首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   35696篇
  免费   5260篇
  国内免费   3704篇
化学   18420篇
晶体学   267篇
力学   1922篇
综合类   217篇
数学   3414篇
物理学   11054篇
无线电   9366篇
  2024年   163篇
  2023年   921篇
  2022年   1179篇
  2021年   1445篇
  2020年   1388篇
  2019年   1279篇
  2018年   1153篇
  2017年   1136篇
  2016年   1583篇
  2015年   1601篇
  2014年   1912篇
  2013年   2547篇
  2012年   2926篇
  2011年   2923篇
  2010年   2090篇
  2009年   2104篇
  2008年   2226篇
  2007年   1901篇
  2006年   1827篇
  2005年   1559篇
  2004年   1088篇
  2003年   937篇
  2002年   827篇
  2001年   714篇
  2000年   745篇
  1999年   876篇
  1998年   745篇
  1997年   714篇
  1996年   649篇
  1995年   601篇
  1994年   523篇
  1993年   438篇
  1992年   379篇
  1991年   315篇
  1990年   275篇
  1989年   218篇
  1988年   160篇
  1987年   144篇
  1986年   100篇
  1985年   106篇
  1984年   71篇
  1983年   55篇
  1982年   59篇
  1981年   26篇
  1980年   16篇
  1979年   6篇
  1976年   1篇
  1959年   1篇
  1957年   7篇
  1936年   1篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
71.
10Gbit/s甚短距离传输系统接收模块研究   总被引:1,自引:0,他引:1  
本文研究了符合OIF—VSR4—01.0规范的甚短距离(VSR)并行光传输系统转换器集成电路,实现了接收部分转换器集成电路中帧同步、8B/10B解码、12路通道去斜移、检错纠错等模块的设计。在Altera的Stratix GX系列的FPGA上实现了接收部分转换器集成电路。仿真分析的结果表明所设计的各个模块能正确的实现接收部分转换器集成电路的功能,给出了仿真结果。  相似文献   
72.
It is a great challenge to effectively manage automated manufacturing systems in which automated guided vehicles (AGVs) are adopted to handle materials, because of such features as prior unknown AGV requests and changing AGV initial positions. This paper aims to find the shortest time routes, while both deadlock and blocking in AGV systems are avoided. It first finds the shortest routes based on a guide path layout, and then performs rerouting, whenever necessary, to avoid deadlock and blocking according to a deadlock avoidance policy, previously developed by the authors. The proposed approach can offer better solutions than existing methods. For some cases, it can find a solution, while the existing ones cannot  相似文献   
73.
The area covered by a mobile ad hoc network consists of obstacles that inhibit transmission and areas where communications can take place. Physical structures, such as buildings, that block transmission, or lakes, where forwarding nodes cannot be located, are permanent obstacles. Temporary obstacles are created as mobile nodes enter or leave an area. Our hypothesis is that the spaces between nearby obstacles are bottlenecks that inhibit the flows in the network. We partition the network into areas that are encompassed by obstacles and bottlenecks. All of the nodes in an area are treated as a single super node, and the bottlenecks between areas are the links between the super nodes. As individual nodes move, the flows and paths in the model change more slowly than the paths and flows between the individual nodes. We apply flow control algorithms to the model and perform admission control within a super node based on the flows that are assigned by the flow control algorithm. We apply the model to the Columbia University campus, and use max–min, fair bottleneck flow control to assign the flows. Our hypothesis is verified for this example.  相似文献   
74.
A new biodegradable starch graft copolymer, starch‐g‐poly(1,4‐dioxan‐2‐one), was synthesized through the ring‐opening graft polymerization of 1,4‐dioxan‐2‐one onto a starch backbone. The grafting reactions were conducted with various 1,4‐dioxan‐2‐one/starch feed ratios to obtain starch‐g‐poly(1,4‐dioxan‐2‐one) copolymers with various poly(1,4‐dioxan‐2‐one) graft structures. The microstructure of starch‐g‐poly(1,4‐dioxan‐2‐one) was characterized in detail with one‐ and two‐dimensional NMR spectroscopy. The effect of the feed composition on the resulting microstructure of starch‐g‐poly(1,4‐dioxan‐2‐one) was investigated. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3417–3422, 2004  相似文献   
75.
研究函数族的正规性定则是复变函数论中的一个重要且有意义的工作.引进多元K-拟全纯函数的定义,并给出了多元K-拟全纯函数族的一个正规定则.  相似文献   
76.
