全文获取类型
收费全文 | 220篇 |
免费 | 6篇 |
专业分类
化学 | 124篇 |
晶体学 | 3篇 |
力学 | 1篇 |
数学 | 30篇 |
物理学 | 38篇 |
无线电 | 30篇 |
出版年
2024年 | 1篇 |
2023年 | 4篇 |
2022年 | 6篇 |
2021年 | 11篇 |
2020年 | 4篇 |
2019年 | 7篇 |
2018年 | 5篇 |
2017年 | 7篇 |
2016年 | 14篇 |
2015年 | 8篇 |
2014年 | 12篇 |
2013年 | 14篇 |
2012年 | 19篇 |
2011年 | 20篇 |
2010年 | 11篇 |
2009年 | 8篇 |
2008年 | 11篇 |
2007年 | 11篇 |
2006年 | 13篇 |
2005年 | 6篇 |
2004年 | 8篇 |
2003年 | 3篇 |
2002年 | 1篇 |
2001年 | 2篇 |
2000年 | 7篇 |
1999年 | 3篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1995年 | 2篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1984年 | 1篇 |
排序方式: 共有226条查询结果,搜索用时 500 毫秒
151.
152.
JPC – Journal of Planar Chromatography – Modern TLC - The study reported in this paper was aimed to develop an accurate, specific, and precise high-performance thin-layer chromatography... 相似文献
153.
The magnetic environments of Cu2+-doped potassium hydrogen citrate (C6H7KO7) complex have been identified by electron paramagnetic resonance (EPR) technique. The angular variation of the EPR spectra
has shown that three different Cu2+ complexes are located in different chemical environments, and each environment contains one magnetic Cu2+ site occupying substantial positions in the lattice and showing a very high angular dependence. The principal g and the hyperfine structure parameter (A) values of three sets of Cu2+ complex groups are determined. The covalency parameter, mixing coefficients and Fermi-contact term of the complex are obtained,
and the ground-state wave function of the Cu2+ ion in the lattice has been constructed. 相似文献
154.
Demirbilek ME Demirbilek M Karahaliloğlu Z Erdal E Vural T Yalçın E Sağlam N Denkbaş EB 《Applied biochemistry and biotechnology》2011,164(6):780-792
Oxidative stress may produce high level of reactive oxygen species (ROS) following cell exposure to endogenous and exogenous
factors. Recent experiments implicate oxidative stress as playing an essential role in cytotoxicity of many materials. The
aim of this study was to measure intracellular malondialdehyde (MDA), advanced oxidation protein product (AOPP) levels, and
superoxide dismutase (SOD) activities of L929 fibroblasts cultured on PDLLA, polyethylene glycol (PEG), or ethylenediamine
(EDA) grafted PDLLA by plasma polymerization method. Cell proliferation on these scaffolds was studied by 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl
tetrazolium bromide assay. The study showed that MDA, AOPP levels, and SOD activities in L929 fibroblast cells cultured on
all scaffolds were significantly different compared to the control group and each other. The highest MDA (0.42 ± 0.76 nmol/mg
protein), AOPP (14.99 ± 4.67 nmol/mg protein) levels, and SOD activities (7.49 ± 3.74 U/mg protein) were observed in cells
cultured on non-modified scaffolds; meanwhile, the most cell proliferation was obtained in EDA-modified scaffolds (MDA 0.15 ± 0.14 nmol/mg
protein, AOPP 13.12 ± 3.86 nmol/mg protein, SOD 4.82 ± 2.64 U/mg protein). According to our finding, EDA- or PEG-modified
scaffolds are potentially useful as suitable biomaterials in tissue engineering. 相似文献
155.
