Palladium-catalyzed hydrosilylation of ynones to access silicon-stereogenic silylenones by stereospecific aromatic interaction-assisted Si–H activation

Hydrosilylation is one of the most important reactions in synthetic chemistry and ranks as a fundamental method to access organosilicon compounds in industrial and academic processes. However, the enantioselective construction of chiral-at-silicon compounds via catalytic asymmetric hydrosilylation remained limited and difficult. Here we report a highly enantioselective hydrosilylation of ynones, a type of carbonyl-activated alkynes, using a palladium catalyst with a chiral binaphthyl phosphoramidite ligand. The stereospecific hydrosilylation of ynones affords a series of silicon-stereogenic silylenones with up to 94% yield, 20:1 regioselectivity and 98:2 enantioselectivity. The density functional theory(DFT) calculations were conducted to elucidate the reaction mechanism and origin of high degree of stereoselectivity, in which the powerful potential of aromatic interaction in this reaction is highlighted by the multiple C–H-π interaction and aromatic cavity-oriented enantioselectivitydetermining step during desymmetric functionalization of Si–H bond.     

有雨概率与分维数关系的初步研究

对武汉地区１９８２～１９９４年有雨分维数与有雨概率之间的关系进行了初步的分析和研究，并给出了研究结果．为今后修改降雨衰减预报模型作准备．     

喷漆室空调系统节能改造方案探讨

针对涂装车间喷漆室空调系统蒸汽浪费的问题,对喷漆室空调系统进行优化与节能改造,通过设置2套空调机组,采用自动控制系统,监控热力参数,实现了值班状态和生产状态的性能优化,预期空调系统年能源消耗将降低30%左右,节能效益可观。     

Decode‐and‐forward with full‐duplex relaying

This paper addresses the full‐duplex relaying. Some expressions for outage and average capacity of a two‐hop cooperative system with a full‐duplex relay are derived under an independent but not identically distributed Rayleigh fading environment. Using these expressions, we provide the performance analysis without Monte Carlo simulations. The impact of interference between the relay output and input is investigated. Copyright © 2011 John Wiley & Sons, Ltd.     

Solvent‐Assisted Low‐Temperature Crystallization of SnO2 Electron‐Transfer Layer for High‐Efficiency Planar Perovskite Solar Cells

A high‐quality polycrystalline SnO₂ electron‐transfer layer is synthesized through an in situ, low‐temperature, and unique butanol–water solvent‐assisted process. By choosing a mixture of butanol and water as a solvent, the crystallinity is enhanced and the crystallization temperature is lowered to 130 °C, making the process fully compatible with flexible plastic substrates. The best solar cells fabricated using these layers achieve an efficiency of 20.52% (average 19.02%) which is among the best in the class of planar n–i–p‐type perovskite (MAPbI₃) solar cells. The strongly reduced crystallization temperature of the materials allows their use on a flexible substrate, with a resulting device efficiency of 18%.     

基于数据预测的手机总全向灵敏度(TIS)的快速测试

手机总全向灵敏度（TIS）是OTA测试的重要指标之一。而基于CTIA的步进测试法,测试非常耗时。本文在深入研究基站发射功率和误码率关系的基础上,得出具有一定通用性的拟合函数,进而提出了一种基于数据预测的TIS测试方法。通过编写相应自动测试软件,实现快速测试。该法将大大提高测试效率,有很高的应用和推广价值。     

采用补硫技术的ZnS∶Mn蒸发膜的成份与结构的研究

本文介绍了电阻蒸发ZnS∶Mn薄膜在硫饱和蒸汽压下进行热处理的工艺。通过AES和XRD分析及带隙宽度的测试,结果表明:此法所制备的薄膜有较好的化学计量比,且具有电致发光薄膜所需要的六方结构。     

Relationship between microscopic and macroscopic structures of organic thin films for SHG

The experiments described in this paper were undertaken in order to obtain information about the relationship between the structure and non-linear optical properties (second-harmonic generation) of organic thin films. For this purpose, two closely related dyes, diones and tetrones, were compared, both of which are shown to have large hyperpolarisabilities. Their microscopic properties are investigated by conformational analysis and electron diffraction. It could be shown that detailed knowledge about the structure and the adjacent neighbour packing can be obtained from conformational analysis and electron diffraction in order to understand the non-linear optical properties of the two dyes.     

Promising Chemotherapy for Malignant Pediatric Brain Tumor in Recent Biological Insights

Brain tumors are the most widespread malignancies in children around the world. Chemotherapy plays a critical role in the treatment of these tumors. Although the current chemotherapy process has a remarkable outcome for a certain subtype of brain tumor, improving patient survival is still a major challenge. Further intensive treatment with conventional non-specific chemotherapy could cause additional adverse reactions without significant advancement in survival. Recently, patient derived brain tumor, xenograft, and whole genome analysis using deep sequencing technology has made a significant contribution to our understanding of cancer treatment. This realization has changed the focus to new agents, targeting the molecular pathways that are critical to tumor survival or proliferation. Thus, many novel drugs targeting epigenetic regulators or tyrosine kinase have been developed. These selective drugs may have less toxicity in normal cells and are expected to be more effective than non-specific chemotherapeutics. This review will summarize the latest novel targets and corresponding candidate drugs, which are promising chemotherapy for brain tumors according to the biological insights.     

光折变晶体中双光束耦合时间响应特性的研究

从描述双光束耦合规律的动态方程组出发．在考虑了光栅调制度变化后，给出了包含晶体固有参数、入射总光强、入射夹角、光强比等变量在内的写入响应时间解析表达式，实验结果与理论分析定性符合很好。