全文获取类型
收费全文 | 101840篇 |
免费 | 15706篇 |
国内免费 | 11121篇 |
专业分类
化学 | 55365篇 |
晶体学 | 725篇 |
力学 | 4991篇 |
综合类 | 428篇 |
数学 | 8899篇 |
物理学 | 30569篇 |
无线电 | 27690篇 |
出版年
2024年 | 439篇 |
2023年 | 2515篇 |
2022年 | 3162篇 |
2021年 | 3986篇 |
2020年 | 3990篇 |
2019年 | 3735篇 |
2018年 | 3209篇 |
2017年 | 3084篇 |
2016年 | 4397篇 |
2015年 | 4658篇 |
2014年 | 5541篇 |
2013年 | 7020篇 |
2012年 | 8662篇 |
2011年 | 8535篇 |
2010年 | 6244篇 |
2009年 | 6084篇 |
2008年 | 6486篇 |
2007年 | 5802篇 |
2006年 | 5442篇 |
2005年 | 4618篇 |
2004年 | 3551篇 |
2003年 | 3133篇 |
2002年 | 3050篇 |
2001年 | 2593篇 |
2000年 | 2306篇 |
1999年 | 2342篇 |
1998年 | 1961篇 |
1997年 | 1751篇 |
1996年 | 1739篇 |
1995年 | 1454篇 |
1994年 | 1263篇 |
1993年 | 1023篇 |
1992年 | 928篇 |
1991年 | 796篇 |
1990年 | 637篇 |
1989年 | 447篇 |
1988年 | 397篇 |
1987年 | 304篇 |
1986年 | 279篇 |
1985年 | 239篇 |
1984年 | 179篇 |
1983年 | 129篇 |
1982年 | 96篇 |
1981年 | 76篇 |
1980年 | 77篇 |
1979年 | 39篇 |
1978年 | 35篇 |
1977年 | 46篇 |
1976年 | 39篇 |
1973年 | 29篇 |
排序方式: 共有10000条查询结果,搜索用时 9 毫秒
971.
972.
Kwang-Ting Liu 《中国化学会会志》1976,23(1):1-10
The proton magnetic resonance spectra of the two isomeric 2-norbornanols (I and II) and of eighteen of their methyl-substituted derivatives (III to XX) under the influence of tris(dipivalomethanato)europium, Eu(dpm)3, have been measured. In all cases linear relationships between the observed shifts and the molar ratios of Eu(dpm)3 to substrate were realized. The chemical shifts obtained from the extrapolation to zero concentration of Eu(dpm)3 are in good agreement with the observed values. The coupling constants were found to be essentially unaffected by Eu(dpm)3. Consequently, determination of a chemical shift by extrapolation or of a coupling constant from the shifted spectrum appears to be justified. Reassignments of a number of signals are discussed. Chemical shifts, normalized induced shifts, and coupling constants are tabulated. 相似文献
973.
强酸阳离子交换树脂催化性能的研究 总被引:1,自引:1,他引:1
通过叔丁醇脱水生成异丁烯的反应研究对比了国内外常见种类的凝胶型和大孔型强酸阳离子交换树脂的催化性能,并对树脂的性质,预处理方法,以及其用量和再生程度等因素对树脂催化活性的影响进行了研究。在此基础上,合成了具有较高催化活性的新型大孔强酸阳离子交换树脂。 相似文献
974.
(PdCl2—PVP)/Al2O3催化剂中Pd状态的探讨 总被引:3,自引:0,他引:3
氯化钯先锚定在聚乙烯吡咯烷酮上后进一步负载到Al_2O_3上所制的催化剂[简称(PdCl_2-PVP)/Al_2O_3]是一种活性、选择性高,稳定性好的烯烃、二烯烃和多烯烃加氢催化剂。本文结合加氢反应,使用XPS、FT-IR、电镜及用CO为探针的FT-IR,对这种催化剂进行了考察。实验说明,在这种催化剂中,钯的价态是在0—2之间。红外光谱在486cm~(-1)处有一微弱的小峰,说明存在Pd—N的配位键。催化剂中钯含量低时(0.2wt%)稳定性好,不吸附CO,活性中心是络合钯原子;当钯含量较高时(0.7wt%),催化剂的初活性虽不低,稳定性却较差,这种催化剂能吸附CO,IR谱图上仅在1919cm~(-1)处有CO桥式吸附态的伸缩振动。表明除络合钯原子外,还有聚集的钯金属存在。FT-IR尚表明,PVP在Al_2O_3上可能并非单纯的物理吸附。电镜结果表明,PVP在Al_2O_3上呈30—70(?)的微球状,(PdCl_2-PVP)/Al)_2O_3上的(PdCl_2-PVP)亦呈微球状,与前者无明显区别,这种催化剂中其活性中心是络合钯原子。 相似文献
975.
IntroductionAnionicclays(layereddoublehydroxides)areimportantlayeredmaterials.Thegeneralformulais[M2+(1-x)Mx3+(OH)2]x+An-x/nm... 相似文献
976.
茂锆载体催化剂下的乙烯/辛烯共聚及聚合物的^13C NMR研究 总被引:3,自引:0,他引:3
茂锆载体催化剂下的乙烯/辛烯共聚及聚合物的~(13)CNMR研究刘胜生,于广谦,黄葆同(中国科学院长春应用化学研究所长春130022)关键词茂锆载体催化剂,共聚,序列分布,~(13)CNMR由于茂锆催化剂具有高活性,单一活性中心等特点[1,2],并且能... 相似文献
977.
978.
The high-sensitivity determination of protein concentrations by the enhancement of Rayleigh light scattering of Arsenazo-DBN 总被引:1,自引:0,他引:1
A new Rayleigh light scattering (RLS) assay of protein is presented in this paper. At the optimum pH 4.10, the weak RLS of Arsenazo-DBN can be greatly enhanced by the addition of proteins due to the interaction between protein and Arsenazo-DBN. Based on this, the reactions of Arsenazo-DBN and proteins, including bovine serum albumin, human serum album, gamma-globulin, egg albumin, lysozyme and trypsin, were studied. A new quantitative determination method for proteins has been developed. The linear range for human serum albumin, for example, is 0.085-34.62 micrograms mL-1 with a detection limit of 44.8 ng mL-1. Besides high sensitivity, the method is characterized by good reproducibility, rapidity of reaction, good stability, and few interfering substances. The determination of the proteins in human serum and urine samples by this method give results very close to those obtained using Coomassie Brilliant Blue G-250 colorimetry, with relative standard deviations of 0.7-2.5%. 相似文献
979.
980.
In this work, surface-enhanced Raman scattering (SERS)-active gold substrates were first developed by combining the technologies of oxidation–reduction cycles (ORCs) and plasmas treatments in roughening metal substrates. First, a gold substrate was treated by argon plasmas. Then the treated gold substrate was further roughened by triangular-wave ORCs in an aqueous solution containing 0.1 M HCl. Encouragingly, the SERS of Rhodamine 6G (R6G) adsorbed on this roughened gold substrate modified by argon plasmas pretreatment exhibits a higher intensity by 10-fold of magnitude and a better resolution, as compared with the SERS of R6G adsorbed on an unmodified roughened gold substrate. Meanwhile, the probing concentration of R6G adsorbed on the modified substrate can be reduced by one order. It was also found that the pretreatment of argon plasmas demonstrates a positive effect on the (2 2 0) face of Au partly changing into the (1 1 1) face with the lowest surface energy after the ORCs roughening, which is contributive to the improved SERS observed. 相似文献