Koşar A Şeşen M Oral O Itah Z Gozuacik D 《IEEE transactions on bio-medical engineering》2011,58(5):1337-1346
This paper presents a study that investigates the destructive energy output resulting from hydrodynamic bubbly cavitation in microchannels and its potential use in biomedical applications. The research performed in this study includes results from bubbly cavitation experiments and findings showing the destructive effects of bubbly cavitating flow on selected solid specimens and live cells. The bubbles generated by hydrodynamic cavitation are highly destructive at the surfaces of the target medium on which they are carefully focused. The resulting destructive energy output could be effectively used for biomedical treatments, such as destroying kidney stones (renal calculi) or killing cancer cells. Motivated by this potential, the cavitation damage to cancerous cells and material removal from chalk pieces (which possess similar material properties as some kidney stones) was investigated. Our results showed that cavitation could induce damage both on chalk pieces and leukemia/lymphoma cells. We discovered that hydrodynamic cavitation exposure had early and delayed effects on cancer cell survival. Hence, the potential of hydrodynamic bubbly cavitation generated at the microscale for biomedical treatments was revealed using the microchannel configuration as a microorifice (with an inner diameter of 147 μm and a length of 1.52 cm), which acts as the source of bubbly cavitating flows. 相似文献
156.
Hatice Başpınar Küçük Zeynep Banu Salt Emel Mataracı Kara Aysema Sayık Mehan Ayşe Sergüzel Yusufoğlu 《Phosphorus, sulfur, and silicon and the related elements》2013,188(9):903-908
AbstractA series of novel 1,2,3-thiadiazoles and 1,2,3-selenadiazoles having a long alkyl chain were synthesized by reacting semicarbazones with SOCl2 and SeO2, respectively. The structures of the target compounds 5–12 were confirmed by spectroscopy (IR, 1H NMR, 13C NMR, and MS) and elemental analysis. Their antibacterial and antifungal activities were evaluated against six bacteria (Pseudomonas aeruginosa, Escherichia coli, Klebsiella pneumoniae, Proteus mirabilis, Enterococcus faecalis, Staphylococcus epidermidis, Staphylococcus aureus) and three fungi (Candida albicans, Candida parapsilosis, Candida tropicalis). The results of bioassays indicated that the compounds 5-Dodecyl-4-(4-methoxy-phenyl)-[1-3]selenadiazole (7), 4-Methyl-5-tetradecyl-[1-3]selenadiazole (8) and 5-Dodecyl-4-(4-methoxy-phenyl)-[1-3]thiadiazole (11) displayed moderate antibacterial activity against S. Epidermidis. On the other hand, according to antifungal screening results, compounds 5-Dodecyl-4-phenyl-[1-3]selenadiazole (5), 4-p-Tolyl-5-undecyl-[1-3]selenadiazole (6), and 5-Dodecyl-4-(4-methoxy-phenyl)-[1-3]selenadiazole (7) exhibited significant antifungal activities studied yeast strains. 相似文献
157.
Ozcan Altintas Ismail Yilmaz Gurkan Hizal Umit Tunca 《Journal of polymer science. Part A, Polymer chemistry》2006,44(10):3242-3249
Poly(methyl methacrylate)‐b‐polystyrene (PMMA‐b‐PS) containing a benzo‐15‐crown‐5 unit at the junction point was prepared by combining atom transfer radical polymerization and nitroxide‐mediated radical polymerization. For this purpose, 6,7,9,10,12,13,15,16‐octahydro‐5,8,11,14,17‐pentaoxa‐benzocyclopentadecene‐2‐carboxylic acid 3‐(2‐bromo‐2‐methyl‐propionyloxy)‐2‐methyl‐2‐[2‐phenyl‐2‐(2,2,6,6‐tetramethyl‐piperidin‐1‐yloxy)‐ethoxycarbonyl]‐propyl ester ( 3 ) was synthesized and used as an initiator in atom transfer radical polymerization of methyl methacrylate in the presence of CuCl and pentamethyldiethylenetriamine at 60°C. A linear behavior was observed in both plots of ln([M]0/[M]) versus time and Mn,GPC versus conversion indicating that the polymerization proceeded in a controlled/living manner. Thus obtained PMMA precursor was used as a macroinitiator in nitroxide‐mediated radical polymerization of styrene (St) at 125°C to give well‐defined PMMA‐b‐PS with crown ether per chain. Kinetic data were also obtained for copolymerization. Moreover, potassium picrate (K+ picrate) complexation of 3 and PMMA‐b‐PS copolymer was studied. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3242–3249, 2006 相似文献
158.
