全文获取类型
收费全文 | 30536篇 |
免费 | 4398篇 |
国内免费 | 3399篇 |
专业分类
化学 | 16698篇 |
晶体学 | 296篇 |
力学 | 1420篇 |
综合类 | 239篇 |
数学 | 2659篇 |
物理学 | 8851篇 |
无线电 | 8170篇 |
出版年
2024年 | 51篇 |
2023年 | 730篇 |
2022年 | 765篇 |
2021年 | 1043篇 |
2020年 | 1173篇 |
2019年 | 1079篇 |
2018年 | 859篇 |
2017年 | 881篇 |
2016年 | 1254篇 |
2015年 | 1241篇 |
2014年 | 1544篇 |
2013年 | 1989篇 |
2012年 | 2501篇 |
2011年 | 2432篇 |
2010年 | 1736篇 |
2009年 | 1742篇 |
2008年 | 2004篇 |
2007年 | 1877篇 |
2006年 | 1804篇 |
2005年 | 1511篇 |
2004年 | 1152篇 |
2003年 | 990篇 |
2002年 | 870篇 |
2001年 | 690篇 |
2000年 | 714篇 |
1999年 | 809篇 |
1998年 | 687篇 |
1997年 | 584篇 |
1996年 | 589篇 |
1995年 | 507篇 |
1994年 | 459篇 |
1993年 | 394篇 |
1992年 | 338篇 |
1991年 | 289篇 |
1990年 | 272篇 |
1989年 | 178篇 |
1988年 | 137篇 |
1987年 | 102篇 |
1986年 | 109篇 |
1985年 | 83篇 |
1984年 | 40篇 |
1983年 | 42篇 |
1982年 | 40篇 |
1981年 | 23篇 |
1980年 | 9篇 |
1979年 | 5篇 |
1976年 | 1篇 |
1957年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 749 毫秒
91.
国内3G网络共享问题之研究 总被引:2,自引:0,他引:2
随着国内3G时代的来临,3G网络共享问题越来越受到人们的关注。本文结合国内移动通信的现状,着重分析了3G网络共享的模式及经济效益,论述了3G网络共享的相应策略。 相似文献
92.
分析了并口处于EPP(增强型并行端口)模式时和单片机进行数据交换的原理.介绍了有关EPP的基本特性、信号定义、操作模式及其程序设计方法,设计了基于EPP协议的便携式数据采集系统,给出了技术解决方案,讨论了系统的硬件接口电路和软件编程.方案具有可靠性高、速度快、软硬件设计简捷等优点. 相似文献
93.
Zhengmao Zhu 《Applied Surface Science》2005,252(2):303-310
The reactivity of the surface of poly(ethylene terephthalate) (PET) film under 172 nm UV irradiation (xenon excimer lamp) towards nitrogen-borne 1-octene, n-nonane and heptafluorodecene vapor was investigated. Materials receiving from 0 to 24 J/cm2 of UV were examined by X-ray photoelectron spectroscopy (XPS), time of flight secondary ion mass spectroscopy (ToF/SIMS), water and mineral oil contact angle measurement and atomic force microscopy (AFM). A uniform nanoscale layer developed on PET surface attributed to the grafting reaction between photolytically-produced polymer radicals and vapor phase molecules. 相似文献
94.
从现有的PCDFs分子的正辛醇 /水分配系数 (logKow)实验数据出发 ,建立定量结构 性质关系方程(QSPR) .采用G98W程序包中的PM3方法对 13 5个多氯代二苯并呋喃 (PCDFs)分子和二苯并呋喃进行了优化计算 ,作业命令为 #pPM3optfreqscf(conver =9) ,以计算所得的分子轨道能量、碳原子电荷作为PCDFs分子结构描述符 ,运用多元线性回归技术建立了PCDFs的logKow与分子结构描述符的四元方程 ,最优相关系数为 0 .95 0 7,标准偏差为 0 .173 7,经检验该模型的稳健性好 ,并对未有实验数据的 85个PCDFs的logKow进行预测 相似文献
95.
