应用超高效液相色谱-四极杆-飞行时间质谱建立茶叶中农药残留的筛查与确证方法

基于超高效液相色谱-四极杆-飞行时间质谱(UPLC-QTOF-MS),使用UNIFI软件建立91种农药残留的筛查与确证方法,进行定性方法验证并应用于流通市场中茶叶的筛查检测。通过对收集的农药认证标准物质(CRM)分析,构建91种农药化合物的质谱数据库。样品经乙腈提取,固相萃取柱净化,Acquity BEH C18色谱柱分离,在MS^E模式下进行全信息采集(ESI+), UNIFI软件对数据进行匹配分析。设置保留时间最大偏差为±0.1 min,精确质量偏差阈值为±5×10^-6,可识别加合物形式包括[M+H]⁺、[M+Na]⁺、[M+K]⁺、[M+NH₄]⁺。参照SANTE/11813/2017指南进行定性方法学验证。在21份茶叶样品中添加混合标准溶液至4个水平(0.01、0.05、0.10、0.20 mg/kg),确定每种农药在茶叶样品中的筛查检出限(SDL),共评估了1 911种农药/样品组合。发现有66种农药的SDL为0.01 mg/...     

用于同步辐射光源的成像板粉末衍射系统

报道了我们研制的一套成像板粉末衍射装置,对其误差来源进行了详细的分析讨论,并与衍射仪进行了比较.该装置的半径为143.3mm,最大测量角度范围不160°，最大角度(2q )偏差小于0.03°,这些性能指标已被实验所证实,完全可应用于粉末衍射全谱的测量.     

论中职生数学学习兴趣的培养

中职生数学底子普遍较差,畏难情绪大,数学教学中,培养学生学习数学的兴趣是关键。     

熟化对SiO2粉末孔结构性能的影响

以水玻璃为原料，用溶胶－凝胶法制备ＳｉＯ２粉末，研究了凝胶熟化条件对最终所得ＳｉＯ２粉末孔结构性能的影响，并分析讨论了熟化过程影响ＳｉＯ２粉末孔结构的作用机理。结果表明：在一定条件下提高熟化介质的ｐＨ值和延长熟化时间均可使ＳｉＯ２粉末的比表面积和总孔体积减小，孔径分布向大孔方向移动。     

Performance Degradation Alarming Method Based on Local Flexural Stiffness Identification for Beams

Uncertain local flexural stiffness is recognized as one of the main barriers against the application of existing damage detection and performance degradation alarming techniques to real-world beams.Therefore,damage localization of beams with original uncertainty has been investigated to ensure their safety.For the beam before serving,it should be simply supported and subject to static load.Based on the concept of suppositional partition,a new loading pattern and mid-span displacement data processing method has been proposed.Actual local flexural stiffness value of each partition can be obtained by solving a set of linear equations.The obtained stiffness data can be used to establish the finite element model of beams.Subsequently,dynamic excitation and mode identification should be carried out for the beam in service.Mode shape curvature index is employed to detect the position of damage.It was validated by example that actual damage and original uncertainty of local flexural stiffness can be differentiated by this new method effectively.The combination of static load and dynamic excitation can keep the serviceability of beam.     

关于总传热系数的简化计算

本文以总传热系数的一般计算公式作为讨论的基础,通过数理推导,得出了总传热系数的简化计算公式。其中引进了C值概念,定量地给出了简化计算应满足的条件。同时还举出了实例来验证简化公式的准确性。实例说明,这种简化计算所产生的误差总是在传热计算的允许误差(<10％)范围内。     

用~(58)Ni(n,p)~(58m+g)Co和~(58)Ni(n,2n)~(57)Ni反应的截面比定平均中子能量

本文叙述了用两个硅半导体探测器和~(58)Ni(n,p)~(58g+m)Co与~(58)Ni(n,2n)~(57)Ni反应截面比定D-T中子的平均能量的方法,得到了该截面比与中子能量的关系曲线并与所引文献中的结果进行了比较.     

公路工程成本管理控制

当前在日趋激烈竞争的建筑市场中,公路工程项目的投资越来越低,如何增收节支挖潜增效,如何获取最佳利润,是公路施工企业最值得思考的问题。只有在工程项目全过程中进行成本管理与控制,才能更好地提高经济效益。     

一种特殊条件下的扩散方程的数值解法及物理分析

利用有限差分方法中的预估校正格式求解裂变产物在燃料芯块中的扩散方程,并进行了灵活的边界条件处理,取得了令人满意的计算精度,为有效开展对反应堆燃料元件破损探测信号的定量分析提供了条件.对数值计算过程进行了一定的物理分析,从物理意义上解释了数值计算过程中一些特殊处理的合理性.     

GISAXS and SAXS studies on the spatial structures of Co nanowire arrays

The spatial structures of magnetic Co nanowire array embedded in anodic aluminium membranes were investigated by grazing incidence small angle X-ray scattering (GISAXS) and conventional small angle X-ray scattering (SAXS) techniques. Compared with SEM observation, the GISAXS and SAXS measurements can get more overall structural information in a large-area scale. In this study, the two-dimensional GISAXS pattern was well reconstructed by using the IsGISAXS program. The results demonstrate that the hexagonal lattice formed by the Co nanowires is distorted (a ≈ 105 nm, b ≈ 95 nm). These Co nanowires are isolated into many structure domains with different orientations with a size of about 2 μm. The SAXS results have also confirmed that the nanopore structures in the AAM can be retained after depositing Co nanowires although the Co nanowires can not completely but only just fill up the nanopores. These results are helpful for understanding the global structure of the Co nanowire array.