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31.
Ultra-Stable and Sensitive Ultraviolet Photodetectors Based on Monocrystalline Perovskite Thin Films
Xu Li Chang Liu Feng Ding Zheyi Lu Peng Gao Ziwei Huang Weiqi Dang Liqiang Zhang Xiaohui Lin Shuimei Ding Bailing Li Ying Huangfu Xiaohua Shen Bo Li Xuming Zou Yuan Liu Lei Liao Yiliu Wang Xidong Duan 《Advanced functional materials》2023,33(15):2213360
The detection of ultraviolet (UV) radiation with effective performance and robust stability is essential to practical applications. Metal halide single-crystal perovskites (ABX3) are promising next-generation materials for UV detection. The device performance of all-inorganic CsPbCl3 photodetectors (PDs) is still limited by inner imperfection of crystals grown in solution. Here wafer-scale single-crystal CsPbCl3 thin films are successfully grown by vapor-phase epitaxy method, and the as-constructed PDs under UV light illumination exhibit an ultralow dark current of 7.18 pA, ultrahigh ON/OFF ratio of ≈5.22 × 105, competitive responsivity of 32.8 A W−1, external quantum efficiency of 10867% and specific detectivity of 4.22 × 1012 Jones. More importantly, they feature superb long-term stability toward moisture and oxygen within twenty-one months, good temperature tolerances at low and high temperatures. The ability of the photodetector arrays for excellent UV light imaging is further demonstrated. 相似文献
32.
Xinzhen Lu Yifeng Cheng Menghao Li Yucheng Zou Cheng Zhen Duojie Wu Xianbin Wei Xiangyan Li Xuming Yang Meng Gu 《Advanced functional materials》2023,33(12):2212847
Solid-state lithium metal batteries (SSLMBs) are a promising candidate for next-generation energy storage systems due to their intrinsic safety and high energy density. However, they still suffer from poor interfacial stability, which can incur high interfacial resistance and insufficient cycle lifespan. Herein, a novel poly(vinylidene fluoride‑hexafuoropropylene)-based polymer electrolyte (PPE) with LiBF4 and propylene carbonate plasticizer is developed, which has a high room-temperature ionic conductivity up to 1.15 × 10−3 S cm−1 and excellent interfacial stability. Benefitting from the stable interphase, the PPE-based symmetric cell can operate for over 1000 h. By virtue of cryogenic transmission electron microscopy (Cryo-TEM) characterization, the high interfacial compatibility between Li metal anode and PPE is revealed. The solid electrolyte interphase is made up of an amorphous outer layer that can keep intimate contact with PPE and an inner Li2O-dominated layer that can protect Li from continuous side reactions during battery cycling. A LiF-rich transition layer is also discovered in the region of PPE close to Li metal anode. The feasibility of investigating interphases in polymer-based solid-state batteries via Cryo-TEM techniques is demonstrated, which can be widely employed in future to rationalize the correlation between solid-state electrolytes and battery performance from ultrafine interfacial structures. 相似文献
33.
Gu P Haas P Hogan WP Kim SK Matthews JN Myung SS Schnetzer S Thomson GB Zou Y Arisaka K Roberts D Slater W Spencer MB Weaver M Briere RA Cheu E Harris DA Krolak P McFarland KS Roodman A Schwingenheuer B Somalwar SV Wah YW Winstein B Winston R Barker AR Swallow EC Bock GJ Coleman R Crisler M Enagonio J Ford R Hsiung YB Jensen DA O'Dell VR Ramberg E Tschirhart R Collins EM Gollin GD Nakaya T Yamanaka T 《Physical review letters》1996,76(23):4312-4315
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Zou Q Bennion BJ Daggett V Murphy KP 《Journal of the American Chemical Society》2002,124(7):1192-1202
Trimethylamine n-oxide (TMAO) is a naturally occurring osmolyte that stabilizes proteins and offsets the destabilizing effects of urea. To investigate the molecular mechanism of these effects, we have studied the thermodynamics of interaction between TMAO and protein functional groups. The solubilities of a homologous series of cyclic dipeptides were measured by differential refractive index and the dissolution heats were determined calorimetrically as a function of TMAO concentration at 25 degrees C. The transfer free energy of the amide unit (-CONH-) from water to 1 M TMAO is large and positive, indicating an unfavorable interaction between the TMAO solution and the amide unit. This unfavorable interaction is enthalpic in origin. The interaction between TMAO and apolar groups is slightly favorable. The transfer free energy of apolar groups from water to TMAO consists of favorable enthalpic and unfavorable entropic contributions. This is in contrast to the contributions for the interaction between urea and apolar groups. Molecular dynamics simulations were performed to provide a structural framework for the interpretation of these results. The simulations show enhancement of water structure by TMAO in the form of a slight increase in the number of hydrogen bonds per water molecule, stronger water hydrogen bonds, and long-range spatial ordering of the solvent. These findings suggest that TMAO stabilizes proteins via enhancement of water structure, such that interactions with the amide unit are discouraged. 相似文献
37.
Yaping Zou 《Tetrahedron letters》2007,48(27):4781-4784
A series of new diphosphite ligands have been easily prepared from BINOL derivatives; moderate enantioselectivities (up to 80% ee) and excellent regioselectivities (b/l up to 98/2) have been achieved in the Rh-catalyzed asymmetric hydroformylation of vinyl acetate. 相似文献
38.
Shao-Chen Yang Qihuang Gong Zongju Xia Y. H. Zou Y. Q. Wu D. Qiang Y. L. Sun Z. N. Gu 《Applied physics. B, Lasers and optics》1992,55(1):51-53
The nonlinear third-order optical susceptibility of C70 in a toluene solution is measured for the first time by the method of degenerate four-wave mixing using 10 ns laser pulses at 1.06 m. The third-order susceptibility X
in
(3)
is 5.6×10–12 esu for a C70 toluene solution at a concentration of 0.476 g/l. The correspondent magnitude of the hyperpolarizability 1111 of the C70 molecule is 1.2×10–30 esu which is in a good agreement with the prediction given by the model of a free electron in a spherical box. 相似文献
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Jun Zou Bo Zhang Jian Guo Jin-Liang He Jaebok Lee Chang S. 《Electromagnetic Compatibility, IEEE Transactions on》2006,48(1):33-41
The design of grounding system often relies on the performance simulations. The evaluation of the current distribution of grounding system for many frequencies by using the method of moments (MoM) may take a long time since the impedance matrix must be recomputed at each new frequency. A multiobject adaptive spatial sampling approach is presented to construct the fitted model of the electric field intensity generated by a horizontal electric dipole. The [Z] matrix spatial interpolation technology with MoM is described to reduce the computational time needed for the transient characteristics analysis of a horizontal grounding system. The accuracy and computational time of the [Z] matrix interpolation method are compared with those of the direct MoM. The numerical examples show that the [Z] matrix spatial interpolation method can reduce the computation requirement effectively. 相似文献