研究溅射功率对薄膜的结构、形貌及光学特性的影响.研究结果表明:沉积态薄膜均为无序结构,氧化物溅射模式下沉积的薄膜为透明状态,金属模式下沉积的薄膜不透明,TiO2薄膜的折射率随着溅射功率变化在1.8～2.3之间变化;在低功率制备的沉积态薄膜存在TiO0.5微晶,它使薄膜样品的透过率降低,这主要是TiO0.5微晶对光波的强烈吸收所致;400 W溅射功率下制备出适合太阳能电池减反射膜应用的透过率高及折射率大的TiO2减反膜.     

Sub-stochiometric MoOx by radio-frequency magnetron sputtering as hole-selective passivating contacts for silicon heterojunction solar cells

The silicon heterojunction (SHJ) solar cell has long been considered as one of the most promising candidates for the next-generation PV market. Transition metal oxides (TMOs) show good carrier selectivity when combined with c-Si solar cells. This has led to the rapid demonstration of the remarkable potential of TMOs (especially MoO_x) with high work function to replace the p-type a-Si:H emitting layer. MoO_x can induce a strong inversion layer on the interface of n-type c-Si, which is beneficial to the extraction and conduction of holes. In this paper, the radio-frequency (RF) magnetron sputtering is used to deposit MoO_x films. The optical, electrical and structural properties of MoO_x films are measured and analyzed, with focus on the inherent compositions and work function. Then the MoO_x films are applied into SHJ solar cells. When the MoO_x works as a buffer layer between ITO/p-a-Si:H interface in the reference SHJ solar cell, a conversion efficiency of 19.1% can be obtained. When the MoO_x is used as a hole transport layer (HTL), the device indicates a desirable conversion efficiency of 17.5%. To the best of our knowledge, this current efficiency is the highest one for the MoO_x film as HTL by RF sputtering.     

用于磁压剪技术的10 T准静态磁场发生器

基于理论分析和数值模拟,建立了一种用于磁驱动压剪加载中产生纯剪切力的准静态磁场发生器,由4台0.5 mF/15 kV的储能电容器并联而成,通过15 kV/30 kA的半导体硅堆开关,向一对磁体线圈放电,进行模拟分析和实验测试。装置在充电9 kV时,在样品区域获得了上升时间1.34 ms的10 T准静态磁场。测试和分析结果表明在半径7 mm区域内磁场分布不均匀性小于2%,满足磁压剪实验要求。     

发光二极管用红色荧光粉Sr0.8-xBaxEu0.2WO4的制备和性质研究

采用化学共沉淀法制备了不同Ba²⁺掺杂浓度、 不同煅烧温度的Sr_0.8-xBa_xEu_0.2WO₄红色荧光粉. 研究了样品的晶体取向和晶格 畸变对发光性质的影响, 实验结果表明: 合成的Sr_0.8-xBa_xEu_0.2WO₄红色荧光粉为四方相, 样品中Eu³⁺的⁵D₀–⁷F₂跃迁的红光能被近紫外光和蓝光有效激发. 适量的Ba²⁺离子取代部分的Sr²⁺提高了Sr_0.8Eu_0.2WO₄荧光粉的发光强度, Ba²⁺掺杂浓度的改变对基质的晶格参数、晶体对称性和发光性能影响较大, Ba²⁺的最佳掺杂量为30%.     

基于一维光子晶体的新型背反射器及其在非晶硅薄膜太阳电池中的应用

本文研究制备一种由低折射率的SiOx层与高折射率的a-Si层周期性交叠构成的新型一维光子晶体(1D PC)背反射器.研究结果表明,随着SiOx/a-Si交叠周期数的增加,一维光子晶体的反射率逐步提高.当周期数大于3时,在空气中500—750 nm波长范围的平均反射率达到96%.将该一维光子晶体作为背反射器应用于NIP型非晶硅电池(电池结构为玻璃/1D PC/AZO/NIP a-Si:H/ITO),当光子晶体周期为4时,效率达到7.9%,略优于传统的AZO/Ag背反射电极结构电池(7.7%),明显高于不锈钢衬底电池(6.9%),相对效率提升14.5%.     

一类具多滞量的二阶中立型差分方程的振动定理

研究了一类具有多个滞量的变系数的二阶中立型差分方程的振动性,给出了该类方程振动及差分算子振动的充分条件。     

BOREL LINES OF RANDOM DIRICHLET SERIES

For random Diriclilet-haelnacher, Steillhaus and N series of order (R) infinite almostsurely (a.s.), it was proved that a.s. every horizontal line is a Borel line of order (R) illfi-uite and witli a possible exceptional value[6][n. In this paper f by generalized Paley-Zygmundlenru['], sonle sli11ple maPpillgs and Nevanlinlla tlieory[2], we prove that for more general ran-dom Dirichlet random Dirichlet series of order (R) infinite a.s. every horizontal line is a Borelline of order (R) infi…     

探讨工程机械液压设备的保养与维护

液压传动以运动传递平稳、均匀,体积小、结构紧凑,反应灵敏、操作简单,易于实现自动化,自动润滑,标准化程度高,元件寿命长等特点,被广泛应用于工程机械中。这给液压油系统的保养及维护提出了更高的要求。因此,必须做好对液压设备的使用与维护,延长其使用寿命。在重视液压系统的维护管理的基础上,采取有效的措施防止故障的发生。     

基于Web Service的公安交通管理信息市场化应用平台研究

为了充分利用全国公安交通管理信息中心存储的交通管理信息,更好地为各级政府、企事业单位、广大民众提供以机动车和驾驶人登记信息为主的综合信息服务,本文提出一种基于Web服务的公安交通管理信息市场化应用平台建设方案。该方案通过在全国公安交通管理信息中心建设专门的Web服务平台,利用Web服务(Web Service)实现与公安外网各类系统的信息共享和服务。本文还给出一个利用该平台实现信息服务的应用实例。     

Theoretical Study of Hydrated Cd~（2＋） Interactions with Guanine

Theoretical study was performed to investigate how the hydration of cadmium ca-tion influences the structure and properties of guanine.The aqueous environment was simulated by both explicit solvent(1-5 water molecules) model and implicit solvent model.For complexes in which Cd2+ attached to the N(7) and O(6) sites of guanine,energy analysis together with the Natural Bonding Orbital(NBO) analysis were performed to elucidate the bonding characteristics in detail.The most stable structures are penta-coordinate complexes without aqua ligand located at the guanine site.Higher number of water ligands corresponds to higher stabilization energies.Average bonding energies of G-Cd increase with the number of water molecules.Bonding energies of water ligands depend on its position in the complexes.The charge distribution of guanine changed with increasing the number of water ligands,which may also influence the base-pairing pattern of guanine.There is positive charge transfer from guanine to aqua ligand as the number of the hydration waters increases.IEFPCM optimization has results comparable to the [CdG(H2O)5]2+ structure 5a.