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51.
Dr. Chao Xu Dr. Guoxin Tian Dr. Simon J. Teat Dr. Guokui Liu Dr. Linfeng Rao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(49):16690-16698
The complexation of NpO22+ and PuO22+ with dipicolinic acid (DPA) has been investigated in 0.1 M NaClO4 by spectrophotometry, microcalorimetry, and single crystal diffractometry. Formation of 1:1 and 1:2 (metal/ligand molar ratio) complexes of DPA with NpO22+ and PuO22+ were identified and the thermodynamic parameters were determined and compared with those of UO22+. All three hexavalent actinyl cations form strong 1:1 DPA complexes with slightly decreasing but comparable stability constants from UO22+ to PuO22+, whereas the stability constants of the 1:2 complexes (log β2) decrease substantially along the series (16.3 for UO2L22?, 15.17 for NpO2L22?, and 14.17 for PuO2L22? at 25 °C). The enthalpies of complexation for the 1:2 complexes become less exothermic from UO2L22? (?28.9 kJ mol?1), through NpO2L22? (?27.2 kJ mol?1), and to PuO2L22? (?22.7 kJ mol?1). The trends in the thermodynamic parameters are discussed in terms of the effective charge of the cations and the steric constraints in the structures of the complexes. In addition, the features of the absorption spectra, including the wavelength and intensity of the absorption bands, are related to the perturbation of the ligand field and the symmetry of the actinyl complexes. 相似文献
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Qingpei Xiang Dongfeng Tian Fanhua Hao Chengsheng Chu Ge Ding Jun Zeng Fei Luo 《Journal of Radioanalytical and Nuclear Chemistry》2014,299(3):1439-1445
In recent years, the cerium-doped lanthanum bromide, LaBr3 (Ce = 5 %) detector is increasingly playing an important role in radiation measurements because of its higher energy resolution (~3 % at 662 keV), faster luminescence decay time (~35 ns) and higher detection efficiency compared to 7.65 cm × 7.65 cm NaI(Tl) detector. Intrinsic spectra between 1,800 and 3,000 keV derived from internal radioactivity within LaBr3(Ce) scintillators have been investigated in some literatures, and these results are confirmed by the experiments in this work. In this paper, a new method for LaBr3(Ce) detector energy calibration from 100 to 2,000 keV is proposed using the intrinsic spectra (self-calibration) instead of the standard gamma sources. Proof-of-concept experiment results show that self-calibration can guarantee energy accuracy of better than 0.815 % and can be applied outside the laboratory. The stability and applicability of this method are also investigated systematically. 相似文献
54.
Quantum interference corrections in ballistic conductors require a minimal time: the Ehrenfest time. In this Letter, we investigate the fate of the interference corrections to quantum transport in bulk ballistic conductors if the Ehrenfest time and the dephasing time are comparable. 相似文献
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An Unusual Triphenylphosphine Oxide Catalyzed Stereoselective 1,3‐Dichlorination of Unsaturated Ketoesters 下载免费PDF全文
Tian‐Yang Yu Yao Wang Peng‐Fei Xu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(1):98-101
An unusual Ph3PO‐catalyzed stereoselective 1,3‐dicholorination of an unsaturated ketoester has been developed. The novel activation mode involved in this cascade reaction can promote consecutively elusive transformations. The products were obtained with good yields and excellent stereoselectivities. This reaction makes important complementation to the limitations associated with the field of dichlorination. 相似文献
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Complex 3D microparticle, as an emerging and attractive field, has attracted more and more attention due to its versatile morphologies and broad range of applications. In this review, we provide an overall recent progress in 3D microparticles fabricated by microfluidic lithography. This review will focus on the synthesis mechanisms, synthesis process, the resultant 3D microparticles, and their applications. Finally, we will look into the future trends in complex 3D microparticles. This review will be beneficial for researchers in numerous fields, including functional materials, sensors, encryption, and biomedical engineering. 相似文献
59.
Hui Shao Xiaonan Gao Zhong‐Tian Wang Ziwei Gao Yu‐Ming Zhao 《Angewandte Chemie (International ed. in English)》2020,59(19):7419-7424
A divergent synthetic approach to six Ganoderma meroterpenoids, namely ganocins A–C, ganocochlearins C and D, and cochlearol T, has been developed for the first time. This synthetic route features a two‐phase strategy which includes early‐stage rapid construction of a common planar tricyclic intermediate followed by highly selective late‐stage transformations into various Ganoderma meroterpenoids. Key to the strategy are a bioinspired intramolecular hetero‐Diels–Alder reaction and Stahl‐type oxidative aromatization, allowing efficient formation of the common tricyclic phenol intermediate. A nucleophilic dearomatization of the phenol unit, combined with a regioselective 1,4‐reduction of the resulting dienone, enabled rapid access to ganocins B and C. Additionally, site‐selective Mukaiyama hydration, followed by an intramolecular oxa‐Michael addition/triflation cascade, served as a key strategic element in the chemical synthesis of ganocin A. 相似文献
60.
Yi Ding Yan Wu Ying Tian Yuzeng Xu Minna Hou Bo Zhou Jingshan Luo Guofu Hou Ying Zhao Xiaodan Zhang 《Journal of Energy Chemistry》2021,(7):48-54
Guanidinium (GA) cations are intentionally introduced in MAPbl3 perovskite by considering its potential capability of stabilizing the material through plenty of... 相似文献