F. Zeynep Sargut 《Operations Research Letters》2007,35(4):549-557
We study a new class of capacitated economic lot-sizing problems. We show that the problem is NP-hard in general and derive a fully polynomial-time approximation algorithm under mild conditions on the cost functions. Furthermore, we develop a polynomial-time algorithm for the case where all cost functions are concave. 相似文献
159.
Ozcan Altintas A. Levent Demirel Gurkan Hizal Umit Tunca 《Journal of polymer science. Part A, Polymer chemistry》2008,46(17):5916-5928
Two samples of dendrimer‐like miktoarm star terpolymers: (poly(tert‐butyl acrylate))3‐(polystyrene‐poly(ε‐caprolactone))3 (PtBA)3‐(PS‐PCL)3, and (PS)3‐(PtBA‐poly(ethylene glycol)3 were prepared using efficient Cu catalyzed Huisgen cycloaddition (click reaction). As a first step, azido‐terminated 3‐arm star polymers PtBA and PS as core (A) were synthesized by atom transfer radical polymerization (ATRP) of tBA and St, respectively, followed by the conversion of bromide end group to azide. Secondly, PS‐PCL and PtBA‐PEG block copolymers with alkyne group at the junction as peripheral arms (B‐C) were obtained via multiple living polymerization mechanisms such as nitroxide mediated radical polymerization (NMP) of St, ring opening polymerization (ROP) of ε‐CL, ATRP of tBA. Thus obtained core and peripheral arms were linked via click reaction to give target (A)3‐(B‐C)3 dendrimer‐like miktoarm star terpolymers. (PtBA)3‐(PS‐PCL)3 and (PS)3‐(PEG‐PtBA)3 have been characterized by GPC, DSC, AFM, and SAXS measurements. (PtBA)3‐(PS‐PCL)3 did not show any self‐organization with annealing due to the miscibility of the peripheral arm segments. In contrast, the micro‐phase separation of the peripheral arm segments in (PS)3‐(PtBA‐PEG)3 resulted in self‐organized phase‐separated morphology with a long period of ~ 13 nm. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 5916–5928, 2008 相似文献
160.
Ozcan Altintas Burcu Yankul Gurkan Hizal Umit Tunca 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3588-3598
The preparation of 3‐miktoarm star terpolymers using nitroxide mediated radical polymerization (NMP), ring opening polymerization (ROP), and click reaction [3 + 2] are carried out by applying two types of one‐pot technique. In the first one‐pot technique, NMP of styrene (St), ROP of ε‐caprolactone (ε‐CL), and [3 + 2] click reaction (between azide end‐functionalized poly(ethylene glycol) (PEG‐N3)/or azide end‐functionalized poly(methyl methacrylate) (PMMA‐N3) and alkyne) are carried out in the presence of 2‐(hydroxymethyl)‐2‐methyl‐3‐oxo‐3‐(2‐phenyl‐2‐(2,2,6,6‐tetramethylpiperidin‐1‐yloxy)ethoxy) propyl pent‐4‐ynoate, 2 , as an initiator for 48 h at 125 °C (one‐pot/one‐step). As a second technique, NMP of St and ROP of ε‐CL were conducted using 2 as an initiator for 20 h at 125 °C, and subsequently PEG‐N3 or azide end‐functionalized poly(tert‐butyl acrylate (PtBA‐N3) was added to the polymerization mixture, followed by a click reaction [3 + 2] for 24 h at room temperature (one‐pot/two‐step). The 3‐miktoarm star terpolymers, PEG‐poly(ε‐caprolactone)(PCL)‐PS, PtBA‐PCL‐PS and PMMA‐PCL‐PS, were recovered by a simple precipitation in methanol without further purification. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3588–3598, 2007 相似文献