Minimum energy transmission scheduling subject to deadline constraints

We consider the problem of transmission scheduling of data over a wireless fading channel with hard deadline constraints. Our system consists of N users, each with a fixed amount of data that must be served by a common deadline. Given that, for each user, the channel fade state determines the throughput per unit of energy expended, our objective is to minimize the overall expected energy consumption while satisfying the deadline constraint. We consider both a linear and a strictly convex rate-power curve and obtain optimal solutions, based on dynamic programming (DP), and tractable approximate heuristics in both cases. For the special non-fading channel case with convex rate-power curve, an optimal solution is obtained based on the Shortest Path formulation. In the case of a linear rate-power curve, our DP solution has a nice “threshold” form; while for the convex rate-power curve we are able to obtain a heuristic algorithm with comparable performance with that of the optimal scheduling scheme. Alessandro Tarello received his M.Sc. and Ph.D. degrees in Electrical and Communication Engineering from Politecnico di Torino, Torino, Italy, in 2002 and 2006 respectively. He currently holds a Postdoctoral position at Politecnico di Torino. He visited the Laboratory for Information and Decision Systems at MIT, Cambridge, MA, USA, in 2004 and 2005. During Summer 2005 he also visited the Jet Propulsion Laboratory, Pasadena, CA, USA. He received the best student paper award at the Third International Symposium on Modeling and Optimization in Mobile, Ad-Hoc and Wireless Networks (WiOPT’05). His research interests are in the fields of stochastic and fluid models for performance evaluation of packet networks and optimization techniques for wireless and ad-hoc networks. Jun Sun received his B.S. degree in Computer Engineering from University of Florida in 1997 and his M.S. in Electrical Engineering from Massachusetts Institute of Technology in 2002. He is currently a Ph.D. student in the Laboratory for Information and Decision Systems at MIT. His research interest is on communication networks with emphasis on satellite and wireless networks. Murtaza Zafer received his B.Tech degree in Electrical Engineering from the Indian Institute of Technology (IIT), Madras, India, in 2001 and his M.S. degree in Electrical Engineering and Computer Science from the Massachusetts Institute of Technology (MIT), MA, USA, in 2003. Currently, he is pursuing his doctoral studies at the Laboratory for Information and Decision Systems (LIDS) in the department of Electrical Engineering and Computer Science at MIT. He spent the summer of 2004 at the Mathematical Sciences Research center, Bell Laboratories and the summer of 2003 at Qualcomm, Inc. His research interests lie in queueing theory, information theory, control and optimization theory and its applications to wireless communication networks. He is the co-recipient of the best Student Paper award at WiOpt, 2005. He also received the Siemens (India) and Philips (India) award for academic excellence. Eytan Modiano received his B.S. degree in Electrical Engineering and Computer Science from the University of Connecticut at Storrs in 1986 and his M.S. and PhD degrees, both in Electrical Engineering, from the University of Maryland, College Park, MD, in 1989 and 1992 respectively. He was a Naval Research Laboratory Fellow between 1987 and 1992 and a National Research Council Post Doctoral Fellow during 1992–1993. Between 1993 and 1999 he was with MIT Lincoln Laboratory where he was the project leader for MIT Lincoln Laboratory’s Next Generation Internet (NGI) project. Since 1999 he has been on the faculty at MIT; where he is presently an Associate Professor. His research is on communication networks and protocols with emphasis on satellite, wireless, and optical networks. He is currently an Associate Editor for Communication Networks for IEEE Transactions on Information Theory and for The International Journal of Satellite Communications. He had served as a guest editor for IEEE JSAC special issue on WDM network architectures; the Computer Networks Journal special issue on Broadband Internet Access; the Journal of Communications and Networks special issue on Wireless Ad-Hoc Networks; and for IEEE Journal of Lightwave Technology special issue on Optical Networks. He is the Technical Program co-chair for Wiopt 2006, IEEE Infocom 2007, and ACM MobiHoc 2007.     

