影响面粉中铝含量测定因素分析

目的探讨了江苏省疾控[2009]97号文件附录A《面制品及海蜇中铝的测定方法》测定面制食品中铝含量。方法样品经干法消化后,在乙二胺-盐酸缓冲溶液中,三价铝在十六烷基三甲基溴化铵阳离子表面活性剂存在下,与铬天青S形成绿色三元体系,其吸光度与铝的含量在一定含量范围内成正比。结果样品消化液在定容30 min时测定结果接近中位值,方法线性系数r=0.999 7,相对标准偏差在3.3%~3.7%之间,样品回收率在88.9%~96.4%。结论该法操作简便,灵敏度高,适用于各实验室开展检测。     

Ab initio calculations on the ground and excited states of InI

Potential energy curves (PECs) of the ground and the low-lying excited states of the InI molecule are computed using the internally contracted multireference singles and doubles configuration interaction with the Davidson correction (ic-MR-CISD + Q) method based on the relativistic effective core potentials (RECPs). The spectroscopic constants are obtained, including the excitation energy (T _e), the equilibrium bond distance (R _e), the dipole moment (μ_e) and the vibrational constants (ω_e and ω_e). Finally, we predict the transition dipole moments, the radiative lifetimes, and the Franc-Condon factors for the transitions of A³Π₀+ ? X¹Σ₀ ⁺ and B³Π^l ? X¹Σ₀ ⁺,. The results reveal that A³Π₀+ and B³Π_l are long-lived states with the lifetimes being of the order of microseconds.     

基于回波平移序列的快速三维磁共振温度成像方法

高强度聚焦超声（HIFU）是一种无创的热消融疗法，为保证其安全性和有效性，需要一种精度高、速度快的测温方法在其治疗过程中对温度进行监控.基于质子共振频率位移（PRFS）的磁共振温度成像（MRT）对温度具有较高的灵敏度，且与温度具有良好的线性关系，因此常被用于引导HIFU治疗.然而在实际应用中，HIFU治疗的最大隐患在于可能造成表皮灼伤，并且灼伤区域可能与焦点区域相隔较远.因此MRT的监控范围十分重要.本文基于三维回波平移成像序列，结合可控混叠的空间并行成像技术，实现了时间分辨率为3 s的快速三维温度成像.为了验证该方法的精度，本文首先设计了仿体降温实验，利用光纤温度计验证回波平移序列测温的准确度和精确度.然后在室温条件下扫描离体猪肉组织，对比加速前后的MRT的测温精确度.在HIFU加热条件下扫描离体猪肉组织，对比加速前后的MRT的测温准确度.结果显示，本文提出的方法可以在3 s内完成三维温度精准测量，对于HIFU治疗的安全监控具有重要意义.     

Differential equation dynamical system based assessment model in GNSS interoperability

With the development of Global Navigation Satellite System (GNSS),the idea of GNSS interoperability is born and has become the focus of study in the field of satellite navigation.The popularity for GNSS to augment the interoperability with the existing ones necessitates the study of the assessment algorithm of this idea.In this paper,an assessment algorithm for interoperability comprehensive benefits based on the differential equation dynamical system is discussed.There are two important aspects in GNSS tha...     

Recoverable Mn~Ⅲ (salen) supported on diamine modified zirconium poly(styrene-isopropenyl phosphonate)-phosphate as an efficient catalyst for epoxidation of unfunctionalized olefins

Chiral Mn Ⅲ (salen) (Jacobsen’s catalyst) was axially immobilized onto a new type of organic polymer-inorganic hybrid materialzirconium poly(styrene-isopropenyl phosphonate)-phosphate(ZPS-IPPA) with different linkage lengths and evaluated as catalysts for the epoxidation of unfunctionalized olefins. The results demonstrated that the prepared catalysts exhibited moderate to good activity and enantioselectivity in the asymmetric epoxidation of unfunctionalized olefins. Furthermore, the immobilized catalysts were relatively stable and could be conveniently separated from the reaction system by simple precipitation in hexane. Moreover, higher enantioselectivity was obtained with catalyst 2c than that of homogeneous counterpart catalyzed even after eight times. The excellent recycling of the catalyst was attributed to its structure feature of ZPS-IPPA which is different from either pure polystyrene or pure zirconium phosphates.     

基于LabVIEW的车辆监测系统的设计

基于National Instructionals公司的LabVIEW虚拟仪器技术,设计和搭建了车辆监测系统。利用车载GPS/北斗定位接收系统获取定位信息,通过GPRS将定位信息传递至监控台,监控台将信息汇总后返回至每一车辆,将所有车辆的位置信息共享并显示。监测及显示软件通过LabVIEW编写,以期实现车辆运行状况的实时监控。实验结果表明,该系统能够精确有效地监测和显示车辆的运行状况。     

MCML结构高速数模转换器的设计

本文基于MCML结构,采用TSMC 0．18μm 1P6M CMOS标准工艺设计方法,通过模拟仿真试验,设计出了一个8位分段式全温度计编码的高速数模转换器,该电路在采样频率为1 GHZ,输入正弦波频率为122 MHz时,SFDR达到了58．35 dB,在采样频率为2 GHZ,输入正弦波频率为244 MHz时,SFDR达到了50．21 dB。     

基于恒流二极管（CRD）的运算放大器低功耗研究

基于CRD对741双极型通用集成运放进行改进研究,通过CRD替代双极型集成运算放大器（OPAMP）输入级及偏置电路中做为恒流源的双极型器件,并利用Multisim 10和Cadence进行设计与仿真。结果表明,当电源电压改变时,双极型运算放大器输入级电流在0．290 mA到0．433 mA变化,而基于CRD的差分输入级电流恒定在0．239 mA到0．244 mA之间,且电流变化只有0．005 mA。当电源电压恒定在13 V时,双极型运算放大器偏置电流达到0．739 mA,而基于CRD偏置电路电流只有0．222 m。由此可知,基于CRD的运算放大器能实现更低功耗。     

基于OpenMP的并行空间电磁分布计算

获得空间电磁场场强分布是电磁频谱管理的重要任务之一,研究如何提高其计算性能以适应快速变化的空间电磁环境具有重要的意义。OpenMP(Open Multi Processing)是一种简单快速提高计算效率的方式,它有助于CPU多核资源被充分利用。提出了一种基于Open MP的并行获得空间电磁场场强分布方法,通过合理分析计算过程,设计相应并行方案,使得设计的并行算法适合CPU多核处理方式,并行度高。大量实验结果表明,该并行算法明显提高了计算效率,且具有高可扩展性。     

一种新型双频段共用馈源设计

提出了一种新的同轴式S/X双频共用馈源的设计方法,用于解决卫星通信与测控天线对于双频共用、双频单脉冲跟踪馈源的需求问题。运用模式匹配法分析了同轴馈源的电磁场特性,给出了利用同轴馈源的TEM模用于单脉冲跟踪的新思路,仿真设计了同轴喇叭和主要波导器件并加工实物进行测试。实测结果表明,在S和X 2个频段,馈源驻波比均小于1.35,轴比低于1.2 d B,边缘照射电平约为-15 d B,差方向图零深低于-30 d B,满足工程应用要求。