全文获取类型
收费全文 | 130247篇 |
免费 | 20678篇 |
国内免费 | 14594篇 |
专业分类
化学 | 68794篇 |
晶体学 | 1060篇 |
力学 | 6279篇 |
综合类 | 683篇 |
数学 | 11212篇 |
物理学 | 40470篇 |
无线电 | 37021篇 |
出版年
2024年 | 538篇 |
2023年 | 3232篇 |
2022年 | 3948篇 |
2021年 | 5145篇 |
2020年 | 5125篇 |
2019年 | 4595篇 |
2018年 | 4100篇 |
2017年 | 3959篇 |
2016年 | 5769篇 |
2015年 | 6121篇 |
2014年 | 7308篇 |
2013年 | 9217篇 |
2012年 | 11000篇 |
2011年 | 11145篇 |
2010年 | 8000篇 |
2009年 | 8080篇 |
2008年 | 8643篇 |
2007年 | 7688篇 |
2006年 | 7346篇 |
2005年 | 6118篇 |
2004年 | 4473篇 |
2003年 | 3720篇 |
2002年 | 3663篇 |
2001年 | 3130篇 |
2000年 | 2815篇 |
1999年 | 2961篇 |
1998年 | 2480篇 |
1997年 | 2264篇 |
1996年 | 2222篇 |
1995年 | 1868篇 |
1994年 | 1653篇 |
1993年 | 1391篇 |
1992年 | 1212篇 |
1991年 | 1029篇 |
1990年 | 789篇 |
1989年 | 593篇 |
1988年 | 471篇 |
1987年 | 375篇 |
1986年 | 366篇 |
1985年 | 305篇 |
1984年 | 190篇 |
1983年 | 143篇 |
1982年 | 116篇 |
1981年 | 76篇 |
1980年 | 52篇 |
1979年 | 30篇 |
1978年 | 7篇 |
1974年 | 5篇 |
1973年 | 3篇 |
1957年 | 31篇 |
排序方式: 共有10000条查询结果,搜索用时 9 毫秒
31.
The thermal and thermo-elastic-plastic response of newly developed ceramic-metalfunctionally graded materials under a thermal shock load is studied.The materials are heated at the ce-ramic surface with a sudden high-intensity heat flux input,and cooled at the metal surface with aflowing liquid nitrogen.Emphasis is placed on two aspects:(1)the influence of the graded composi-tion of the materials on the temperature and stress response;and(2)the optimum design of the gradedcomposition from a unified viewpoint of the heat insulation property and stress relaxation property.Moreover,a comparison between the thermoelastic stress and the thermo-elastic-plastic stress is alsomade to indicate the plasticity effect. 相似文献
32.
Lizeng Wang Chengsong Ma Xiaoli Zhang Yibing Ren Yong Yu 《Fresenius' Journal of Analytical Chemistry》1995,351(7):689-691
The electrochemical behavior of the copper-tyrosine complex has been studied by linear-sweep adsorption voltammetry. In 0.02 mol/L Na2HPO4 buffer solution (pH=9.6), the complex can be adsorped on a hanging mercury drop electrode and reduced at a peak potential of about –0.42 V (vs. SCE). The secondary derivative peak height is linear proportional to the concentration of tyrosine in the range 1.0×10–7–5.0×10–5 mol/L. The detection limit is 5×10–8 mol/L.Project supported by the Provincial Science Foundation of Shandong Province 相似文献
33.
本文介绍了一种计算机存储系统中的单向错误检测码,系统构成采用9位字节,其中8位数据位,1位校验位,并使用一个单独的附加奇偶校验字节。单向错误检测码有两类,一类每个字包含固定的奇偶校验位;另一类每个字节包含的检验位的构成方式是任意的。 相似文献
34.
35.
In this paper, we present efficient VLSI architectures for full-search block-matching motion estimation (BMME) algorithm. Given a search range, we partition it into sub-search arrays called tiles. By fully exploiting data dependency within a tile, efficient VLSI architectures can be obtained. Using the proposed VLSI architectures, all the block-matchings in a tile can be processed in parallel. All the tiles within a search range can be processed serially or concurrently depending on various requirements. With the consideration of processing speed, hardware cost, and I/O bandwidth, the optimal tile size for a specific video application is analyzed. By partitioning a search range into tiles with appropriate size, flexible VLSI designs with different throughput can be obtained. In this way, cost effective VLSI designs for a wide range of video applications, from H.261 to HDTV, can be achieved. 相似文献
36.
