Intersections of random walks and Wiener sausages in four dimensions

Let {S ₁ (n)} _n0and {S ₂ (n)} _n0be independent simple random walks in Z ⁴ starting at the origin, and let % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiGc9yrFr0xXdbba91rFfpec8Eeeu0x% Xdbba9frFj0-OqFfea0dXdd9vqaq-JfrVkFHe9pgea0dXdar-Jb9hs% 0dXdbPYxe9vr0-vr0-vqpWqaaeaabiGaciaacaqabeaadaqaaqGaaO% qaaiabfc6aqnaaBaaaleaacaqGPbaabeaatCvAUfKttLearyqr1ngB% Prgaiuaakiab-HcaOiaadggacaGGSaGaamOyaiab-LcaPiabg2da9i% ab-Tha7Hqbciab+Hha4jabgIGiolab+PfaAnaaCaaaleqabaGaaGin% aaaakiaacQdaieGacaqFtbWaaSbaaSqaaiaabMgaaeqaaOGae8hkaG% Iaa0xBaiab-LcaPiabg2da9iab+Hha4baa!5761!\[\Pi _{\rm{i}} (a,b) = \{ x \in Z^4 :S_{\rm{i}} (m) = x\]for the some % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiGc9yrFr0xXdbba91rFfpec8Eeeu0x% Xdbba9frFj0-OqFfea0dXdd9vqaq-JfrVkFHe9pgea0dXdar-Jb9hs% 0dXdbPYxe9vr0-vr0-vqpWqaaeaabiGaciaacaqabeaadaqaaqGaaO% qaaGqaciaa-1gacqGHiiIZtCvAUfKttLearyqr1ngBPrgaiuaacqGF% OaakcaWGHbGaaiilaiaadkgacqGFPaqkcqGF9bqFaaa!4936!\[m \in (a,b)\} \]. Let two integervalued sequences {a _n}_n0and {b _n}_n0be given, such that the limit lim_n a _nexists and lim _n b _n=+. In this paper, it is shown that the probability of % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiGc9yrFr0xXdbba91rFfpec8Eeeu0x% Xdbba9frFj0-OqFfea0dXdd9vqaq-JfrVkFHe9pgea0dXdar-Jb9hs% 0dXdbPYxe9vr0-vr0-vqpWqaaeaabiGaciaacaqabeaadaqaaqGaaO% qaaiabfc6aqnaaBaaaleaacaaIXaaabeaatCvAUfKttLearyqr1ngB% Prgaiuaakiab-HcaOiab-bdaWiab-XcaSiabg6HiLkab-LcaPiabgM% Iihlabfc6aqnaaBaaaleaacaaIYaaabeaakiab-HcaOiaadggadaWg% aaWcbaGaamOBaiaacYcaaeqaaOGaamyyamaaBaaaleaacaWGUbaabe% aakiabgUcaRiaadkgadaWgaaWcbaGaamOBaaqabaGccqWFPaqkcqGH% GjsUieaacaGFydaaaa!5904!\[\Pi _1 (0,\infty ) \cap \Pi _2 (a_{n,} a_n + b_n ) \ne \O \] is asymptotic to % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiGc9yrFr0xXdbba91rFfpec8Eeeu0x% Xdbba9frFj0-OqFfea0dXdd9vqaq-JfrVkFHe9pgea0dXdar-Jb9hs% 0dXdbPYxe9vr0-vr0-vqpWqaaeaabiGaciaacaqabeaadaqaaqGaaO% qaamaalaaabaGaaGymaaqaaiaaikdaaaGaciiBaiaac+gacaGGNbWe% xLMBb50ujbqeguuDJXwAKbacfaGae8hkaGIae8xmaeJae83kaSIaam% OyamaaBaaaleaacaWGUbaabeaakiaac+cacaWGHbWaaSbaaSqaaiaa% d6gaaeqaaOGae8xkaKIae83la8IaciiBaiaac+gacaGGNbGaamOyam% aaBaaaleaacaWGUbaabeaaaaa!5364!\[\frac{1}{2}\log (1 + b_n /a_n )/\log b_n \] if it tends to zero as n, and the probability of % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiGc9yrFr0xXdbba91rFfpec8Eeeu0x% Xdbba9frFj0-OqFfea0dXdd9vqaq-JfrVkFHe9pgea0dXdar-Jb9hs% 0dXdbPYxe9vr0-vr0-vqpWqaaeaabiGaciaacaqabeaadaqaaqGaaO% qaaiabfc6aqnaaBaaaleaacaaIXaaabeaatCvAUfKttLearyqr1ngB% Prgaiuaakiab-HcaOiab-bdaWiab-XcaSiabg6HiLkab-LcaPiabgM% Iihlabfc6aqnaaBaaaleaacaaIYaaabeaakiab-HcaOiaadggadaWg% aaWcbaGaamOBaaqabaGccaGGSaGaamyyamaaBaaaleaacaWGUbaabe% aakiabgUcaRiaadkgadaWgaaWcbaGaamOBaaqabaGccqWFPaqkcqWF% 9aqpieaacaGFydaaaa!583C!\[\Pi _1 (0,\infty ) \cap \Pi _2 (a_n ,a_n + b_n ) = \O \]is asymptotic to % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiGc9yrFr0xXdbba91rFfpec8Eeeu0x% Xdbba9frFj0-OqFfea0dXdd9vqaq-JfrVkFHe9pgea0dXdar-Jb9hs% 0dXdbPYxe9vr0-vr0-vqpWqaaeaabiGaciaacaqabeaadaqaaqGaaO% abaeqabaaabaGaam4yaiaacUfaciGGSbGaai4BaiaacEgatCvAUfKt% tLearyqr1ngBPrgaiuaacqWFOaakcaWGHbWaaSbaaSqaaiaad6gaae% qaaOGaey4kaSIaamOyamaaBaaaleaacaWGUbaabeaakiab-LcaPiab% -9caViab-XgaSjab-9gaVjab-DgaNjab-HcaOiaadggadaWgaaWcba% GaamOBaaqabaGccqGHRaWkcaaIYaGae8xkaKIae8xxa01aaWbaaSqa% beaacqWFTaqlcqWFXaqmcqWFVaWlcqWFYaGmaaaaaaa!5BAC!\[\begin{array}{l} \Pi _1 (0,\infty ) \cap \Pi _2 (a_n ,a_n + b_n ) = \O \\ c[\log (a_n + b_n )/log(a_n + 2)]^{ - 1/2} \\ \end{array}\], for some constant c, if it tends to a finite constant (1) as n. These results extend some results obtained by G. F. Lawler about the intersection properties of simple random walks in Z ⁴. By using similar arguments, we also get corresponding results for the intersections of Wiener sausages in four dimensions. In particular, a conjecture suggested by M. Aizenman, which describes nonintersection of independent Wiener sausages in R ⁴, is proven.Partly supported by AvH Foundation.     

