Efficient synthesis of an aldehyde‐capped polythiophene containing fluorinated electron‐withdrawing groups

To incorporate an acceptor type polythiophene segment onto a supramolecular block copolymer for potential light harvesting applications, effective synthetic routes for the end‐functionalized and acceptor‐substituted polythiophenes are critical. The Ullmann coupling reaction can be utilized to obtain electron‐deficient polythiophenes and to attach terminal thiophene units that carry functional groups. In this article, the reactions involving a 2,5‐dibromothiophene monomer containing an electron‐withdrawing fluorinated ester and 5‐bromo‐2‐thiophenecarboxaldehyde (the end‐capper) were studied in detail. It was found that the Ullmann coupling reaction of the dibromide is very fast (completed in a few minutes) and the terminal bromine group does not survive long under the reaction condition. These findings lead to the development of an effective procedure for aldehyde end‐capping of electron‐deficient polythiophenes. Polymers with molecular weights around 4000 Da are routinely obtained. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 41–47, 2007     

Chemical synthesis and electric properties of the conducting copolymer of aniline and o‐aminophenol

A copolymer, poly(aniline‐co‐o‐aminophenol), was prepared chemically by using ammonium peroxydisulfate as an oxidant. The monomer concentration ratio of o‐aminophenol to aniline strongly influences the copolymerization rate and properties of the copolymer. The optimum composition of a mixture for the chemical copolymerization consisted of 0.3 M aniline, 0.021 M o‐aminophenol, 0.42 M ammonium peroxydisulfate, and 2 M H₂SO₄. The result of cyclic voltammograms in a potential region of ?0.20 to 0.80 V (vs.SCE) indicates that the electrochemical activity of the copolymer prepared under the optimum condition is similar to that of polyaniline in more acid solutions. However, the copolymer still holds the good electrochemical activity until pH 11.0. Therefore, the pH dependence of the electrochemical property of the copolymer is improved, compared with poly(aniline‐co‐o‐aminophenol) prepared electrochemically, and is much better than that of polyaniline. The spectra of IR and ¹H NMR confirm that o‐aminophenol units are included in the copolymer chain, which play a key role in extending the usable pH region of the copolymer. The visible spectra of the copolymers show that a high concentration ratio of o‐aminophenol to aniline in a mixture inhibits the chain growth. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5573–5582, 2007     

Improving communication energy efficiency in wireless networks powered by Renewable energy sources

Energy efficiency is an important issue in wireless networks where the nodes are powered by batteries. In this work, we analyze the energy consumption in one-transmitter-multiple-receiver communication and develop scheduling schemes to improve energy efficiency at the transmitter. Our focus is on systems powered by a renewable energy source such as solar power. We consider an environment where both energy and time to access the wireless channel and transmit data are limited, and data destined for different receivers have different values and incur different energy costs. We present optimal scheduling algorithms that selectively transmit data at calculated rates so that the throughput or the total transmission value is maximized under given time limits and energy constraints.     

广义频率响应函数的鲁棒建模新方法

针对基于非线性谱分析的故障诊断技术的需要,研究了非线性系统的广义频率响应函数的鲁棒在线建模方 法。首先将次元分析算法应用于Volterra级数模型的辨识,并通过对此算法的修正,得到了一种改进的Volterra系统的鲁 棒辨识算法。对其鲁棒性能进行的分析表明,改进算法的鲁棒抗噪性能被明显提高。在此基础上,提出了一种广义频率响 应函数的两步鲁棒建模新方法。仿真实验表明,该方法具有良好的鲁棒收敛性能,能够有效解决GFRF的在线建模问题。     

基于预前控制异步电机直接转矩控制方案的研究

在传统异步电动机直接转矩控制方案中，由于负载的变化规律不可预测，因此其常会带来较大的开关频率的变化，为此提出了一种基于预前控制的异步电动机直接转矩控制的方法。该方法依据前一个周期的磁链和转矩误差，对下一个开关周期所应施加到异步电动机的定子电压矢量进行预测，然后借助空间矢量PWM的方法，合成此开关电压矢量。样机实验结果表明，该方案不但能维持逆变器的开关频率基本恒定，而且还具有比传统直接转矩控制更为优良的动静态特性。     

Mobility Influences on the Capacity of Wireless Cellular Networks

Capacity has always been a major concern in wireless networks. This letter studies the impact of mobility on the overall system capacity in wireless cellular networks. In this letter, we present a simple system model which we developed to capture the inherent relationships among system capacity, new call blocking probability, handoff dropping probability, call terminating probability, and bandwidth utilization rate. We investigate the complex relationship between mobility and capacity‐related parameters. Through simulation, we demonstrate that mobility has a significant impact on capacity and is reversely proportional to the bandwidth reserved for handoff traffic.     

光波分复用技术及其应用

分析了波分复用系统的组成原理和几种分类方式,最后给出了一些基本应用形式。     

PMD Measurement of Hollow-Core Photonic Bandgap Fiber by Investigating Power Penalty of Optically Generated Microwave Signals

A simple method based on carrier suppression modulation for measuring first-order polarization-mode dispersion of hollow-core photonic bandgap fiber (HC-PBGF) is proposed and investigated. By adjusting the incident optical wavelength and measuring the power penalty of optically generated microwave signals, the wavelength-dependent differential group delay (DGD) in HC-PBGF can be obtained. Moreover, this proposed method is chromatic-dispersion-insensitive. The experimental results indicate that a segment of 20-m HC-PBGF exhibits highly birefringent DGD of 25, 59, and 84 ps with measurement error less than 2 ps for the incident optical wavelength of 1560, 1575, and 1580 nm, respectively     

Isoelectric focusing sample injection for capillary zone electrophoresis in a fused silica capillary.

An improvement has been made to couple isoelectric focusing (IEF) sample injection and capillary zone electrophoresis in an untreated fused silica capillary. Electroosmotic flow is efficiently prevented by simply using a rubber block at the outlet end of the capillary during IEF sample injection. The experimental conditions that affect the concentration effect are discussed. A concentration enhancement factor of over 100-fold can be easily obtained for two model proteins: lysozyme and ribonuclease A.     

Optical Endless Polarization Stabilization at 9 krad/s With FPGA-Based Controller

We demonstrate endless polarization stabilization with a control speed of up to 9 krad/s, over random Poincare sphere trajectories. These are in total >35 Mrad long, are composed in particular of difficult-to-track circles with all radii and orientations, and thereby include all possible worst cases. The maximum polarization mismatch and relative intensity errors are 0.13 rad and 0.43%, respectively. The controller runs on a field-programmable gate array and uses a commercial multistage LiNbO₃ polarization transformer as the control device.