企业员工绩效考评方法研究及应用

本文提出了一种新的员工绩效考评方法－ＡＦＴ,即用层次分析法（ＡＨＰ）确定考评指标的权重,用模糊数学的方法（Ｆｕｚｚｙ）对各类质化考评指标值进行量化处理,并进行系统的综合,用逼近于理想解的方法（ＴＯＰＳＩＳ）排出被质评者的优劣顺序。     

丁腈橡胶标准物质的~1H-NMR表征

应用1H -NMR技术对系列丁腈橡胶 (BNR)标准物质的结构进行了表征。测定了丁腈橡胶标准物质中聚丁二烯链段中的顺式和反式结构含量、聚丁二烯链段中 1,4加成聚合与 1,2加成聚合的含量以及丁腈橡胶标准物质中结合丙烯腈的含量     

色谱交点在失活催化剂研究中的应用 Ⅰ.苯-催化裂化衰化系列催化剂体系

测定了苯在五种积炭量不同的催化裂化衰化系列催化剂上的保留体积,发现它们的logV_g对1/T直线有一共同交点。这是吸附色谱中同一吸附剂上吸附质为同系物时存在色谱交点的延伸。这是将色谱交点规律应用于失活催化剂研究的新探索。     

A Density Functional Theory Study on Electronic Structure and Second—order Nonlinear Optical Properties of Some Push—Pull Molecules

Time-dependent density-functional theory(TDDFT)has been applied to calculate the electronic structure and second-order nonlinear optical(NLO) properties of some organic molecules.The two-dimensional(2-D)charge transfer charateristics of calculated molecules were studied and compared with corresponding experimental results.All the theoretical results agree well with the measurement.For 2-D molecule with two-fold symmetry,the dominant charge transfer is off-diagonal,while for three-fold symmetry 2-D molecule,the dominant charge transfer is not only between branches and central group but also among branches.     

Synthesis, Characterization and Two-Photon Absorption Properties of a Novel Pyridinium Salt

A novel pyridinium salt, 2,4-bis[p-(N,N-dimethylamino)styryll-N-metlayl pyridinium iodide (BMSPI) was synthesized and characterized by TG, ^1H NMR spectroscopy and elemental analysis, and the reaction process was studied by using ES-MS. When BMSPI was pumped by a pulsed 1064 nm, 50 ps laser beam, it manifests highly efficient TPA (Two-Photon Absorption) and up-conversion superradiance. The up-conversion efficiency was 6.0% at the pump energy of 4-6 mJ and the lifetime of two-photon fluorescence was measured as 59 ps.     

乙烯在纳米催化剂InVO4-TiO2上的可见光降解

The InVO₄-TiO₂ nano-crystalline photocatalyst was prepared by sol-gel method and characterized by DRS, FTIR, Raman and XRD. The photocatalytic activities of the prepared sample were investigated by photocatalytic degradation of ethylene in the gaseous phase under visible light irradiation (λ>450 nm). The results indicate that both of pure TiO₂ and InVO₄ or their simple mixture show no photocatalytic activities for degradation of ethylene under visible light irradiation. However, as-synthesized InVO₄-TiO₂ catalyzes the degradation of ethylene into CO₂ under visible light irradiation. In addition, the interaction between InVO₄ and TiO₂ results in some structural distortion to all the crystal forms of TiO₂ in as-synthesized catalyst InVO₄-TiO₂.     

碳纤维改善水泥石韧性试验研究

针对油田中后期开发面临的固井质量问题，即水泥环脆性破裂问题，对水泥石韧性测定方法进行了讨论，采用水泥试件抗折强度和弹性模量试验以及薄片分析对碳纤维改善水泥石的韧性进行了考察，并分析了碳纤维改善水泥石韧性的机理。结果表明，纤维的加入可以使水泥石的抗折强度提高30％以上；随纤维掺量的增加，水泥石的弹性模量减小，泊松比增加；纤维在水泥石中的分布有效地阻止了裂纹的发展，增强了水泥石的韧性抗断裂能力。对于水泥石的抗折强度存在着最佳纤维长度和纤维掺量，本试验条件下，纤维的最佳长度为700～l400μm，最佳掺量为0．12％～0．19％。     

板几何中一类具周期边界条件迁移算子的谱分析

分析了板几何中一类与时间有关的具周期边界条件的线性迁移方程一些谱的性质，证明了：这类迁移算子的谱在区域中仅由有限个具有限代数重数的离散本征值组成，并证明了该迁移算子的占优本征值的存在性等结果。     

中厚板控制冷却数学模型

介绍了中厚板控制冷却过程中所用的数学模型,包括差分模型、空冷和水冷换热系数模型、比热和热传导率模型,并采用有限差分法模拟计算了钢板在冷却过程中厚度、宽度方向上的温度场分布,以及间歇冷却对控制冷却的影响·从模拟结果可以看出,返红时间、厚度上温度梯度随钢板厚度增加而增加;间歇冷却时钢板内部温度呈均匀下降,表面不断冷却与返红过程·在线应用证明该套数学模型计算精度较高,可以满足现场实际生产的要求·     

表层纳米化铝合金材料的微尺度力学行为

通过对表层纳米化铝合金材料显微组织的观测, 从实验(压缩实验和纳米压痕实验)和理论两方面研究了该材料的微尺度力学行为. 在实验方面, 测量了压缩应力应变曲线和硬度-压入深度曲线; 针对压缩和压痕两种实验特征, 采用微结构构元模型和应变梯度理论, 对该材料的压缩应力应变曲线和硬度曲线进行了预测和模拟; 进而确定出相关的材料参量及模型参量.