In an attempt to develop a low‐k interlayer dielectric, adamantane‐diphenyldiethynyl moiety containing oligomer is prepared. Oligomerization of 1,3,5,7‐tetrakis[3/4‐ethynylphenyl]adamantane ( 4 ) is accomplished by a Glaser–Hay oxidative coupling with 1,3,5‐triethynylbenzene and phenylacetylene end‐capping agent. The CHCl3 soluble oligomer is then thermally treated by step‐curing at 200, 300, 380, and 450 °C for 30 min at each temperature under nitrogen flow to render a shiny void‐free black polymer. TGA analysis indicates that the polymer is stable under nitrogen up to 500 °C with a marginal decomposition up to 800 °C. Solid‐state 13C NMR, Raman scattering, and FTIR are used to characterize the structure of the polymer. The polymer consists of amorphous carbon networks with the adamantane moieties and nanosized graphitic regions (clusters), which are generated from the thermal crosslinking of the diphenyldiethynyl units. It shows a remarkably low linear coefficient of thermal expansion (~25 ppm/°C), presumably due to the presence of the disordered graphitic structure. Its high density (~1.21 g/cm3), refractive index (~1.80 at 632 nm), and Young's modulus (~17.0 GPa) are also consistent with the interpretation. This study reveals important details about the effect of microscopic structure on the macroscopic properties of the highly crosslinked polymer. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 6909–6925, 2006  相似文献   
77.
In this paper, the authors have developed and implemented a decentralized decision-making strategy using field-programmable gate array (FPGA) technology as a prototype for an integrated controller of a microelectromechanical systems (MEMS) array for air-flow planar micromanipulation. The MEMS array was proposed to be integrated in a hybrid multichip module containing the FPGA-based controller. Algorithms and architectures, used for the decentralized control implementation and the hardware resource optimization, are described. A charge-coupled device camera was used to make each MEMS like an autonomous system when the distributed MEMS chip was tested. Finally, under air-flow condition, the FPGA-based decentralized control system successfully performed an object manipulation.  相似文献   
78.
We report a new route for the design of soluble phenylene vinylene (PV) based electroluminescent polymers bearing electron‐deficient oxadizole (OXD) and triazole (TZ) moieties in the main chains with the aryloxy linkage. Both series of the PV‐based polymers were prepared by Wittig reaction. By properly adjusting the OXD and/or TZ content through copolymerization, we can achieve an enhanced balance of hole‐ and electron injections, such that the device efficiency is significantly improved. Light‐emitting diodes fabricated from P1, P2, P3, P4, P5, P6, and P7 with the configuration of Indium–Tin Oxide (ITO)/Poly (styrene sulfonic acid) doped poly (ethylenedioxythiophene) (PEDOT)/polymer/Ca/Al, emit bright green light with the maximum peak around 500 nm. For the device using the optimal polymer (P4) as emitting layer, a maximum brightness of 1300 cd/m2 at 20 V and a maximum luminance efficiency of 0.325 cd/A can be obtained. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3469–3478, 2006  相似文献   
79.
2,2,6,6‐Tetramethyl‐4‐[d‐(+)‐10‐camphorsulfonyl]‐1‐piperidinyloxy was synthesized and used as a chiral nitroxide for the bulk polymerizations of styrene initiated with benzoyl peroxide (BPO), tetraethylthiuram disulfide (TETD), and thermal initiation. The results showed that the polymerizations proceeded in a controlled/living way; that is, the kinetics presented approximately first‐order plots, and the number‐average molecular weights of the polymers with narrow molecular weight distributions (weight‐average molecular weight/number‐average molecular weight) increased with the monomer conversion linearly. The molecular weight distributions in the case of thermal initiation were narrower than those in the case of BPO and TETD, whereas the polymerization rate with BPO or TETD as an initiator was obviously faster than that with thermal initiation. In addition, successful chain‐extension reactions were carried out, and the structures of the obtained polymers were characterized by gel permeation chromatography and 1H NMR. The specific rotations of the polymers were also measured by polarimetric analysis. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1522–1528, 2006  相似文献   
80.
A series of crystals of phenyl‐capped tetraaniline in the leucoemeraldine oxidation state were obtained at different isothermal temperatures and were observed directly under transmission electron microscope. The crystals obtained at higher temperatures exhibit more perfect structures than those obtained at lower temperatures. Both the lamella thickness and the crystal size increase with crystallization temperature. The tetraaniline is apt to form larger scale crystals under lower degree of supercooling. However, their crystal structures keep steady with the crystallization temperature. The tetramer was found to adopt a monoclinic lattice with unit cell parameter of a = 13.93 Å, b = 8.82 Å, c = 23.20 Å, and β = 95.03°, as determined using electron diffraction tilting method combined with wide‐angle X‐ray diffraction experiment. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 764–769, 2006  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号