Orthogonal array design (OAD) for the optimization of mercury extraction from soils by dilute acid with microwave heating

The use of dilute acid for mercury extraction from geological samples with microwave assisted heating was investigated. An orthogonal array design OA(16)(4(1)x2(12)) was applied to select the optimum conditions. The effects of the concentration of HNO(3), the additions of HCl and H(2)S0(4), the extraction time and their interactions were evaluated by the mixed-level orthogonal array design (OAD). The results indicated that the addition of small amount of HCl would improve significantly the extraction of mercury from soil matrices. From the study, it is seen that the mercury in the soil matrices could be extracted completely by 14% (v/v) HNO(3) with small quantity of HCl. The effects of the pressure within the digestion vessel and the sample mass were studied under the optimum conditions derived from the OAD. The extraction methods with optimum conditions were evaluated by determining mercury in NIST SRM 1645 River Sediment, NIES CRM No. 2 Pond Sediment and NRCC BCSS-1 Marine Sediment. Recoveries of 78-109% were achieved. Good mean recoveries of 95-98% were also obtained from real soil samples spiked with different species of mercury.     

Strain Energies in Homoatomic Nitrogen Clusters N(4), N(6), and N(8)

Strain energies and resonance energies can be obtained as the energy changes for appropriate homodesmotic reactions using ab initio calculated total energies as the energies of the reactants and products involved. Homodesmotic reactions conserve bond types and preserve valence environments at all atoms, requirements that favor the cancellation of basis set and electron correlation errors in the ab initio energies. In this paper we calculate strain energies and resonance energies for N(4), N(6), and N(8) clusters in a number of chemically significant but, for nitrogen, hypothetical structural forms. The nitrogen cluster strain energies are generally of the same order of magnitude as those of isostructural hydrocarbon clusters, and individual differences can be explained by using the ring strain additivity rule and recognizing the effect of the presence of lone pairs of electrons on nitrogen clusters but not on the hydrocarbons. Resonance energies of the nitrogen clusters are much smaller than those of the comparable aromatic hydrocarbons. The differences can be rationalized by considering the relative strengths of CC and NN single and double bonds. Strain and resonance energies of nitrogen clusters are compared with those previously reported for homoatomic clusters of phosphorus and arsenic. Trends through the series are remarkably similar, but strain energies for clusters from lower periods are progressively smaller. Strain and resonance have been important organizing concepts in organic chemistry for many years. Estimates of corresponding parameters for inorganic analogs are only now becoming available.     

Total Synthesis of d,l-Isospongiadiol: An Intramolecular Radical Cascade Approach to Furanoditerpenes

A stereoselective oxidative free-radical cyclization of beta-keto ester polyenes 7 and 19 has been accomplished as a one-step entry to the tricarbocyclic synthons 8and 21 which contain five and six stereogenic centers, respectively. These key synthons possessing an axial carboethoxy group at C-4 were ultimately converted to the spongian skeleton (8--> 14 and 21 --> 25 -->14). The synthesis of d,l-isospongiadiol (3) from the common intermediate 14 was realized after introduction of the 2alpha-hydroxy group in the spongian A-ring via epoxidation of silyl enol ether 28 and subsequent desilylation.     

Converse theorems for multidimensional Kantorovich operators

L _p [0, l]. . . - .

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Supported by National Science Foundation, Zhejiang Provincial Science Foundation of China, and Alexander von Humboldt Foundation of Germany.