全文获取类型
收费全文 | 221篇 |
免费 | 6篇 |
专业分类
化学 | 125篇 |
晶体学 | 3篇 |
力学 | 1篇 |
数学 | 30篇 |
物理学 | 38篇 |
无线电 | 30篇 |
出版年
2024年 | 1篇 |
2023年 | 4篇 |
2022年 | 7篇 |
2021年 | 11篇 |
2020年 | 4篇 |
2019年 | 7篇 |
2018年 | 5篇 |
2017年 | 7篇 |
2016年 | 14篇 |
2015年 | 8篇 |
2014年 | 12篇 |
2013年 | 14篇 |
2012年 | 19篇 |
2011年 | 20篇 |
2010年 | 11篇 |
2009年 | 8篇 |
2008年 | 11篇 |
2007年 | 11篇 |
2006年 | 13篇 |
2005年 | 6篇 |
2004年 | 8篇 |
2003年 | 3篇 |
2002年 | 1篇 |
2001年 | 2篇 |
2000年 | 7篇 |
1999年 | 3篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1995年 | 2篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1984年 | 1篇 |
排序方式: 共有227条查询结果,搜索用时 15 毫秒
221.
Murata H Miyazaki Y Inaba A Paduan-Filho A Bindilatti V Jr NF Delen Z Lahti PM 《Journal of the American Chemical Society》2008,130(1):186-194
The title radical (F4BImNN) is a stable nitronylnitroxide that forms hydrogen-bonded NH... ON chains in the solid state. The chains assemble the F4BImNN molecules to form stacked contacts between the radical groups, in a geometry that is expected to exhibit ferromagnetic (FM) exchange based on spin polarization (SP) models. The experimental magnetic susceptibility of F4BImNN confirms the expectation, showing 1-D Heisenberg chain FM exchange behavior over 1.8-300 K with an intrachain exchange constant of Jchain/k = +22 K. At lower temperatures, ac magnetic susceptibility and variable field heat capacity measurements show that F4BImNN acts as a quasi-1-D ferromagnet. The dominant ferromagnetic exchange interaction is attributable to overlap between spin orbitals of molecules within the hydrogen-bonded chains, consistent with the SP model expectations. The chains appear to be antiferromagnetically exchange coupled, giving cusps in the ac susceptibility and zero field heat capacity at lower temperatures. The results indicate that the sample orders magnetically at about 0.7 K. The magnetic heat capacity ordering cusp shifts to lower temperatures as external magnetic field increases, consistent with forming a bulk antiferromagnetic phase below a Néel temperature of TN(0) = 0.72 K, with a critical field of Hc approximately 1800 Oe. The interchain exchange is estimated to be zJ/k congruent with (-)0.1 K. 相似文献
222.
A highly sensitive micelle-mediated extraction methodology for the preconcentration of trace levels of vanadium as a prior step to its determination by flame atomic absorption spectrometry (FAAS) has been developed. Vanadium was complexed with 1-(2-pyridylazo)-2-naphthol (PAN) and hydrogen peroxide in acidic medium (0.2 mol L−1 phosphoric acid) using Triton X-100 as surfactant and quantitatively extracted into a small volume of the surfactant-rich phase after centrifugation. The color reaction of vanadium ions with hydrogen peroxide and PAN in phosphoric acid medium is highly selective. The chemical variables affecting cloud point extraction (CPE) were evaluated and optimized. The R.S.D. for 5 replicate determinations at the 20 μg L−1 V level was 3.6%. The calibration graph using the preconcentration system for vanadium was linear with a correlation coefficient of 0.99 at levels near the detection limits up to at least 0.6 μg L−1. The method has good sensitivity and selectivity and was applied to the determination of trace amounts of vanadium in water samples with satisfactory result. The proposed method is a rare application of CPE-atomic spectrometry to vanadium assay, and is superior to most other similar methods, because its useful pH range is in the moderately acidic range achieved with phosphoric acid. At this pH, many potential interferents are not chelated with PAN, and iron(III) as the major interferent is bound in a stable phosphate complex. 相似文献
223.
Based on a survey of participants in Egypt's Tahrir Square protests, we demonstrate that social media in general, and Facebook in particular, provided new sources of information the regime could not easily control and were crucial in shaping how citizens made individual decisions about participating in protests, the logistics of protest, and the likelihood of success. We demonstrate that people learned about the protests primarily through interpersonal communication using Facebook, phone contact, or face‐to‐face conversation. Controlling for other factors, social media use greatly increased the odds that a respondent attended protests on the first day. Half of those surveyed produced and disseminated visuals from the demonstrations, mainly through Facebook. 相似文献
224.
