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21.
Xin‐Gui Li Run‐Feng Chen Mei‐Rong Huang Mei‐Fang Zhu Qun Chen 《Journal of polymer science. Part A, Polymer chemistry》2004,42(9):2073-2092
A new series of copolymers was synthesized through the oxidative polymerization of pyrrole (PY) and o‐phenetidine (PHT) with inorganic oxidants in acidic media. The polymerization parameters including the mixing method of the oxidant with the comonomer, the comonomer ratio, the time, the temperature, the oxidant, the organic medium, and the acid were systematically optimized for the synthesis of copolymers with high yields, intrinsic viscosities, and solubility. The resultant copolymers were characterized by elemental analysis, infrared, ultraviolet–visible, solution high‐resolution 1H NMR and solid‐state high‐resolution 13C NMR, circular dichroism spectroscopy, and cyclic voltammetry. The results showed that the PY observed content in the copolymers was much higher than the PY feed content. The regular variation of the polymerization yield, intrinsic viscosity, solubility, macromolecular structure, and electroactivity of the resulting polymers with the comonomer ratio, together with the complete solubility of a PY/PHT (10/90) polymer in highly polar solvents, indicated the formation of real random copolymers containing both PY and PHT units rather than a mixture of two homopolymers. However, the polymers containing more than 59 mol % PY were not homogeneous copolymers consisting of soluble and insoluble parts. A semiquantitative relationship between the polymerization yield or solubility of the copolymers and the polarity index of the organic solvents was examined. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2073–2092, 2004 相似文献
22.
Akihide Itoh Taisuke Nagasawa Yanbei Zhu Kyue-Hyung Lee Eiji Fujimori Hiroki Haraguchi 《Analytical sciences》2004,20(1):29-36
In order to elucidate the distributions of the elements among the particulate and dissolved fractions in pond water, major-to-ultratrace elements in different sizes of particles as well as in the filtrate passed through the 0.05 microm filter were determined by inductively coupled plasma atomic emission spectrometry (ICP-AES) and inductively coupled plasma mass spectrometry (ICP-MS). The different sizes of particle samples (ca. 100-300 microg each) were collected on the membrane filters with pore sizes of 10, 3.0, 1.2, 0.4, 0.2 and 0.05 microm, respectively, by sequential fractionation. As a result, about 40 elements in different sizes of particles could be determined by ICP-AES and ICP-MS, after acid digestion using HNO3/HF/HClO4. Then, the fractional distribution factors of major-to-ultratrace elements among the particulate and dissolved fractions were estimated from the analytical results. The total contents of Al, Fe, Ti, REEs (rare earth elements), Bi, Pb and Ag in the particulate fractions (larger than 0.05 microm) were more than 80-90%, while those of Ca, Sr, Cs, W, Ba, Mn and Co in the dissolved fraction, which corresponded to the filtrate passed through the 0.05 microm membrane filter, were more than 80%. It was further found that the fractional distributions of Cu and Zn in the dissolved fraction were ca. 50%. In addition, the enrichment factors (EFs) of the elements in the particulate fractions with particle sizes of 3.0-10 microm and 0.05-0.2 microm were estimated to elucidate their geochemical characteristics in natural water. 相似文献
23.
24.
Zhu Yongliang; Pagilla Prabhakar R. 《IMA Journal of Mathematical Control and Information》2005,22(2):181-186
We derive some useful and easily computable necessary conditionsfor the existence of a positive semi-definite solution to thealgebraic Ricatti equation (ARE). A motivating example is givento highlight the usefulness of the conditions for controllerand observer designs for nonlinear systems. Further, an upperbound on the trace of the solution to the ARE is also derived. 相似文献
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26.
A numerical study of confined jets in a cylindrical duct is carried out to examine the performance of two recently proposed turbulence models: an RNG-based K-? model and a realizable Reynolds stress algebraic equation model. The former is of the same form as the standard K-? model but has different model coefficients. The latter uses an explicit quadratic stress-strain relationship to model the turbulent stresses and is capable of ensuring the positivity of each turbulent normal stress. The flow considered involves recirculation with unfixed separation and reatachment points and severe adverse pressure gradients, thereby providing a valuable test of the predictive capability of the models for complex flows. Calculations are performed with a finite volume procedure. Numerical credibility of the solutions is ensured by using second-order-accurate differencing schemes and sufficiently fine grids. Calculations with the standard K-? model are also made for comparison. Detailed comparisons with experiments show that the realizable Reynolds stress algebraic equation model consistently works better than does the standard K-? model in capturing the essential flow features, while the RNG-based K-? model does not seem to give improvements over the standard K-? model under the flow conditions considered. 相似文献
27.
BaTiO_3系PTCR热敏电阻器用烧结助剂的研究 总被引:3,自引:1,他引:2
研究了烧结助剂的作用,实验结果表明:如只引入半导化元素,不引入烧结助剂,则室温电阻率ρ25很大,甚至是绝缘体。由于烧结助剂的加入,既改善了PTCR热敏电阻陶瓷的烧结性,又改善了其ρ25、耐电压Vb、PTC效应等特性,从而使产品的各种特性易于重复。烧结助剂昔日多用AST,现在常用SiO2,其加入量x宜小于2%。SiO2的纯度、杂质等化学特性,与粒子形状、粒度分布、晶系等物理特性,对PTCR热敏电阻器的电性能有很大的影响。据此提出了BaTiO3系PTCR热敏电阻器用SiO2的技术标准。 相似文献
28.
Feding Ge Jing Zhu Limin Chen 《Journal of Infrared, Millimeter and Terahertz Waves》1996,17(2):449-455
The effective parameters of chiral composite are studied using a simple model, that is, randomly oriented non-interacting wire helices embedded in a nonchiral host medium. It is found that both the effective permittivity ? and permeability μ are independent on the handedness of the chiral objects while the effective chirality admittance ξ is dependent. It is also found that when the ratio of the radius of the chiral helix to its pitch is about 0.23, maximum chirality admittance is achieved. The effective parameters of equichiral sample are also discussed. 相似文献
29.
单麦克风和双麦克风语音增强系统的研究 总被引:3,自引:0,他引:3
本文对采用减谱法和箱关法的语音增强系统进行了研究,系统的噪声为白噪声和普通机房噪声。减谱法采用单麦克风输入,试验中发现语音的分帧方法对消噪影响很大,通过比较得到了一种具有明显消噪效果的分帧方法,在相关法中采用双麦克风输入,对两个输入信号之间的时延差进行了补偿,在求维纳滤波器系数时,对信号谱进行统计平均,从而使消噪后的语音信号具有较好的自然度。在研究以上两种方法的基础上,我们提出了一种混合消噪系统, 相似文献
30.
Voigt线型及其精确快速算法 总被引:1,自引:1,他引:0
通过把上半复平面分为4个区,并在每一区利用不同近似,建立了一种精确快速计算Voigt函数、修正的Voigt函数和Voigt函数偏导数的算法,其最大相对误差小于5×10-4.该算法是Line-by-Line大气透过率/辐射强度计算及其相关应用的有效算法. 相似文献