Polarization self-modulation effect in a free oscillated Nd:YAG laser is investigated after a quarter wave plate is introduced independently in the two positions of the cavity. As described in the previous experiments, the intensity components in the orthogonal directions are modulated with a period of the round-trip time or twice. Different pulse shapes reveal that the seed field from the spontaneous emission is not uniform and seems to be stochastic for each pulse. 相似文献
96.
The original article to which this Erratum refers was published in Journal of Graph Theory 47:129–146,2004 . 相似文献
97.
A new reagent, potassium permanganate adsorbed on aluminum silicate, suitable for the oxidation of primary and secondary alcohols to the corresponding carbonyl compounds is described. 相似文献
98.
An experimental method is developed to examine the near tip deformation at the mesoscopic scale level. The differential interference contrast (DIC) method is used by application of the Nomarski prism in polarized microscope for measuring the out of surface deformation. The method is very sensitive to small height changes detected by different interference color. Discussed are results for the crack tip deformation field. 相似文献
99.
Xin‐Gui Li Run‐Feng Chen Mei‐Rong Huang Mei‐Fang Zhu Qun Chen 《Journal of polymer science. Part A, Polymer chemistry》2004,42(9):2073-2092
A new series of copolymers was synthesized through the oxidative polymerization of pyrrole (PY) and o‐phenetidine (PHT) with inorganic oxidants in acidic media. The polymerization parameters including the mixing method of the oxidant with the comonomer, the comonomer ratio, the time, the temperature, the oxidant, the organic medium, and the acid were systematically optimized for the synthesis of copolymers with high yields, intrinsic viscosities, and solubility. The resultant copolymers were characterized by elemental analysis, infrared, ultraviolet–visible, solution high‐resolution 1H NMR and solid‐state high‐resolution 13C NMR, circular dichroism spectroscopy, and cyclic voltammetry. The results showed that the PY observed content in the copolymers was much higher than the PY feed content. The regular variation of the polymerization yield, intrinsic viscosity, solubility, macromolecular structure, and electroactivity of the resulting polymers with the comonomer ratio, together with the complete solubility of a PY/PHT (10/90) polymer in highly polar solvents, indicated the formation of real random copolymers containing both PY and PHT units rather than a mixture of two homopolymers. However, the polymers containing more than 59 mol % PY were not homogeneous copolymers consisting of soluble and insoluble parts. A semiquantitative relationship between the polymerization yield or solubility of the copolymers and the polarity index of the organic solvents was examined. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2073–2092, 2004 相似文献
100.
Akihide Itoh Taisuke Nagasawa Yanbei Zhu Kyue-Hyung Lee Eiji Fujimori Hiroki Haraguchi 《Analytical sciences》2004,20(1):29-36
In order to elucidate the distributions of the elements among the particulate and dissolved fractions in pond water, major-to-ultratrace elements in different sizes of particles as well as in the filtrate passed through the 0.05 microm filter were determined by inductively coupled plasma atomic emission spectrometry (ICP-AES) and inductively coupled plasma mass spectrometry (ICP-MS). The different sizes of particle samples (ca. 100-300 microg each) were collected on the membrane filters with pore sizes of 10, 3.0, 1.2, 0.4, 0.2 and 0.05 microm, respectively, by sequential fractionation. As a result, about 40 elements in different sizes of particles could be determined by ICP-AES and ICP-MS, after acid digestion using HNO3/HF/HClO4. Then, the fractional distribution factors of major-to-ultratrace elements among the particulate and dissolved fractions were estimated from the analytical results. The total contents of Al, Fe, Ti, REEs (rare earth elements), Bi, Pb and Ag in the particulate fractions (larger than 0.05 microm) were more than 80-90%, while those of Ca, Sr, Cs, W, Ba, Mn and Co in the dissolved fraction, which corresponded to the filtrate passed through the 0.05 microm membrane filter, were more than 80%. It was further found that the fractional distributions of Cu and Zn in the dissolved fraction were ca. 50%. In addition, the enrichment factors (EFs) of the elements in the particulate fractions with particle sizes of 3.0-10 microm and 0.05-0.2 microm were estimated to elucidate their geochemical characteristics in natural water. 相似文献