A New Approach to Develop a Standardized Method for Simultaneous Analysis of Astragaloside IV and Formononetin in Radix Astragali by High-Performance Thin-Layer Chromatography

JPC – Journal of Planar Chromatography – Modern TLC - A new high-performance thin-layer chromatographic (HPTLC) method has been developed for the simultaneous estimation of...     

Synthesis and Photophysical Properties of a Sc3N@C80‐Corrole Electron Donor–Acceptor Conjugate

Embedding endohdedral metallofullerenes (EMFs) into electron donor–acceptor systems is still a challenging task owing to their limited quantities and their still largely unexplored chemical properties. In this study, we have performed a 1,3‐dipolar cycloaddition reaction of a corrole‐based precursor with Sc₃N@C₈₀ to regioselectively form a [5,6]‐adduct ( 1 ). The successful attachment of the corrole moiety was confirmed by mass spectrometry. In the electronic ground state, absorption spectra suggest sizeable electronic communications between the electron acceptor and the electron donor. Moreover, the addition pattern occurring at a [5,6]‐bond junction is firmly proven by NMR spectroscopy and electrochemical investigations performed with 1 . In the electronically excited state, which is probed in photophysical assays with 1 , a fast electron‐transfer yields the radical ion pair state consisting of the one‐electron‐reduced Sc₃N@C₈₀ and of the one‐electron‐oxidized corrole upon its exclusive photoexcitation. As such, our results shed new light on the practical work utilizing EMFs as building blocks in photovoltaics.     

红树林保护与修复标准发展现状及对策

回顾近20年来中国对红树林的保护以及通过人工造林进行恢复的情况, 梳理我国红树林保护与修复的相关标准, 厘清现行标准存在的问题, 提出如下相应的建议与对策。1) 应结合国家碳中和战略及红树林保护与恢复规划目标, 制定完善的红树林保护与生态修复技术标准体系规划, 加快相关国家标准的出台; 2) 在编制红树林保护与修复相关标准的同时, 应注重红树林固碳能力和增汇效应的提高; 3) 建议制定退塘还林相关标准, 填补国内空白; 4) 应充分落实“自然恢复为主、人工修复为辅”的生态修复原则, 重视并加强红树林保护与修复标准的技术细节制定; 5) 标准的制定和实施应由红树林研究专业机构及专家深度参与, 提高造林成活率。     

An Efficient Selective Oxidation of Alcohols with Potassium Permanganate Adsorbed on Aluminum Silicate under Solvent-free Conditions and Shaking

A new procedure for the selective oxidation of alcohols to the corresponding aldehydes and ketones with potassium permanganate supported on aluminum silicate at room temperature under solvent-free conditions and shaking is reported.     

黎锦明小说的艺术特色

在中国现代文学史上，黎锦明创作颇丰，曾是一位较为活跃的有影响的著名作家，有些作品在当时曾引起文坛的瞩目和社会的反响。长期以来，他和他的作品被人漠视和遗忘。实际上，他的小说在题材内容选取上很是广阔，在体式技法运用的多样性上更是有其独特之处。     

物理理论与美的统一

从物理学的概念、定义、定理、定律、公式中，浅谈物理学形式美的基本内容：对称美、简洁美、和谐美和多样统一美。     

数据挖掘:实现有效CRM的动力

从介绍CRM的有关原理出发，着重阐述了数据挖掘在CRM中的技术应用和商业价值，其中数据挖掘的商业价值部分着重从客户生命周期角度展开探讨。