FREE STANDING FILM OF POLYANILINE

A free standing film of polyaniline as large as 18 cm×18cm×0.002 cm can be obtained by evaporation of a solution of the chemically synthesized base in NMP. Its structure was examined by the elemental analysis, IR, U.V.-visible spectra, XPS, DSC, SEM and X-ray scattering and its conducting behavior as well as electrochemical properties were studied. Results show that the composition, structure of main chain, physical properties of the free standing film of polyanilme is similar to that of the powder. However, some differences in its electronic structure, conductivity at room temperature and potential of redox couple between the flee standing film and powder are observed, which may be due to cross-linking of the film of polyaniline.     

盐类对4-氯-4′-羟基二苯砜钾盐真空熔融聚合的影响

聚苯砜醚是一种综合性能比较好、可在180℃长期使用的热塑性工程塑料,在国内外受到一定的重视。我们与武汉化工原料厂协作,对4-氯-4′-羟基二苯砜钾盐真空熔融缩聚合成聚苯砜醚的途径进行过一些探索,得到了较好的结果。但是,在实践中发现,由于这一反应速度快,放出的热量大而集中,在真空中聚合热不易导出,随着单体用量     

双氮桥联1,10-菲咯啉大环化合物分子构型的从头算研究

应用规范不变原子轨道法(GIAO)在RHF/6-31G**和B3LYP/6-31G**水平上计算了质子化双氮桥联1,10-菲咯啉大环化合物(H4HAPP2+)C2h和C2h构型的1HNMR,并用TDDFT法计算了H4HAPP2+电子光谱.结果表明,B3LYP/6-31G*优化的C2h构型为较优构型,经谐振频率验证无虚频,C2h构型是H4HAPP2+合理的对称性构型.     

CATIONIC CONDUCTIVITY FOR THE CROSSLINKED P [OLIGO (OXYETHYLENE) METHACRYLATE-COoMETHACRYLOYL ALKYLSULFONIC ACID LITHIUM]

Crosslinked copolymers with single Li~+-ionic conductivity were prepared from oligo (oxyethylene) methacrylate (MEO_n), methacryloyl alkylsulfonic acid lithium (SAMLi), and oligo (oxyethylene) dimethacrylate (DMEO_n). Li~+-ionic conductivity of the copolymer is improved by crosslinking and presented as a function of polymerization degree (n) in MEO_n, comonomeric salt concentration (O/Li), and crosslinking degree. The crosslinked copolymer P (0.7 MEO_(14)-0.3DMEO_(14)-SHMLi) without other small molecular additives exhibits an optimum Li~+-ionic conductivity of 1.2×10~(-6) S/cm at 25℃. Dc polarization test in the cell composed of Li/copolymer/Li shows a constant dc ionic conductivity which closes gradually to the ac one with decreasing dc polarization potential.     

STUDIES ON ENHANCED CONDUCTIVITY OF STRETCHED CONDUCTING POLYMERS

A physical model of series of the conductivity on chain and the interchain conductivitybetween chains is proposed to explain enhanced conductivity of stretched conducting polymers.This model suggests that the enhanced conductivity for stretched conducting polymers might bedue to increasing of the interchain conductivity between chains along the elongation direction afterdrawing processes if the conductivity on chain is assumed much larger than that of the interchainconductivity between chains. According to this model, it is expected that the temperaturedependence of conductivity measured by four-probe method for stretched conducting polymers iscontrolled by a variation of the interchain conductivity between chains with temperature, whichcan be used to explain that a metallic temperature dependence of conductivity for stretchedconducting polymers is not observed although the conductivity along the elongation direction isenhanced by two or three orders of magnitude.     

一类非线性方程的迭代解及应用

利用锥理论和单调迭代方法研究了一类非线性方程解的存在唯一性及其迭代过程，对所述的映射没有作连续性、紧性或具有上、下解的假定．作为应用，把所获得的结果用到Banach空间一阶微分方程．     

影响木材火焰传播速度特征量的实验研究

木材着火时火焰的传播规律将为木材在火灾场景中的行为提供重要参考,分析了木材燃烧的机理和影响木材燃烧时火焰传播速度的特征量,借助于实验的方法,研究了空间方位角和几何尺寸等特征量对火焰传播速度的影响.结果表明,方位角越小,不同尺寸木条火焰传播速度差别越大;火焰传播速度随方位角的增大而增大;木条宽度越大,火焰传播速度越慢.     

一类Lucas数方幂和

设Un，Vn是Lucas数，实数d≠0，使用发生函数方法给出下面形式方幂和计算公式：∑k=1^nUk^rd^k，及∑k=1^n（-1）^kUk^rd^k。     

粉煤灰资源特性及综合利用途径探讨

研究了粉煤灰的资源特性。粉煤灰具有活性炭的结构和比表面积,利用其有较强的吸附、沉降和过滤的特性,提出了利用粉煤灰处理石化系统采油废水,实现采油废水达标排放,论述了粉煤灰综合利用的经济效益、环保效益和社会效益。     

语言交际与文化关系的辨证探析

语言交际是人类生存、生活的主要手段，也是人类精神文明、物质文明以及世界各民族文化传统、风俗习惯得以传承并发展的主要方式。“语言与文化”、“跨文化交际”、“语言交际与文化”三者既有内在联系又有本质上的不同。语言交际与文化同质同构，二者既相互制约，又相互依存，构成一种对立统一的关系。