Vibrational Fingerprinting of Defects Sites in Thin Films of Zeolitic Imidazolate Frameworks

Surface-mounted metal–organic frameworks (SURMOFs) are crystalline films of MOFs and have garnered a great deal of attention in the past years. So far, thin-film MOF research has been mainly focused on the synthesis and the exploration of potential applications of these materials, while a detailed understanding of their growth is still lacking. In this report evidence is provided for the inter-grown nature of surface-mounted thin films of Zn-ZIF-8 (SURZIF-8; ZIF=zeolitic imidazolate framework). Two distinct SURZIF-8 thin films have been made through layer-by-layer (LBL) growth after applying 20 and 50 LBL cycles. They have been characterized with atomic force microscopy (AFM) and Raman micro-spectroscopy. A detailed analysis of the Raman mapping data, inter alia using principal component analysis (PCA), revealed the existence of phase boundaries within the 20-cycle thin film, while the 50-cycle thin film is chemically more homogeneous. To further analyze these chemical heterogeneities, density functional theory (DFT) calculations were performed of three theoretical models providing spectroscopic fingerprints of the molecular vibrations associated with the Zn-ZIF-8 thin films. Based on these calculations and the experimental data distinct vibrational markers indicative for the presence of defects sites were identified.     

Distinguishing and quantification of the human visual pathways using high-spatial-resolution diffusion tensor tractography

Quantification of the living human visual system using MRI methods has been challenging, but several applications demand a reliable and time-efficient data acquisition protocol. In this study, we demonstrate the utility of high-spatial-resolution diffusion tensor fiber tractography (DTT) in reconstructing and quantifying the human visual pathways. Five healthy males, age range 24–37 years, were studied after approval of the institutional review board (IRB) at The University of Texas Health Science Center at Houston. We acquired diffusion tensor imaging (DTI) data with 1-mm slice thickness on a 3.0-Tesla clinical MRI scanner and analyzed the data using DTT with the fiber assignment by continuous tractography (FACT) algorithm. By utilizing the high-spatial-resolution DTI protocol with FACT algorithm, we were able to reconstruct and quantify bilateral optic pathways including the optic chiasm, optic tract, optic radiations free of contamination from neighboring white matter tracts.     

Renewability is not Enough: Recent Advances in the Sustainable Synthesis of Biomass‐Derived Monomers and Polymers

Taking advantage of the structural diversity of different biomass resources, recent efforts were directed towards the synthesis of renewable monomers and polymers, either for the substitution of petroleum‐based resources or for the design of novel polymers. Not only the use of biomass, but also the development of sustainable chemical approaches is a crucial aspect for the production of sustainable materials. This review discusses the recent examples of chemical modifications and polymerizations of abundant biomass resources with a clear focus on the sustainability of the described processes. Topics such as synthetic methodology, catalysis, and development of new solvent systems or greener alternative reagents are addressed. The chemistry of vegetable oil derivatives, terpenes, lignin, carbohydrates, and sugar‐based platform chemicals was selected to highlight the trends in the active field of a sustainable use of renewable resources.     

In situ electrochemical solid-phase extraction of anions and cations using polypyrrole and overoxidized sulfonated polypyrrole

A new method for the extraction of both anions and cations is proposed using electro-synthesized polypyrrole (PPy) and overoxidized sulfonated polypyrrole film (OSPPy). In situ anion (chloride, nitrate, sulfate) and cation (calcium, magnesium) uptake and release were examined under controlled potential conditions for prospective applications in electrochemically controlled solid-phase extraction (EC-SPE). The PPy film was used as an anode (anion-exchanger) and OSPPy film was used as a cathode (cation-exchanger) material and reverse order of the electrodes were investigated in EC-SPE. This new cell arrangement containing two ion exchanger polymer electrodes was developed to provide in situ removal of both anions and cations from aqueous solution. Simple preparation of the film coatings on a platinum plate was possible using a constant potential method. Applied positive and negative potentials facilitated the in situ extraction and desorption of ions, respectively. Both anions and cations were desorbed into sample aliquot and were determined by ion chromatography (IC). The method was validated using a standard reference material and tested for the determination of the ions in real water samples.     