A novel method is presented for designing FIR linear phase filters with discrete coefficients using Hopfield neural networks. The proposed procedure is based on the minimisation of the energy function of the Hopfield neural network, and can produce a good solution to the design of FIR linear phase filters with discrete coefficients 相似文献
37.
To incorporate an acceptor type polythiophene segment onto a supramolecular block copolymer for potential light harvesting applications, effective synthetic routes for the end‐functionalized and acceptor‐substituted polythiophenes are critical. The Ullmann coupling reaction can be utilized to obtain electron‐deficient polythiophenes and to attach terminal thiophene units that carry functional groups. In this article, the reactions involving a 2,5‐dibromothiophene monomer containing an electron‐withdrawing fluorinated ester and 5‐bromo‐2‐thiophenecarboxaldehyde (the end‐capper) were studied in detail. It was found that the Ullmann coupling reaction of the dibromide is very fast (completed in a few minutes) and the terminal bromine group does not survive long under the reaction condition. These findings lead to the development of an effective procedure for aldehyde end‐capping of electron‐deficient polythiophenes. Polymers with molecular weights around 4000 Da are routinely obtained. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 41–47, 2007 相似文献
38.
Jing Zhang Dan Shan Shaolin Mu 《Journal of polymer science. Part A, Polymer chemistry》2007,45(23):5573-5582
A copolymer, poly(aniline‐co‐o‐aminophenol), was prepared chemically by using ammonium peroxydisulfate as an oxidant. The monomer concentration ratio of o‐aminophenol to aniline strongly influences the copolymerization rate and properties of the copolymer. The optimum composition of a mixture for the chemical copolymerization consisted of 0.3 M aniline, 0.021 M o‐aminophenol, 0.42 M ammonium peroxydisulfate, and 2 M H2SO4. The result of cyclic voltammograms in a potential region of ?0.20 to 0.80 V (vs.SCE) indicates that the electrochemical activity of the copolymer prepared under the optimum condition is similar to that of polyaniline in more acid solutions. However, the copolymer still holds the good electrochemical activity until pH 11.0. Therefore, the pH dependence of the electrochemical property of the copolymer is improved, compared with poly(aniline‐co‐o‐aminophenol) prepared electrochemically, and is much better than that of polyaniline. The spectra of IR and 1H NMR confirm that o‐aminophenol units are included in the copolymer chain, which play a key role in extending the usable pH region of the copolymer. The visible spectra of the copolymers show that a high concentration ratio of o‐aminophenol to aniline in a mixture inhibits the chain growth. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5573–5582, 2007 相似文献
39.
Sung‐Fu Hsu Tzong‐Ming Wu Chien‐Shiun Liao 《Journal of Polymer Science.Polymer Physics》2006,44(23):3337-3347
Poly(3‐hydroxybutyrate) (PHB)/layered double hydroxides (LDHs) nanocomposites were prepared by mixing PHB and poly(ethylene glycol) phosphonates (PEOPAs)‐modified LDH (PMLDH) in chloroform solution. Both X‐ray diffraction data and TEM micrographs of PHB/PMLDH nanocomposites indicate that the PMLDHs are randomly dispersed and exfoliated into the PHB matrix. In this study, the effect of PMLDH on the isothermal crystallization behavior of PHB was investigated using a differential scanning calorimeter (DSC) and polarized optical microscopy. Isothermal crystallization results of PHB/PMLDH nanocomposites show that the addition of 2 wt % PMLDH into PHB induced more heterogeneous nucleation in the crystallization significantly increasing the crystallization rate and reducing their activation energy. By adding more PMLDH into the PHB probably causes more steric hindrance of the diffusion of PHB, reducing the transportation ability of polymer chains during crystallization, thus increasing the activation energy. The correlation among crystallization kinetics, melting behavior and crystalline structure of PHB/PMLDH nanocomposites can also be discussed. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3337–3347, 2006 相似文献
40.
An improvement has been made to couple isoelectric focusing (IEF) sample injection and capillary zone electrophoresis in an untreated fused silica capillary. Electroosmotic flow is efficiently prevented by simply using a rubber block at the outlet end of the capillary during IEF sample injection. The experimental conditions that affect the concentration effect are discussed. A concentration enhancement factor of over 100-fold can be easily obtained for two model proteins: lysozyme and ribonuclease A. 相似文献