We have investigated the effect of counter-rotating terms on the dynamics of entanglement and quantum discord between two identical atoms interacting with a lossy single mode cavity field for a system initially in a vacuum state. The counter-rotating terms are found to lead to steady states in the long-time limit which can have high quantum discord, but have no entanglement. The effect of cavity decay rate on this steady-state quantum discord has been also investigated, surprisingly, the increase in cavity decay rate is found to enhance the steady-state quantum discord. 相似文献
225.
Marianna Tosato Marco Verona Chiara Favaretto Marco Pometti Giordano Zanoni Fabrizio Scopelliti Francesco Paolo Cammarata Luca Morselli Zeynep Talip Nicholas P. van der Meulen Valerio Di Marco Mattia Asti 《Molecules (Basel, Switzerland)》2022,27(13)
Copper radioisotopes are generally employed for cancer imaging and therapy when firmly coordinated via a chelating agent coupled to a tumor-seeking vector. However, the biologically triggered Cu2+-Cu+ redox switching may constrain the in vivo integrity of the resulting complex, leading to demetallation processes. This unsought pathway is expected to be hindered by chelators bearing N, O, and S donors which appropriately complements the borderline-hard and soft nature of Cu2+ and Cu+. In this work, the labelling performances of a series of S-rich polyazamacrocyclic chelators with [64Cu]Cu2+ and the stability of the [64Cu]Cu-complexes thereof were evaluated. Among the chelators considered, the best results were obtained with 1,7-bis [2-(methylsulfanyl)ethyl]-4,10,diacetic acid-1,4,7,10-tetraazacyclododecane (DO2A2S). DO2A2S was labelled at high molar activities in mild reaction conditions, and its [64Cu]Cu2+ complex showed excellent integrity in human serum over 24 h. Biodistribution studies in BALB/c nude mice performed with [64Cu][Cu(DO2A2S)] revealed a behavior similar to other [64Cu]Cu-labelled cyclen derivatives characterized by high liver and kidney uptake, which could either be ascribed to transchelation phenomena or metabolic processing of the intact complex. 相似文献
226.
Anna-Maria Tsirigoni Melis Goktas Zeynep Atris Angelo Valleriani Ana Vila Verde Kerstin G. Blank 《Macromolecular bioscience》2023,23(5):2200563
Coiled coils (CCs) are key building blocks of biogenic materials and determine their mechanical response to large deformations. Of particular interest is the observation that CC-based materials display a force-induced transition from α-helices to mechanically stronger β-sheets (αβT). Steered molecular dynamics simulations predict that this αβT requires a minimum, pulling speed-dependent CC length. Here, de novo designed CCs with a length between four to seven heptads are utilized to probe if the transition found in natural CCs can be mimicked with synthetic sequences. Using single-molecule force spectroscopy and molecular dynamics simulations, these CCs are mechanically loaded in shear geometry and their rupture forces and structural responses to the applied load are determined. Simulations at the highest pulling speed (0.01 nm ns−1) show the appearance of β-sheet structures for the five- and six-heptad CCs and a concomitant increase in mechanical strength. The αβT is less probable at a lower pulling speed of 0.001 nm ns−1 and is not observed in force spectroscopy experiments. For CCs loaded in shear geometry, the formation of β-sheets competes with interchain sliding. β-sheet formation is only possible in higher-order CC assemblies or in tensile-loading geometries where chain sliding and dissociation are prohibited. 相似文献
227.
The effect of melt temperature on the phase behavior and preferential orientation development in Nylon 6/montmorillonite nanocomposites were investigated at melt spinning temperatures ranging from 230° to 250°C. The fibers were found to exhibit mostly γ crystalline form that is typical of Nylon 6 filled with montmorillonite nanoparticles. At higher take-up speeds α-crystals begin to appear in the crystalline phase. The presence of nanoparticles was found to impart substantial chain orientation levels even at low to moderate take up speeds reaching a plateau at moderate take up speeds. This was attributed to the increased spin line stress in the presence of nanoparticles that increase the overall viscosity due to their large contact areas with the polymer chains. This increased spinline tension was found to cause fiber breakup at moderate speeds. Increasing melt temperature from 230° to 250°C alleviated this problem. 相似文献