Photoconductive novel mesomorphic oxotitanium phthalocyanines

The synthesis and photoconductivity properties of the alkylthia and triethyleneoxysulfonyl substituted oxotitanium(IV) phthalocyanines (1a and 2a) are reported for the first time. The new compounds have been characterized by elemental analysis, IR, ¹H and ¹³C NMR spectroscopy, electronic spectroscopy and mass spectroscopy. The mesogenic properties of these new materials were studied by differential scanning calorimetry and optical microscopy. The electrical dark conductivities (σ_d) and photoconductivities (σ_ph) of deposited films of 1a and 2a were investigated in various media with different concentrations of oxygen. Molecular oxygen increases photoconductivities (σ_ph) significantly. The photoconductivity mechanism and formation of Pc⁺ which is positive charge carrier under the light irradiation of the phthalocyanine molecules are demonstrated using the theoretical calculations. The geometries of the oxotitanium(IV) phthalocyanines (TiOPc) are optimized with PM3 semi-empirical method, and their visible absorption maxima are calculated with ZINDO/S method. The results agree well with the observed values. It was found that for the calculation of visible absorption of neutral and positively charged substituted TiOPc molecules using ZINDO/S method could rapidly yield excellent results. Dipole moment, HOMO, LUMO energies and atomic charges are also calculated for clarification of the oxygen effect on the photoconductivity using PM3 and ZINDO/S methods.     

An Effective Approach for High‐Efficiency Photoelectrochemical Solar Cells by Using Bifunctional DNA Molecules Modified Photoanode

This paper firstly reports the effect of deoxyribonucleic acid (DNA) molecules extracted from chickpea and wheat plants on the injection/recombination of photogenerated electrons and sensitizing ability of dye‐sensitized solar cells (DSSCs). These high‐yield DNA molecules are applied as both linker bridging unit as well as thin tunneling barrier (TTB) at titanium dioxide (TiO₂ )/dye interface, to build up high‐efficient DSSCs. With its favorable energy levels, effective linker bridging role, and double helix structure, bifunctional DNA modifier shows an efficient electron injection, suppressed charge recombination, longer electron lifetime, and higher light harvesting efficiency, which leads to higher photovoltaic performance. In particular, a photoconversion efficiency (PCE) of 9.23% is achieved by the binary chickpea and wheat DNA‐modified TiO₂ (CW@TiO₂) photoanode. Furthermore, time‐resolved fluorescence spectroscopy measurements confirm a better electron transfer kinetics for DNA‐modified TiO₂ photoanodes, implying a higher electron transfer rate (k_ET). This work highlights a great contribution for the photoanodes that are linked with DNA molecule, which act as both bridging unit and TTB to control the charge recombination and injection dynamics, and hence, boost the photovoltaic performance in the DSSCs.     

Electronic structure and correlations of vitamin B<Subscript>12</Subscript> studied within the Haldane-Anderson impurity model

We study the electronic structure and correlations of vitamin B₁₂ (cyanocobalamine) by using theframework of the multi-orbital single-impurity Haldane-Anderson model of atransition-metal impurity in a semiconductor host. The parameters of the effectiveHaldane-Anderson model are obtained within the Hartree-Fock (HF) approximation. Thequantum Monte Carlo (QMC) technique is then used to calculate the one-electron andmagnetic correlation functions of this effective model. We observe that new states forminside the semiconductor gap found by HF due to the intra-orbital Coulomb interaction atthe impurity 3d orbitals. In particular, the lowest unoccupiedstates correspond to an impurity bound state, which consists of states from mainly the CNaxial ligand and the corrin ring as well as the Co e_g-like orbitals. We alsoobserve that the Co?(3d) orbitals can develop antiferromagneticcorrelations with the surrounding atoms depending on the filling of the impurity boundstates. In addition, we make comparisons of the HF+QMC data with the density functionaltheory calculations. We also discuss the photoabsorption spectrum of cyanocobalamine.